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For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both conventional diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study.

For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.

Fuel supercriticality has recently received significant attention due to the elevated pressures and temperatures that directly-injected (DI) fuel sprays encounter in modern internal combustion (IC) engines. This paper presents a theoretical examination of conventional and alternative DI fuels at conditions relevant to the operation of compression ignition (CI) engines. The focus is to identify the conditions under which the injected liquid fuel can bypass the atomization process and directly transition to a diffusional mixing regime with the chamber gas. Evaluating the microscopic length-scales of the phase boundary associated with the injection of liquid nitrogen into its own vapor, it is found that the conventional threshold based on the interfacial Knudsen number (i.e. Kn = 0.1) does not adequately quantify the direct transition between sub- and supercriticality. Instead, a threshold that is an order of magnitude smaller is more appropriate for this purpose.

Compressed natural gas (CNG) is an attractive, alternative fuel for spark-ignited (SI), internal combustion (IC) engines due to its high octane rating, and low energy-specific CO2 emissions compared with gasoline. Directly-injected (DI) CNG in SI engines has the potential to dramatically decrease vehicles’ carbon emissions; however, optimization of DI CNG fueling systems requires a thorough understanding of the behavior of CNG jets in an engine environment. This paper therefore presents an experimental and modeling study of DI gaseous jets, using methane as a surrogate for CNG. Experiments are conducted in a non-reacting, constant volume chamber (CVC) using prototype injector hardware at conditions relevant to modern DI engines. The schlieren imaging technique is employed to investigate how the extent of methane jets is impacted by changing thermodynamic conditions in the fuel rail and chamber.