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Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.