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Startup from subzero temperature is one of the major challenges for polymer electrolyte membrane fuel cell (PEMFC) to realize commercialization. Below the freezing point (0°C), water will freeze easily, which blocks the reactant gases into the reaction sites, thus leading to the start failure and material degradation. Therefore, for PEMFC in vehicle application, finding suitable ways to reach successful startup from subfreezing environment is a prerequisite. As it’s difficult and complex for experimental studies to measure the internal quantities, mathematical models are the effective ways to study the detailed transport process and physical phenomenon, which make it possible to achieve detailed prediction of the inner life of the cell. However, review papers only on cold start numerical models are not available. In this study, an extensive review on cold start models is summarized featuring the states and phase changes of water, heat and mass transfer.

As turbulence modeling has become an indispensable approach to perform flow simulation in a wide range of industrial applications, how to enhance the prediction accuracy has gained increasing attention during the past years. Of all the turbulence models, RANS is the most common choice for many OEMs due to its short turn-around time and strong robustness. However, the default setting of RANS is usually benchmarked through classical and well-studied engineering examples, not always suitable for resolving complex flows in specific circumstances. Many previous researches have suggested a small tuning in turbulence model coefficients could achieve higher accuracy on a variety of flow scenarios. Instead of adjusting parameters by trial and error from experience, this paper introduced a new data-driven method of turbulence model recalibration using adjoint solver, based on Generalized k-ω (GEKO) model, one variant of RANS.

Cold start remains a major obstacle to the commercialization of proton exchange membrane fuel cell (PEMFC), however, there are few studies on the cold start characteristics, especially at a complicated stack level. In this study, a novel layer-lumped numerical model with higher computational efficiency is proposed to investigate the cold start behavior of PEMFC stack, in which phase transition, heat transfer and electrochemical reaction are comprehensively considered. Besides, phase transition mechanisms are reconstructed based on the assumption that super-cooled water exists within the cell. With this model, the inconsistency of the stack temperature distribution and output performance is presented, some constant loading voltage strategies are investigated, and a linear variable controlling voltage strategy is developed.