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Technical Paper

Low Frequency Impedance Spectroscopy – Modeling Study on the Transferability of Solid Diffusion Coefficients

2023-04-11
2023-01-0505
This work elaborates the transferability of electrode diffusion coefficients gained from fitting procedures in frequency domain to an electrochemical battery model run in time domain. An electrochemical battery model of an NMC622 half-cell electrode is simulated with sinusoidal current excitations at different frequencies. The current and voltage signals are analyzed in frequency domain via Nyquist and Bode plots. The frequency domain analysis of time domain simulations is applied to assess the numerical convergence of the simulation and the sensitivity on particle diameter, electrode and electrolyte diffusion coefficients. The simulated frequency spectra are used to fit the electrode diffusion coefficient by means of different electrical equivalent circuit models and the electrochemical battery model itself. The fitted diffusion coefficients from the different electrical equivalent circuit models deviate by one order of magnitude from the a priori known reference data.
Technical Paper

An Application of the Linear and Time-Invariant Method for the System-Level Thermal Simulation of an EV Battery

2015-04-14
2015-01-1197
This paper presents a system-level thermal model of a fluid-cooled Li-Ion battery module. The model is a reduced order model (ROM) identified by results from finite element analysis (FEA)/computational fluid dynamic (CFD) coupling simulation using the linear and time-invariant (LTI) method. The ROM consists of two LTI sub-systems: one of which describes the battery temperature response to a transient battery current, and the other of which takes into account of the battery temperature variation due to a heat flux induced by a varied inlet temperature of the battery cooling circuit. The thermal LTI model can be coupled to an electrical model to build a complete system-level battery ROM. Test examples show that the ROM is able to provide as accurate results as those from FEA/CFD coupling simulations.
Technical Paper

Modeling of the System Level Electric Drive using Efficiency Maps Obtained by Simulation Methods

2014-04-01
2014-01-1875
This work presents a physical model that calculates the efficiency maps of the inverter-fed Permanent Magnet Synchronous Machine (PMSM) drive. The corresponding electrical machine and its controller are implemented based on the two-phase (d-q) equivalent circuits that take into account the copper loss as well as the iron loss of the PMSM. A control strategy that optimizes the machine efficiency is applied in the controller to maximize the possible output torque. In addition, the model applies an analytical method to predict the losses of the voltage source inverter. Consequently, the efficiency maps within the entire operating region of the PMSM drive can be derived from the simulation results, and they are used to represent electric drives in the system simulation model of electric vehicles (EVs).
Technical Paper

Parameterization of an Electrochemical Battery Model Using Impedance Spectroscopy in a Wide Range of Frequency

2024-04-09
2024-01-2194
The parameterization of the electrochemical pseudo-two-dimensional (P2D) model plays an important role as it determines the acceptance and application range of subsequent simulation studies. Electrochemical impedance spectroscopy (EIS) is commonly applied to characterize batteries and to obtain the exchange current density and the solid diffusion coefficient of a given electrode material. EIS measurements performed with frequencies ranging from 1 MHz down to 10 mHz typically do not cover clearly isolated solid state diffusion processes of lithium ions in positive or negative electrode materials. To extend the frequency range down to 10 μHz, the distribution function of relaxation times (DRT) is a promising analysis method. It can be applied to time-domain measurements where the battery is excited by a current pulse and relaxed for a certain period.
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