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According to the requirements of two-wheel vehicle's future market and the characteristic of urban road conditions in China, the advantages and disadvantages of three basic configurations for the Hybrid Electric Vehicle are compared, finally, the serial hybrid configuration is chosen to be applied to hybrid Electric Moped solution. The selection principle of main components of this hybrid powertrain system includes ICE, generator, battery and hub motor, and the optimal match for performance parameters of these components are introduced in this paper. Then, a hybrid system model is established based on AVL-CRUISE. The simulations of fuel efficiency and exhaust emissions for both serial hybrid moped and conventional motorcycle is offered.