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The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges. Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies. The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission.

This paper presents the detailed characterization of particulate emissions from a NADI™ dual mode engine (HCCI at low load and conventional combustion at high load). Morphology, composition and chemical reactivity of the particulate matter generated on an engine running in HCCI mode have been specified and compared to the conventional mode reference. Results showed that HCCI combustion formed particles with a higher volatile organic fraction due to the relatively high level of HC generated by this kind of combustion. Advanced soot characterization emphasized that HCCI soot is oxidized at a slower reaction rate than conventional soot, but with a lower temperature. This last characteristic could partially compensate the poor continuous regeneration effect due to low NO2 emission levels observed in HCCI combustion. Microscopic observation and particle sizing did not show significant differences between HCCI and conventional soot.

Lean-burn combustion in SI engines can significantly reduce fuel consumption but NOx reduction becomes challenging because classic three-way catalyst (TWC) is no more efficient. Urea-SCR is then an interesting alternative solution because of its high NOx conversion efficiency without any additional fuel consumption. The coupling between two SI lean-burn engines (stratified and homogeneous combustion) and a urea-SCR catalyst was simulated on the NEDC cycle. Simulation results showed that the SCR efficiency would comply with the limits required by future Euro 5/6 regulations. Associated urea solution consumptions were estimated thanks to a simplified model. Finally, a comparison with a Diesel application was also made. It showed that the required amount of reducing agent remained significantly higher for SI lean-burn engines than for Diesel engine.