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Condensation of fuel vapor on the cold surfaces within the combustion chamber is investigated as a possible mechanism for increased HC emissions from SI engines during cold start. A one-dimensional, transient, mass diffusion analysis is used to examine the condensation of single-species fuels on the surfaces of the combustion chamber as the pressure within the cylinder rises during compression and combustion, and re-vaporization during expansion, blowdown, and exhaust. The effects of wall temperature, fuel volatility, and engine load and speed on this mechanism are also discussed. This analysis shows that low-volatility fuel components can condense on the surfaces of the combustion chamber when the surface temperatures are sufficiently low. This condensed fuel may re-vaporize during the power and exhaust strokes, or it may remain in the combustion chamber until surface temperatures rise, perhaps tens of seconds later.