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Journal Article

A Simple Method to Predict Knock Using Toluene, N-Heptane and Iso-Octane Blends (TPRF) as Gasoline Surrogates

2015-04-14
2015-01-0757
The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.
Technical Paper

Simultaneous Negative PLIF and OH* Chemiluminescence Imaging of the Gas Exchange and Flame Jet from a Narrow Throat Pre-Chamber

2020-09-15
2020-01-2080
Pre-chamber combustion (PCC) is a promising engine combustion concept capable of extending the lean limit at part load. The engine experiments in the literature showed that the PCC could achieve higher engine thermal efficiency and much lower NOx emission than the spark-ignition engine. Improved understanding of the detailed flow and combustion physics of PCC is important for optimizing the PCC combustion. In this study, we investigated the gas exchange and flame jet from a narrow throat pre-chamber (PC) by only fueling the PC with methane in an optical engine. Simultaneous negative acetone planar laser-induced fluorescence (PLIF) imaging and OH* chemiluminescence imaging were applied to visualize the PC jet and flame jet from the PC, respectively. Results indicate a delay of the PC gas exchange relative to the built-up of the pressure difference (△ P) between PC and the main chamber (MC). This should be due to the gas inertia inside the PC and the resistance of the PC nozzle.
Technical Paper

High-Speed Imaging of Main-Chamber Combustion of a Narrow Throat Pre-Chamber under Lean Conditions

2020-09-15
2020-01-2081
Pre-chamber combustion (PCC) allows an extension on the lean limit of an internal combustion engine (ICE). This combustion mode provides lower NOx emissions and shorter combustion durations that lead to a higher indicated efficiency. In the present work, a narrow throat pre-chamber was tested, which has a unique nozzle area distribution in two rows of six nozzle holes each. Tests were carried out in a modified heavy-duty engine for optical visualization. Methane was used as fuel for both the pre-chamber and the main chamber. Seven operating points were tested, including passive pre-chamber mode as a limit condition, to study the effect of pre- and main-chamber fuel addition on the pre-chamber jets and the main chamber combustion via chemiluminescence imaging. A typical cycle of one of the tested conditions is explained through the captured images. Observations of the typical cycle reveal a predominant presence of only six jets (from the lower row), with well-defined jet structures.
Technical Paper

A Demonstration of High Efficiency, High Reactivity Gasoline Compression Ignition Fuel in an On & Off Road Diesel Engine Application

2020-04-14
2020-01-1311
The regulatory requirements to reduce both greenhouse gases and exhaust gas pollutants from heavy duty engines are driving new perspectives on the interaction between fuels and engines. Fuels that reliefs the burden on engine manufacturers to reach these goals are of particular interest. A low carbon fuel with a higher volatility and heating value than diesel is one such fuel that reduces engine-out emissions and carbon footprint from the entire hydrocarbon lifecycle (well-to-wheel) and improves fuel efficiency, which is a main enabler for gasoline compression ignition (GCI) technology. The present study investigated the potential of GCI technology by evaluating the performance of a low carbon high efficiency, high reactivity gasoline fuel in Doosan’s 6L medium duty diesel engine.
Technical Paper

Auto-ignition and Anti-Knock Evaluation of Dicyclopentadiene-PRF and TPRF Blends

2021-09-21
2021-01-1160
The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels.
Technical Paper

Development of Fast Idle Catalyst Light-Off Strategy for Gasoline Compression Ignition Engine - Part 2

2020-04-14
2020-01-0314
The present investigation expands on our previous work on development of fast idle catalyst light-off strategy for a light duty gasoline compression ignition (GCI) engine. In part 1, the steady state experimental investigation in a single cylinder GCI engine indicate an optimum strategy for effective catalyst light off during cold start fast idle operation. According to this strategy, the strategy includes (1) dispersing a first fuel injection during the intake stroke, (2) dispersing a second fuel injection during the expansion stroke, and (3) igniting a spark during the expansion stroke. This strategy increases the exhaust temperature during cold starts thereby assisting in lighting the oxidation catalyst, and reduce emissions and provide greater combustion stability as compared to other injection and spark strategies.
Technical Paper

Development of Fast Idle Catalyst Light-Off Strategy for Gasoline Compression Ignition Engine - Part 1

2020-04-14
2020-01-0316
The present investigation pertains to the development of fast idle catalyst light-off strategy for a light duty gasoline compression ignition (GCI) engine. The engine cold start fast idle operation poses a problem of increased criteria emissions if the catalyst is not activated during the warm up period. Therefore, a control strategy is proposed here to minimize the criteria pollutants during the fast idle phase via enabling fast catalyst light off in a GCI engine and relying on the spark ignition of a globally stoichiometric fuel air mixture. The engine has unique design features such as certain geometry configuration between spark plug and fuel injector arrangement, and the location of spark plug in a high compression ratio (CR) diesel-like combustion chamber. The experiments were performed in a single cylinder GCI engine at cold start fast idle conditions using certification gasoline fuel (RON 91).
Technical Paper

Experimental Investigation of the Compression Ignition Process of High Reactivity Gasoline Fuels and E10 Certification Gasoline using a High-Pressure Direct Injection Gasoline Injector

2020-04-14
2020-01-0323
Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.
Technical Paper

Impact of Drag Reducing Agents on Gasoline Engine Deposits

2021-09-21
2021-01-1185
Drag reducing agents (DRAs) are extensively used to increase the capacity of pipelines to transport crude oils and finished products. The amount of DRA that can be used in gasoline is limited by the tendency of the high molecular weight DRAs to form engine deposits. The use of deposit control additives (DCAs) could help to mitigate this effect, enabling increased DRA treatment rates and improved pipeline capacity. A study has been undertaken to investigate the engine test response of these additives, and has suggested that higher DRA treat rates may be possible when accompanied by a deposit control additive to address increased intake valve deposits. Conversely, the effect on combustion chamber deposits is not clear and further studies would be required. Other engine related aspects such as intake valve deposit stick have also been investigated and under the conditions tested do not appear to be adversely affected by either the DRA or the deposit control additive.
Journal Article

Investigation into Light Duty Dieseline Fuelled Partially-Premixed Compression Ignition Engine

2011-04-12
2011-01-1411
Conventional diesel-fuelled Partially Premixed Compression Ignition (PPCI) engines have been investigated by many researchers previously. However, the ease of ignition and difficulty of vaporization of diesel fuel make it imperfect for PPCI combustion. In this study, dieseline (blending of diesel and gasoline) was looked into as the Partially Premixed Compression Ignition fuel for its combination of two fuel properties, ignition-delay-increasing characteristics and higher volatility, which make it more suitable for PPCI combustion compared to neat diesel. A series of tests were carried out on a Euro IV light-duty common-rail diesel engine, and different engine modes, from low speed/load to middle speed/load were all tested, under which fuel blend ratios, EGR rates, injection timings and quantities were varied. The emissions, fuel consumption and combustion stability of this dieseline-fuelled PPCI combustion were all investigated.
Journal Article

Vehicle Demonstration of Naphtha Fuel Achieving Both High Efficiency and Drivability with EURO6 Engine-Out NOx Emission

2013-04-08
2013-01-0267
Demand for transport energy is growing but this growth is skewed heavily toward commercial transport, such as, heavy road, aviation, marine and rail which uses heavier fuels like diesel and kerosene. This is likely to lead to an abundance and easy availability of lighter fractions like naphtha, which is the product of the initial distillation of crude oil. Naphtha will also require lower energy to produce and hence will have a lower CO₂ impact compared to diesel or gasoline. It would be desirable to develop engine combustion systems that could run on naphtha. Many recent studies have shown that running compression ignition engines on very low Cetane fuels, which are very similar to naphtha in their auto-ignition behavior, offers the prospect of developing very efficient, clean, simple and cheap engine combustion systems. Significant development work would be required before such systems could power practical vehicles.
Journal Article

Fuel Effects on Knock in a Highly Boosted Direct Injection Spark Ignition Engine

2012-09-10
2012-01-1634
Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.
Journal Article

Butanol Blending - a Promising Approach to Enhance the Thermodynamic Potential of Gasoline - Part 1

2011-08-30
2011-01-1990
Blending gasoline with oxygenates like ethanol, MTBE or ETBE has a proven potential to increase the thermodynamic efficiency by enhancing knock resistance. The present research focuses on assessing the capability of a 2- and tert-butanol mixture as a possible alternative to state-of-the-art oxygenates. The butanol mixture was blended into a non-oxygenated reference gasoline with a research octane number (RON) of 97. The butanol blending ratios were 15% and 30% by mass. Both the thermodynamic potential and the impact on emissions were investigated. Tests are performed on a highly boosted single-cylinder gasoline engine with high load capability and a direct injecting fuel system using a solenoid-actuated multi-hole injector. The engine is equipped with both intake and exhaust cam phasers. The engine has been chosen for the fuel investigation, as it represents the SI technology with a strongly increasing market share.
Journal Article

An Alternative Method Based on Toluene/n-Heptane Surrogate Fuels for Rating the Anti-Knock Quality of Practical Gasolines

2014-10-13
2014-01-2609
As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.
Journal Article

Compression Ratio and Derived Cetane Number Effects on Gasoline Compression Ignition Engine Running with Naphtha Fuels

2014-04-01
2014-01-1301
In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).
Technical Paper

Modeling of Heating and Evaporation of FACE I Gasoline Fuel and its Surrogates

2016-04-05
2016-01-0878
The US Department of Energy has formulated different gasoline fuels called ''Fuels for Advanced Combustion Engines (FACE)'' to standardize their compositions. FACE I is a low octane number gasoline fuel with research octane number (RON) of approximately 70. The detailed hydrocarbon analysis (DHA) of FACE I shows that it contains 33 components. This large number of components cannot be handled in fuel spray simulation where thousands of droplets are directly injected in combustion chamber. These droplets are to be heated, broken-up, collided and evaporated simultaneously. Heating and evaporation of single droplet FACE I fuel was investigated. The heating and evaporation model accounts for the effects of finite thermal conductivity, finite liquid diffusivity and recirculation inside the droplet, referred to as the effective thermal conductivity/effective diffusivity (ETC/ED) model.
Technical Paper

Some Insights on the Stochastic Nature of Knock and the Evolution of Hot Spots in the End-Gas During the Engine Cycle from Experimental Measurements of Knock Onset and Knock Intensity

2017-10-08
2017-01-2233
Knock in spark ignition engines is stochastic in nature. It is caused by autoignition in hot spots in the unburned end-gas ahead of the expanding flame front. Knock onset in an engine cycle can be predicted using the Livengood-Wu integral if the variation of ignition delay with pressure and temperature as well as the pressure and temperature variation with crank angle are known. However, knock intensity (KI) is determined by the evolution of the pressure wave following knock onset. In an earlier paper (SAE 2017-01-0689) we showed that KI can be approximated by KI = Z (∂T/∂x)-2 at a fixed operating condition, where Z is a function of Pko, the pressure, and (∂T/∂x) is the temperature gradient in the hot spot at knock onset. Then, from experimental measurements of KI and Pko, using five different fuels, with the engine operating at boosted conditions, a probability density function for (∂T/∂x) was established.
Technical Paper

Blending Octane Number of Ethanol on a Volume and Molar Basis in SI and HCCI Combustion Modes

2017-10-08
2017-01-2256
The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.
Technical Paper

Combustion Optimization of a Multi-Cylinder CI Engine Running with a Low RON Gasoline Fuel Considering Different Air Loop and After-Treatment Configurations

2017-10-08
2017-01-2264
Recent work has demonstrated the potential of gasoline-like fuels to reduce NOx and particulate emissions when used in compression ignition engines. In this context, low research octane number (RON) gasoline, a refinery stream derived from the atmospheric crude oil distillation process, has been identified as a highly valuable fuel. In addition, thanks to its higher H/C ratio and energy content compared to diesel, CO2 benefits are also expected when used in such engines. In previous studies, different cetane number (CN) fuels have been evaluated and a CN 35 fuel has been selected. The assessment and the choice of the required engine hardware adapted to this fuel, such as the compression ratio, bowl pattern and nozzle design have been performed on a single cylinder compression-ignition engine.
Technical Paper

Improving the Efficiency of Conventional Spark-Ignition Engines Using Octane-on-Demand Combustion - Part II: Vehicle Studies and Life Cycle Assessment

2016-04-05
2016-01-0683
This paper is the second of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This second study focuses on drive cycle simulations and Life Cycle Assessment (LCA) for vehicles equipped with Octane-on-Demand combustion. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. The experimental engine calibration maps developed in the previous study are first provided as inputs to a drive cycle simulation tool. This is used to quantify the total fuel consumption, octane requirement and tank-to-wheel CO2 emissions for a light-duty vehicle equipped with two alternative powertrain configurations. The properties of the lower octane fuel are shown to affect the vehicle fuel consumption and CO2 emissions significantly.
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