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Monitoring Urea Quantity Delivery for Diesel SCR After-treatment

2012-02-01
While providing significant benefits to vehicle operation and emissions, on board diagnosis comes at a cost. In many cases the additional cost comes in the form of reduced optimal performance. Often the additional cost can be mitigated by considering the OBD requirements early in the development stages. In this presentation we show these trade-offs in a number of case studies. We will point out where the ability to diagnose comes at the cost of suboptimal performance, and where system design decisions can facilate the OBD task. Presenter Michiel Van Nieuwstadt, Ford Motor Co.
Journal Article

The Effects of Sulfur Poisoning and Desulfation Temperature on the NOx Conversion of LNT+SCR Systems for Diesel Applications

2010-04-12
2010-01-0300
A laboratory study was performed to assess the effects of sulfur poisoning and desulfation temperature on the NO conversion of a LNT+(Cu/SCR) in-situ system. Four LNT+(Cu/SCR) systems were aged for 4.5 hours without sulfur at 600, 700, 750, and 800°C using A/F ratio modulations to represent 23K miles of desulfations at different temperatures. NO conversion tests were performed on the LNT alone and on the LNT+SCR system using a 60 s lean/5 s rich cycle. The catalysts were then sulfur-poisoned at 400°C and desulfated four times and re-evaluated on the 60/5 tests. This test sequence was repeated 3 more times to represent 100K miles of desulfations. After simulating 23K miles of desulfations, the Cu-based SCR catalysts improved the NO conversion of the LNT at low temperatures (e.g., 300°C), although the benefit decreased as the desulfation temperature increased from 600°C to 800°C.
Journal Article

The Impact of Biodiesel on Particle Number, Size and Mass Emissions from a Euro4 Diesel Vehicle

2010-04-12
2010-01-0796
New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.
Journal Article

A Study of Active and Passive Regeneration Using Laboratory Generated Soot on a Variety of SiC Diesel Particulate Filter Formulations

2010-04-12
2010-01-0533
In this study an attempt to understand and demonstrate the effects of various washcoat technologies under active and passive regeneration conditions was performed. Six different formulations, on 1.0" D. x 3.0" L. SiC wall flow filters at the laboratory level were used at various test conditions, including variable NO₂/NO ratios and O₂ concentrations. Samples were regenerated using active and passive conditions to evaluate regeneration rates and the potential impact of regeneration at the vehicle level. Results were applied to vehicle operating conditions to determine passive functionality and potential benefits. Active regenerations at 2% O₂ and 5% O₂ showed no significant difference in time to complete regeneration and soot burn rates. Active regenerations performed at 1% O₂ and 5% O₂ concentration showed that the regeneration temperature was shifted by approximately 50°C.
Journal Article

Laboratory and Vehicle Demonstration of “2nd-Generation” LNT + in-situ SCR Diesel NOx Emission Control Systems

2010-04-12
2010-01-0305
This study extends research previously reported from our laboratory [SAE 2009-01-0285] on diesel NOx control utilizing a new generation of Lean NOx Trap (LNT) plus in-situ Selective Catalytic Reduction (SCR) catalyst systems. Key findings from this work include 1) evidence for a “non-ammonia” reduction pathway over the SCR catalyst (in addition to the conventional ammonia pathway), 2) high NOx conversions utilizing LNT formulations with substantially lower platinum group metal (PGM) loadings than utilized in earlier systems, 3) ability of the downstream SCR catalyst to maintain high overall system NOx efficiency with aged LNTs, and 4) effectiveness of both Cu- and Fe-zeolite SCR formulations to enhance overall system NOx efficiency. FTP NOx conversion efficiencies in excess of 95% were obtained on two light-duty vehicle platforms with lab-aged catalyst systems, thus showing potential of the LNT+SCR approach for achieving the lowest U.S. emissions standards
Journal Article

Turbocharger Turbine Inlet Isentropic Pressure Observer Model

2015-04-14
2015-01-1617
Exhaust pressures (P3) are hard parameters to measure and can be readily estimated, the cost of the sensors and the temperature in the exhaust system makes the implementation of an exhaust pressure sensor in a vehicle control system a costly endeavor. The contention with measured P3 is the accuracy required for proper engine and vehicle control can sometimes exceed the accuracy specification of market available sensors and existing models. A turbine inlet exhaust pressure observer model based on isentropic expansion and heat transfer across a turbocharger turbine was developed and investigated in this paper. The model uses 4 main components; an open loop P3 orifice flow model, a model of isentropic expansion across the turbine, a turbine and pipe heat transfer models and an integrator with the deviation in the downstream turbine outlet parameter.
Journal Article

NVH Development of the Ford 2.7L 4V-V6 Turbocharged Engine

2015-06-15
2015-01-2288
A new turbocharged 60° 2.7L 4V-V6 gasoline engine has been developed by Ford Motor Company for both pickup trucks and car applications. This engine was code named “Nano” due to its compact size; it features a 4-valves DOHC valvetrain, a CGI cylinder block, an Aluminum ladder, an integrated exhaust manifold and twin turbochargers. The goal of this engine is to deliver 120HP/L, ULEV70 emission, fuel efficiency improvements and leadership level NVH. This paper describes the upfront design and optimization process used for the NVH development of this engine. It showcases the use of analytical tools used to define the critical design features and discusses the NVH performance relative to competitive benchmarks.
Journal Article

Laboratory and Vehicle Demonstration of “2nd-Generation” LNT + in-situ SCR Diesel Emission Control Systems

2011-04-12
2011-01-0308
Diesel NOx emissions control utilizing combined Lean NOx Trap (LNT) and so-called passive or in-situ Selective Catalytic Reduction (SCR) catalyst technologies (i.e. with reductant species generated by the LNT) has been the subject of several previous papers from our laboratory [ 1 - 2 ]. The present study focuses on hydrocarbon (HC) emissions control via the same LNT+SCR catalyst technology under FTP driving conditions. HC emissions control can be as challenging as NOx control under both current and future federal and California/Green State emission standards. However, as with NOx control, the combined LNT+SCR approach offers advantages for HC emission control over LNT-only aftertreatment. The incremental conversion obtained with the SCR catalyst is shown, both on the basis of vehicle and laboratory tests, to result primarily from HC adsorbed on the SCR catalyst during rich LNT purges that reacts during subsequent lean engine operation.
Journal Article

Determining Soot Distribution in the Vehicle Exhaust Downstream of a Faulty Diesel Particulate Filter

2013-04-08
2013-01-1562
New emissions certification requirements for medium duty vehicles (MDV) meeting chassis dynamometer regulations in the 8,500 lb to 14,000 lb weight classes as well as heavy duty (HD) engine dynamometer certified applications in both the under 14,000 lb and over 14,000 lb weight classes employing large diameter exhaust pipes (up to 4″) have created new exhaust stream sampling concerns. Current On-Board-Diagnostic (OBD) dyno certified particulate matter (PM) requirements were/are 7x the standard for 2010-2012 applications with a planned phase in down to 3x the standard by 2017. Chassis certified applications undergo a similar reduction down to 1.75x the standard for 2017 model year (MY) applications. Failure detection of a Diesel Particulate Filter (DPF) at these low detection limits facilitates the need for a particulate matter sensor.
Journal Article

An Adaptive Proportional Integral Control of a Urea Selective Catalytic Reduction System based on System Identification Models

2010-04-12
2010-01-1174
For urea Selective Catalytic Reduction (SCR) systems, adaptive control is of interest to provide a capability of maintaining high NOx conversion efficiency and low ammonia slip in the presence of uncertainties in the system. In this paper, the dynamics of the urea SCR system are represented by a control-oriented model which is based on a linear transfer function, with parameters dependent on engine operating conditions. The parameters are identified from input-output data generated by a high fidelity full chemistry model of the urea SCR system. The use of the full chemistry model facilitated the representation of the dynamics of stored ammonia (not a directly measurable parameter) as well as post SCR NOx and ammonia slip. A closed-loop Proportional-plus-Integral (PI) controller was first designed using the estimate of stored ammonia as a feedback signal.
Technical Paper

The Effect of a Preload on the Decoupling Efficiency of Exhaust Flexible Coupling Devices

1997-11-17
973272
The variation in the decoupling effect of exhaust flexible couplings under a vertical preload caused by changes in the direction of the exhaust pipe routing was investigated. Both self-supporting and underbody flexible couplings were tested. The results indicate that, in general, a preload decreases the decoupling efficiency of both types of flexible couplings. In addition, the results indicate that the efficiency of the flexible coupling is effected by the following three conditions: the direction of preload with respect to gravity, the location of the preload relative to the coupling, and the stiffness of the various components of the flexible coupling.
Technical Paper

Initial Evaluation of a Spill Valve Concept for Two-Stroke Cycle Engine Light Load Operation

1990-09-01
901663
Two-stroke cycle direct injection engines can achieve adequate stability at idle with stratified combustion at very lean overall air-fuel ratio, but exhaust temperature is very low. A rotary valve system was designed to spill charge from the cylinder into the intake tract during the compression stroke, in order to allow stable operation at lower engine delivery ratio and thereby increase exhaust temperature. Reduction of the engine delivery ratio was not achieved due to the poor scavenging characteristics of the swirl liners used, which resulted in high content of exhaust residual gas in the spill recirculation flow. Although the concept objective of higher exhaust temperature was not realized, the results indicate that the concept may be feasible if high purity of the spill recirculation flow can be achieved in conjunction with high trapping efficiency.
Technical Paper

Power Steering Noise Characterization and Evaluation

2008-03-30
2008-36-0550
Each more the consumer uses the vehicle noise, vibration, and harshness (NVH) attributes to define the vehicle model when purchasing a car, so the sound quality development is very important to guarantee the automaker success in a competitive market. Several vehicle components contribute to the consumer sound quality perception, as engine, gearbox and exhaust systems. So those components improvement is necessary in order to enrich the sound perception. In this article will be developed a case study that evaluates the contribution and the characteristics of the irradiated noise from the power steering system, which was classified as moan, whine and hiss noise, defines objectively each phenomena and evaluate the proposed systems.
Technical Paper

The Development of Advanced Urea-SCR Systems for Tier 2 Bin 5 and Beyond Diesel Vehicles

2010-04-12
2010-01-1183
An advanced diesel aftertreatment system utilizing Selective Catalytic Reduction (SCR) with urea for lean nitrogen oxides (NOx) control was tested on a 2.7L V6 Land Rover vehicle to demonstrate the capability of achieving Tier 2 Bin 5 and lower emission standards for light-duty trucks. SCR washcoat was applied to a diesel particulate filter (DPF) to perform NOx and particulate reduction simultaneously. Advanced SCR systems employed both traditional SCR catalysts and SCR-coated filters (SCRF) to improve the NOx reduction efficiency. The engine-out NOx level was adjusted by modifying the EGR (Exhaust Gas Recirculation) calibration. Cold start NOx performance was improved by SCR warm-up strategy and urea over injection. This study showed the advanced SCR system could tolerate higher NH₃ storage in the SCR catalyst, resulting in overall higher NOx conversion on the FTP-75 test cycle.
Technical Paper

Deactivation of Cu/Zeolite SCR Catalyst under Lean-Rich Aging Conditions

2010-04-12
2010-01-1180
A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.
Technical Paper

Diesel EGR Cooler Fouling with Ni-Fe-Cr-Al DPF at Freeway Cruise

2010-10-05
2010-01-1955
This study investigates the effect of diesel particulate filters (DPF) on the performance of exhaust gas recirculation (EGR) coolers. EGR coolers were tested with and without the use of a DPF and their measured performances were compared. The exhaust gas was filtered using a Ni-Fe-Cr-Al metallic foam wall flow diesel particulate filter. The DPFs used in this investigation had very low Space Velocity (SV) characteristics in order to minimize the effect of filtration on the pressure drop. Two different measurement methods were employed to determine particulate matter (PM) emission levels at locations before and after the DPF. The first method involved the collection of PM on quartz filters followed by thermal analysis of the filters to monitor the removal of soot, semi-volatile organics, and sulfate across the DPF. The second method measured the time resolved PM mass in the exhaust with a Dekati Mass Monitor.
Technical Paper

Optimum Gap Design And Durability Analysis of Catalytic Converter Assembly

2001-03-05
2001-01-0942
A method to predict gap distribution, can deformation and mounting force of catalytic converter during assembling and operation cycles has been developed using ABAQUS contact algorithm with user subroutine for material properties. Inherent in the methodology is the constitutive model for both vermiculite mat and wire mesh mounting materials, which is able to describe their nonlinear and thermal behaviors and shows good agreement with test results. A design optimization procedure is presented to achieve uniform gap design of can and substrate. The technology will enable engineers to generate robust converter can designs, substrate shape and stamping tools for minimum manufacturing failure rate and maximum durability performance once a mounting material is selected.
Technical Paper

A Dyno Data Acquisition System for Lean NOx Trap Investigations

2001-03-05
2001-01-0208
A flexible, easily configuration data acquisition system was designed and built for detailed studies of the steady state and dynamic properties of lean NOx traps for an engine dynamometer environment. The system is based on the industry standard VXI backplane. The overriding design philosophy was to design and develop a data acquisition system that was user friendly and could be operated easily by engine laboratory technicians, as well as by test engineers. The primary requirements guiding the design were the following: (1) the ability easily to configure, save, recall, modify, and print test configurations. (2) The ability to configure the gain, channel name, and engineering units for each analog channel. (3) The ability to trigger from one analog input channel. (4) A provision for numeric auto-incrementing of data file names. (5) The ability to save data in Excel™ compatible ASCII format. (6) The utilization of off-the shelf VXI hardware.
Technical Paper

Suppression of Sulfide Emission During Lean Nox Trap Desulfation

2001-03-05
2001-01-1299
Lean NOx traps are being extensively examined (Ref. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 and 12) because they can be efficiently used to reduce the NOx emissions from port fuel injected and direct fuel injected spark ignited gasoline engines. A lean NOx trap (LNT) stores NOx during lean A/F engine operation. However, its storage capacity is limited and the LNT must be regenerated periodically by subjecting the LNT to momentary rich A/F operation for several seconds. The regeneration process releases the NOx that is chemically bonded to the washcoat and subsequently reduces it to N2 and O2. Fuel that contains a non-zero amount of sulfur will contaminate an LNT by significantly reducing its NOx storage capacity. Therefore, except for the case of a zero level of sulfur in the fuel, the LNT must be desulfated on a periodic basis. The desulfation process requires that the temperature of the LNT be raised to a temperature of about 650°C for several minutes.
Technical Paper

Catalytic Converter Design Incorporating Dynamic Can Deformation

2002-05-06
2002-01-1751
A stochastic simulation based on the Monte-Carlo method was developed to re-target gap bulk density (GBD) in ceramic catalytic converters. The combined effect of manufacturing tolerances, shell spring back and thermal expansion was analyzed by this model. Shell spring back during the canning process was calculated using Finite Element Analysis (FEA). Thermal shell expansion was obtained using can deformation data from the Key-Life Test (KLT). An example of optimized GBD that provides a robust and manufacturable design is also presented.
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