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After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Some lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot predict all possible events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Thermal characterization was performed on a vapor compression heat pump using a novel, hybrid two phase loop design. Previous work on this technology has demonstrated its ability to provide passive phase separation and flow control based on capillary action. This provides high quality vapor to the compressor without relying on gravity-based phase separation or other active devices. This paper describes the subsequent work done to characterize evaporator performance under various startup scenarios, tilt angles, and heat loads. The use of a thermal expansion valve as a method to regulate operation was investigated. The effect of past history of use on startup behavior was also studied. Testing under various tilt angles showed evaporator performance to be affected by both adverse and favorable tilts for the given compressor. And depending on the distribution of liquid in the system upon startup, markedly different performance can result for the same system settings and heat loads.

Polymers are one of the major constituents in electrical components. A study investigating pre-combustion off-gassing and particle release by polymeric materials over a range of temperatures can provide an understanding of thermal degradation prior to failure which may result in a fire hazard. In this work, we report simultaneous measurements of pre-combustion vapor and particle release by heated polymeric materials. The polymer materials considered for the current study are silicone and Kapton. The polymer samples were heated over the range 20 to 400°C. Response to vapor releases were recorded using the JPL Electronic Nose (ENose) and Industrial Scientific's ITX gas monitor configured to detect hydrogen chloride (HCl), carbon monoxide (CO) and hydrogen cyanide (HCN). Particle release was monitored using a TSI P-TRAK particle counter.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

The NASA-wide CEV Smart Buyer Team (SBT) was assembled in January 2006 and was tasked with the development of a NASA in-house design for the CEV Crew Module (CM), Service Module (SM), and Launch Abort System (LAS). This effort drew upon over 250 engineers from all of the 10 NASA Centers. In 6 weeks, this in-house design was developed. The Thermal Systems Team was responsible for the definition of the active and passive design architecture. The SBT effort for Thermal Systems can be best characterized as a design architecting activity. Proof-of-concepts were assessed through system-level trade studies and analyses using simplified modeling. This nimble design approach permitted definition of a point design and assessing its design robustness in a timely fashion. This paper will describe the architecting process and present trade studies and proposed thermal designs

An EVA simulation with a medical contingency scenario was conducted in 2006 with the NASA Haughton-Mars and EVA Physiology System and Performance Projects, to develop medical contingency management and evacuation techniques for planetary surface exploration. A rescue/evacuation system to allow two rescuer astronauts to evacuate one incapacitated astronaut was evaluated. The rescue system was utilized effectively to extract an injured astronaut up a slope of15-25° and into a surface mobility rover for transport to a simulated habitat for advanced medical care. Further research is recommended to evaluate the effects of reduced gravity and to develop synergies with other surface systems for carrying out the contingency procedures.

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.

Phoenix is NASA's first Mars Scouts Mission that will place a soft-lander on the Martian surface at a high northern latitude. Much of the Mars surface environmental flight data from landed missions pertains to the near-equatorial regions. However, orbital observations have yielded very useful data about the surface environment. These data along with a simple, but highly effective one-dimensional atmospheric model was used to develop the Phoenix surface thermal environment. As candidate landing sites were identified, parametric studies including statistical variations were conducted to prescribe minimum nighttime and maximum daytime temperature design Sols (a Martian day). Atmospheric effects such as clouds and ice were considered. Finally, recent candidate landing site imaging conducted by the Mars Reconnaissance Orbiter revealed that the prime site contained a much higher rock density than first thought.

Providing water necessary to maintain life support has been accomplished in spacecraft vehicles for over forty years. This paper will investigate how previous U.S. space vehicles provided potable water. The water source for the spacecraft, biocide used to preserve the water on-orbit, water stowage methodology, materials, pumping mechanisms, on-orbit water requirements, and water temperature requirements will be discussed. Where available, the hardware used to provide the water and the general function of that hardware will also be detailed. The Crew Exploration Vehicle (CEV or Orion) water systems will be generically discussed to provide a glimpse of how similar they are to water systems in previous vehicles. Conclusions, questions, and recommendations on strategies that could be applied to CEV based on previous spacecraft water system lessons learned will be made.

As part of preparing for the Crew Exploration Vehicle (CEV), the National Aeronautics and Space Administration (NASA) worked on developing the requirements to manage the fire risk. The new CEV poses unique challenges to current fire protection systems. The size and configuration of the vehicle resembles the Apollo capsule instead of the current Space Shuttle or the International Space Station. The smaller free air volume and fully cold plated avionic bays of the CEV requires a different approach in fire protection than the ones currently utilized. The fire protection approach discussed in this paper incorporates historical lessons learned and fire detection and suppression system design philosophy spanning from Apollo to the International Space Station.

Work is underway to deliver an instrument for analysis of the atmosphere aboard the International Space Station. The Vehicle Cabin Atmosphere Monitor (VCAM) is based on a low-mass, low-power miniature preconcentrator gas chromatograph/mass spectrometer (PCGC/MS) capable of providing sub-ppm measurements of volatile constituents in a space vehicle or outpost. VCAM is designed to operate autonomously, maintenance-free, once per day, with its own carrier and calibration gas supplies sufficient for a one-year lifetime. VCAM performance is sufficient to detect and identify 90% of the target compounds specified at their 180-day Spacecraft Maximum Allowable Concentration (SMAC) levels. The flight units will be delivered in mid-2008 and be operated in the ISS EXPRESS rack.

To meet the challenge of future deep space programs an accurate and efficient engineering code for analyzing the shielding requirements against high-energy galactic heavy radiations is needed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. In consequence, a new version of the HZETRN code capable of simulating HZE ions with either laboratory or space boundary conditions is currently under development. The new code, GRNTRN, is based on a Green's function approach to the solution of Boltzmann's transport equation and like its predecessor is deterministic in nature. Code validation in the laboratory environment is addressed by showing that GRNTRN accurately predicts energy loss spectra as measured by solid-state detectors in ion beam experiments.

Protecting astronauts from space radiation exposure is an important challenge for mission design and operations for future exploration-class and long-duration missions. Crew members are exposed to sporadic solar particle events (SPEs) as well as to the continuous galactic cosmic radiation (GCR). If sufficient protection is not provided the radiation risk to crew members from SPEs could be significant. To improve exposure risk estimates and radiation protection from SPEs, detailed evaluations of radiation shielding properties are required. A model using a modern CAD tool ProE™, which is the leading engineering design platform at NASA, has been developed for this purpose. For the calculation of radiation exposure at a specific site, the cosine distribution was implemented to replicate the omnidirectional characteristic of the 4π particle flux on a surface.

A system of amine-based carbon dioxide (CO2) and water vapor sorbent in pressure-swing regenerable beds has been developed by Hamilton Sundstrand and is baselined for the Orion Atmosphere Revitalization System (ARS). In two previous years at this conference, reports were presented on extensive Johnson Space Center (JSC) testing of the technology, which was performed in a representative environment with simulated human metabolic loads. The next step in developmental testing at JSC was to use real human loads in the spring of 2008.

In the design of a new space suit it is necessary to have requirements that define what mobility space suit joints should be capable of achieving in both a system and at the component level. NASA elected to divide mobility into its constituent parts -- range of motion (ROM) and torque -- in an effort to develop clean design requirements that limit subject performance bias and are easily verified. Unfortunately, the measurement of mobility can be difficult to obtain. Current technologies, such as the Vicon motion capture system, allow for the relatively easy benchmarking of range of motion (ROM) for a wide array of space suit systems. The ROM evaluations require subjects in the suit to accurately evaluate the ranges humans can achieve in the suit. However, when it comes to torque, there are significant challenges for both benchmarking current performance and writing requirements for future suits.

This paper describes the need for dynamic (transient) simulation of automotive air conditioning systems, the reasons why such simulations are challenging, and the applicability of a general purpose off-the-shelf thermohydraulic analyzer to answer such challenges. An overview of modeling methods for the basic components are presented, along with relevant approximations and their effect on speed and accuracy of the results.

The 2001 Mars Odyssey spacecraft Martian Radiation Environment Experiment (MARIE) is a solid-state silicon telescope high-energy particle detector designed to measure galactic cosmic radiation (GCR) and solar particle events (SPEs) in the 20 – 500 MeV/nucleon energy range. In this paper we discuss the instrument design and focus on the observations and measurements of SPEs at Mars. These are the first-ever SPE measurements at Mars. The measurements are compared with the geostationary GOES satellite SPE measurements. We also discuss some of the current interplanetary particle propagation and diffusion theories and models. The MARIE SPE measurements are compared with these existing models.

As shielding materials are developed for protection against the hazards of galactic cosmic rays, it is desirable to develop a protocol for rapid assessment of shielding properties. Solid state energy loss detectors are often used to estimate the charge and energy of particles in ion beam experiments. The direct measurement is energy deposited in the detector. As a means of separating the charge components in typical shield transmission studies with observation, a stack of many such detectors is used. With high-energy beams and thin targets, surviving primaries and fragments emerging from the target have nearly-equal velocities and deposited energy scales with the square of the charge, simplifying the data analysis. The development of a transport model for the shield and detector arrangement and evaluation of prediction of the energy loss spectrum for direct comparison with the experimentally derived data allows a rapid assessment of the shield transmission characteristics.

The International Space Station (ISS) Active Thermal Control System (ATCS) (Ref. 1,2) has changed over the past several years to address problems and to improve its assembly and operation on-orbit. This paper captures the ways in which the Internal (I) ATCS and External (E) ATCS have changed design characteristics and operations both for the system currently operating on-orbit and the new elements of the system that are about to be added and/or activated. The rationale for changes in ATCS design, assembly and operation will provide insights into the lessons learned during ATCS development. The state of the assembly of the integrated ATCS will be presented to provide a status of the build-up of the system. The capabilities of the on-orbit system will be presented with a summary of the elements of the ISS ATCS that are functional on-orbit plus the plans for launch of remaining parts of the integrated ISS ATCS.