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Fuel injection during negative valve overlap offers a promising method of controlling HCCI combustion, but sorting out the thermal and chemical effects of NVO fueling requires knowledge of temperatures throughout the cycle. Computing bulk temperatures throughout closed portions of the cycle is relatively straightforward using an equation of state, once a temperature at one crank angle is established. Unfortunately, computing charge temperatures at intake valve closing for NVO operation is complicated by a large, unknown fraction of residual gases at unknown temperature. To address the problem, we model blowdown and recompression during exhaust valve opening and closing events, allowing us to estimate in-cylinder charge temperatures based on exhaust-port measurements. This algorithm permits subsequent calculation of crank-angle-resolved bulk temperatures and residual gas fraction over a wide range of NVO operation.

Piston-wetting effects are investigated in an optical direct-injection spark-ignition (DISI) engine. Fuel spray impingement on the piston leads to the formation of fuel films, which are visualized with a laser-induced fluorescence (LIF) imaging technique. Oxygen quenching is found to reduce the fluorescence yield from liquid gasoline. Fuel films that exist during combustion of the premixed charge ignite to create piston-top pool fires. These fires are characterized using direct flame imaging. Soot produced by the pool fires is imaged using laser elastic scattering and is found to persist throughout the exhaust stroke, implying that piston-top pool fires are a likely source of engine-out particulate emissions for DISI engines.

Optical engines are often skip-fired to maintain optical components at acceptable temperatures and to reduce window fouling. Although many different skip-fired sequences are possible, if exhaust emissions data are required, the skip-firing sequence ought to consist of a single fired cycle followed by a series of motored cycles (referred to here as singleton skip-firing). This paper compares a singleton skip-firing sequence with continuous firing at the same inlet conditions, and shows that combustion performance trends with equivalence ratio are similar. However, as expected, reactant temperatures are lower with skip-firing, resulting in retarded combustion phasing, and lower pressures and combustion efficiency. LIF practitioners often employ a homogeneous charge of known composition to create calibration images for converting raw signal to equivalence ratio.

This paper proposes a method for quantitatively predicting emissions from a homogeneous-charge compression-ignition (HCCI) engine using laser-induced fluorescence (LIF) imaging of the in-cylinder fuel distribution. The prediction scheme, which is applied to stratified operation, is based on the premise that local fuel-air packets at a given equivalence ratio burn as if in an isolated homogeneous mixture at the same equivalence ratio. Insofar as the premise holds true, the emissions produced by each packet can be predicted using a look-up table of exhaust emission values measured during homogeneous operation. LIF images of fuel distribution during stratified operation are reduced to probability density functions (PDF) that, together with the look-up tables, allow prediction of engine-out emissions. Despite the simplifications associated with the prediction scheme, predicted values of CO2, CO and HC emissions each agree to within 15% of total fuel carbon for low-load operation.

Frequent use is made of planar laser-induced fluorescence (LIF) to quantify in-cylinder fuel-air mixing in optical engines. This diagnostic typically relies on one or more fluorescent tracers mixed with a non-fluorescing fuel. An important consideration is the evaporation behavior of the fuel-tracer mixture: the liquid fuel and tracer must co-evaporate so that the tracer can properly track fuel molecules in the vapor phase. Previous work matched tracers to fuels frequently used in direct-injection, spark-ignition research engines. The goal of the current research is to identify appropriate LIF tracers for the primary reference fuels (PRF) commonly used in homogeneous-charge, compression-ignition (HCCI) research engines. A bench-top evaporation experiment characterizes the evaporation of four selected tracers blended with a range of PRF fuels with octane numbers from 0 to 100.

Our previous work applied LIF measurements of in-cylinder fuel distribution to predict CO2, CO, and HC emissions from an HCCI engine under low-load stratified-charge conditions. The prediction method is based on the premise that local fuel-air packets at a given equivalence ratio (characterized using LIF imaging) burn as if in a homogeneous charge at the same equivalence ratio. Thus, emissions measured during homogeneous operation provide an emission-versus- equivalence-ratio look-up table for predicting stratified-charge emissions. The present paper extends the technique to predict engine-out NOX emissions. Because of operating-range limitations, NOX look-up data for homogeneous operation cannot adequately be determined by experiment. Instead, a CHEMKIN-based model provides this look-up table data instead.