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In the present study, we developed a reduced TRF-PAH chemical reaction mechanism consisted of iso-octane, n-heptane and toluene as gasoline surrogate fuels for GDI (gasoline direct injection) spark ignition engine combustion simulation. The reduced mechanism consists of 85 species and 232 reactions including 17 species and 40 reactions related to the PAHs (polycyclic aromatic hydrocarbons) formation. The present mechanism was validated for extensive validations with experimental ignition delay times in shock tubes and laminar flame speeds in flat flame adiabatic burner for gasoline/air and TRF/air mixtures under various pressures, temperatures and equivalence ratios related to engine conditions. Good agreement was achieved for most of the measurement. Mole fraction profiles of PAHs for n-heptane flame were also simulated and the experimental trends were reproduced well. The vapor-phase and particulate-bound PAHs existed in GDI engine exhaust were sampled and analyzed by GC-MS.

This research presents an experimental study of the laminar burning combustion and emission characteristics of premixed methane -dissociated methanol-air mixtures in a constant volume combustion chamber. All experiments were conducted at 3 bar initial pressure and 373K initial temperature. The dissociated methanol fractions were from 20% to 80% with 20% intervals, and the equivalence ratio varied from 0.6 to 1.8 with 0.2 intervals. The images of flame propagation were visualized by using a schlieren system. The combustion pressure data were measured and exhaust emissions were sampled with a portable exhaust gas analyzer. The results show that the unstretched laminar burning velocities increased significantly with dissociated methanol enrichment. The Markstein length decreased with increasing dissociated methanol fraction and decreasing equivalence ratio.