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Urea-SCR system consisted of combined deNOx catalysts with wide range of temperature window, injector, sensor and injection controller. Synthetic gas activity test and NOx conversion efficiency test on the engine bench were carried out to evaluate and improve the performance of this system. To better suit the application of the urea-SCR system without engine modification, temperature of catalyst and engine RPM were used as input data to control amounts of urea aqueous solution that reacts with NOx. We concentrated on designing types of deNOx catalysts and controlling amounts of urea solution under different driving conditions to achieve higher NOx reduction and wider temperature window. Designed urea-SCR system showed substantial NOx reduction performance and relatively wide temperature window under different driving conditions.

The combustion characteristics of a HSDI diesel engine were analyzed numerically using a reduced chemical kinetics. The reaction mechanism consisting of 26 steps and 17 species including the Zel'dovich NOx mechanism for the higher hydrocarbon fuel was implemented in the KIVA-3V. The characteristic time scale model was adopted to account for the effects of turbulent mixing on the reaction rates. The soot formation and oxidation processes are represented by Hiroyasu's model and NSC's model. The validation cases include the homogenous fuel/air mixture and the spray combustion in a constant volume chamber. After the validation, the present approach was applied to the analysis of the spray combustion processes in a HSDI diesel engine. The present approach reasonably well predicts the ignition delay, combustion processes, and emission characteristics in the high-pressure turbulent spray flame-field encountered in the practical HSDI diesel engines.

The Representative Interactive Flamelet(RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection diesel engine. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the RIF concept has the capabilities to predict the auto-ignition and subsequent flame propagation in the diesel engine combustion chamber as well as to effectively account for the detailed mechanisms of soot and NOx formation. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the Eulerian Particle Flamelet Model using the multiple flamelets has been employed. Special emphasis is given to the turbulent combustion model which properly accounts for vaporization effects on turbulence-chemistry interaction.

Emission of carbon dioxide from mobile sources seriously concerned to solve greenhouse effect and high price of gasoline in some countries have resulted in the development of lean-burn concept engine. In spite of many studies on the lean deNOx catalyst, we have no clear solution to obtain high fuel economy and high efficiency of NOx conversion in lean-burn application. This paper describes applicability and problems of NOx adsorber system to partial lean-burn vehicle, the development of three-way catalyst with improvement of washcoat technology based on three-way catalyst used for gasoline application, and comparison test results of evaluations is synthesized gas activity test, Federal Test Procedure (FTP) test, etc. This study shows improved three-way catalysts in partial lean- burn vehicle have max. 89% of NOx conversion in FTP without adding rich spike and regeneration functions to engine management system.

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.

Diesel engines are the most commonly used power train of the freight and public transportations in the world. From the viewpoint of global warming restraint, however, reduction of exhaust emissions from the diesel engine is urgent demand. Stringent emission regulations are being proposed with growing concern on NOx, PM and CO2 emissions. Future emission regulations require advanced emission control technologies, such as SCR(Selective Catalytic Reduction), LNT(Lean NOx Trap) and EGR(Exhaust Gas Recirculation). The EGR is a commonly used technique to reduce emission. In this study, a LP-EGR(Low Pressure Exhaust Gas Recirculation) system was investigated to evaluate its potential on emission reduction and fuel economy improvement, especially for a passenger diesel engine. A 3.0ℓ diesel engine equipped with the LP-EGR system was tested using an in-house control algorithm.

Currently, diesel engine-out exhaust NOx emission level prediction is a major challenge for complying with the stricter emission legislation and for control purpose of the after-treatment system. Most of the NOx prediction research is based on the Zeldovich thermal mechanism, which is reasonable from the physical point of view and for its simplicity. Nevertheless, there are some predictable range limitations, such as low temperature with high EGR rate operating conditions or high temperature with low EGR rates. In the present paper, 3 additional considerations, pilot burned gas mixing before the main injection; major NO formation area; concentration correction, were applied to the previously developed real-time NO estimation model based on in-cylinder pressure and data available from ECU. The model improvement was verified on a 1.6 liter EURO5 diesel engine in both steady and transient operation.

As environmental problems such as global warming are emerging, regulations on automobile exhaust gas are strengthened and various exhaust gas reduction technologies are being developed in various countries in order to satisfy exhaust emission regulations. Exhaust gas recirculation (EGR) technology is a very effective way to reduce nitrogen oxides (NOx) at high combustion temperatures by using EGR coolers to lower the combustion temperature. This EGR cooler has been mass-produced in stainless steel, but it is expensive and heavy. Recently, high efficiency and compactness are required for the EGR cooler to meet the new emission regulation. If aluminum material is applied to the EGR cooler, heat transfer efficiency and light weight can be improved due to high heat transfer coefficient of aluminum compared to conventional stainless steel, but durability is insufficient. Therefore, the aluminum EGR cooler has been developed to enhance performance and durability.

The author's new approach, diesel and gasoline dual fuel powered combustion system based on diesel CI triggered ignition control, provides not only how key ideas extracted from LTC concept could be established in a small bore HSDI turbocharged diesel engine but also which mechanism works to bring almost same benefits as we have experienced in both conventional diesel combustion and LTC based advanced combustion systems like HCCI, PCCI and PPCI combustions. The combustion system presented in the paper physically combines both mixing controlled diesel compression ignition combustion and gasoline premixed charge combustion in one power generation cycle. Gasoline fuel in the system is provided by the conventional gasoline PFI system firstly into the cylinder in which premixed charge spreads out. In compression stroke, the exact amount of diesel fuel is injected into the highly diluted EGR ambient with premixed gasoline charge.

A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

In diesel engine development, the new technology is coming out to meet the stringent exhaust emission regulation. The regulation demands more eco-friendly vehicles. Euro6c demands to meet not only WLTP mode, but also RDE(Real Driving Emission). In order to satisfy RDE mode, the new technology to reduce emissions should cover all operating areas including High Load & High Speed. It is a big challenge to reduce NOx on the RDE mode and a lot of DeNOx technologies are being developed. So the new DeNOx technology is needed to cover widened operating area and strict acceleration / deacceleration. The existing LNT(Lean NOx Trap) and Urea SCR(Selective Catalytic Reduction) is necessary to meet the typical NEDC or WLTP, but the RDE mode demands the powerful DeNOx technology. Therefore, the LNT & Urea SCR on DPF was developed through this study.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

The worldwide fuel economy compliance level has been tightening, at the same time, LEV-III/Euro-6d/China-6/BS-6 regulations for NMOG and NOx emissions are being introduced or already effective. Therefore, intensive research effort has been conducted in order to improve the fuel efficiency of passenger cars and reduce exhaust emission. In response to these demands, turbocharged gasoline direct injection (TGDI) engine is being introduced for gasoline vehicles in consideration of fuel efficiency improvement, high output and driving performance compared to naturally aspirated (NA) engine. However, due to its larger thermal mass from the turbo hardware in the exhaust, it suffers from the cold-start emission. The main hazardous gases emitted from gasoline vehicles are CO, HC and NOx, and a three-way catalyst (TWC) is installed for the purification of these harmful emissions.

Generally, vehicles do not need power during deceleration. Therefore, the fuel efficiency can be improved by stopping the fuel injection in this period. However, when the fuel cut is activated, NOx is emitted immediately after fuel cut. During the fuel cut period, a large amount of fresh air flows into the catalytic converter installed on a vehicle since there is no combustion. Thus, the catalytic materials are converted into an oxidizing atmosphere. As a result, NOx purification performance of the catalyst deteriorates, and eventually NOx is emitted when combustion restarts. The quantity of NOx in this period is relatively small. However, in case of increasing fuel cuts, emission problem could arise. Therefore, in order to meet the stringent regulation such as LEV III-SULEV20 or 30, the number of fuel cuts need to be limited. The problem is that this strategy leads to a disadvantage of fuel efficiency.

Recently, regulations on automobile emission have been significantly strengthened to address climate change. The automobile industry is responding to these regulations by developing electric vehicles that use batteries and fuel-cells. Automobile emissions are environmentally harmful, especially in the case of vehicles equipped with high-temperature and high-pressure diesel engines using compression-ignition, the proportion of nitrogen oxides (NOx) emissions reaches as high as 85%. Additionally, air pollution caused by particulate matter (PM) is six to ten times higher compared to gasoline engines. Therefore, the electrification of commercial vehicles using diesel engines could potentially yield even greater environmental benefits. For commercial vehicles battery electric vehicles (BEVs) require a large number of batteries to secure a long driving range, which reduces their maximum payload capacity.