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Technical Paper

Exhaust Gas Sensor with High Water Splash Resistant Layer for Lower Emission

2020-04-14
2020-01-0565
Increasingly stringent regulations call for the reduction of emissions at engine startup to purify exhaust gas and reduce the amount of CO2 emitted. Air-fuel ratio (A/F) sensors detect the composition of exhaust gas and provide feedback to control the fuel injection quantity in order to ensure the optimal functioning of the catalytic converter. Reducing the time needed to obtain feedback control and enabling the restriction-free installation of A/F sensors can help meet regulations. Conventional sensors do not activate feedback control immediately after engine startup as the combination of high temperatures and splashes of condensed water in the exhaust pipe can cause thermal shock to the sensor element. Moreover, sensors need to be installed near the engine to increase the catalyst reaction efficiency. This increases the possibility of water splash from the condensed water in the catalyst.
Technical Paper

Low-Emission and Fuel-Efficient Exhaust System with New Air-Fuel Ratio Sensor

2020-04-14
2020-01-0655
This paper describes an exhaust system using a new air-fuel ratio (hereinafter, A/F) sensor that contributes to low emissions and low fuel consumption of gasoline engines. As the first technical feature, the water splash resistance of the A/F sensor has been substantially improved which allows A/F control to be enabled without delay during engine cold start. To realize this capability, it is important that the sensor characteristics are not affected by the condensed water generated in the exhaust pipe. Therefore, a technique that has the effectiveness of a water splash resistance layer with water repellent function is demonstrated. As the second technical feature, the power consumption of the sensor has been substantially reduced. This is achieved by improving thermal efficiency of the sensor that the element can be activated at a low temperature.
Journal Article

Calibration and Validation of a Diesel Oxidation Catalyst Model: from Synthetic Gas Testing to Driving Cycle Applications

2011-04-12
2011-01-1244
To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.
Technical Paper

Nano Particle Emission Evaluation of State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI) and Fuel Qualities Effects (EtOH, ETBE, FAME, Aromatics and Distillation)

2007-10-29
2007-01-4083
Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Performance of Two/Four Stroke Gasoline HCCI Engine with Electromagnetic Valve Train

2007-07-23
2007-01-1868
Comparison of net thermal efficiency and emission in two and four stroke gasoline HCCI engine has been carried out for various valve-timings as negative valve overlap and exhaust valve double opening. The valve timings could easily be converted from a mode to another by configuring schedule of electromagnetic valve-train. Extension of operable torque with high thermal efficiency had been expected in two-stroke HCCI operation, however friction and supercharger loss curtailed about half of the gain in indicated thermal efficiency. In four-stroke operation modes, exhaust valve double opening (‘reinduction’ or ‘rebreathing’) showed the best net thermal efficiency and emission, however the extension of high load limit could not be achieved considerably.
Technical Paper

Study of a Two-Degree-of-Freedom Exhaust System

1990-02-01
900164
An investigation was conducted into pressure pulsation in the exhaust port, which greatly affects volumetric efficiency and engine performance. From experiments using a single blow-down generator, it was established that the amplitude of the pressure pulsation increases as the manifold branch is lengthened and that large negative pressure synchronized with the timing of valve overlap can be obtained if a proper branch length is used. The performance of a 2ℓ test engine was optimized by varying the length of both the manifold branches and front pipe forks. It was found that whereas front pipe fork length affects engine performance over only a narrow range of engine speed, optimizing manifold branch length results in a considerable improvement over a wide engine speed range. In the course of optimizing the exhaust pipe manifold length of this two-degree-of-freedom exhaust system, abnormal exhaust noises were emitted at specific engine speeds during deceleration.
Technical Paper

Development of Robust Design Method in Pedestrian Impact Test

2007-04-16
2007-01-0881
This paper describes that a method has been developed to estimate the range of the scatter of Head Injury Criterion (HIC) values in pedestrian impact tests, which could help to reduce the range of the scatter of HIC values by applying the stochastic method for Finite Element (FE) analysis. A major advantage of this method is that it enables the range of scatter of HIC values to be estimated and to explain the mechanics of the behavior. The test procedure of pedestrian impact allows some tolerances for the resultant conditions of impact such that the distance of actual impact location from the selected point is within 10 mm and the impact velocity is within ±0.7 km/h [1]. A HIC value calculated by impact simulation under a deterministic impact condition with the nominal input data does not necessarily represent the variation of measured data in impactor tests.
Technical Paper

Study of Vehicle-to-Vehicle Collision Performance Based on Balance of Front End Strength

2007-04-16
2007-01-1175
Compatibility in vehicles crashes has been studied worldwide in recent years. In cases where primary energy-absorbing structures such as front end members were bypassed in front-to-front collisions, energy-absorbing efficiency declined compared to cases when no such bypassing occurred. A bumper beam that connects the front end members in the transverse direction can help prevent bypassing of primary energy-absorbing structures. The strength balance between front end members and a bumper beam was studied in this paper. It was verified in front-to-front offset vehicle collision tests that crash energy can be efficiently absorbed by balancing the strength of the bumper beam with the compression strength of the front end members.
Technical Paper

Development and Application of an Enhanced SID-IIs Dummy for Analyzing Side Impact Kinematics

2009-04-20
2009-01-1432
Due to the relative high speed and short distance between the door and occupant, side impact presents a challenging task when analyzing the input force from the door to the occupant. The new FMVSS214 Final Rule in 2007 and the new NCAP in 2008 mandated the use of a SID-IIs in the oblique pole impact test and in the rear seat during an MDB side impact test. Therefore, a high-precision measurement and calculation of the three-dimensional dummy kinematics, as well as the interaction of force inside the dummy (internal force) and force exerted from outside the dummy (external force) will help provide efficient evaluation of design requirements for the door trim and supplemental restraint systems that meet legally mandated requirements.
Technical Paper

Development of High Performance Three-Way-Catalyst Technology to Lower NOx Emission

2009-04-20
2009-01-1398
One primary result of the reduction of platinum group metals (PGM) within a catalytic converter is the decline in NOx conversion efficiency. This paper hypothesizes that the primary factor of this decline to be hydrocarbon (HC) poisoning. To maintain high NOx conversion efficiency as the PGM reduces, Rh activation improvement becomes significant to overcome the HC poisoning. Analysis of the Rh deterioration mechanism found that it is effective to separately arrange Rh and CeO2 on the converter, avoiding the Rh deactivation. By this improvement, we improved the catalyst activity at less than 25% of the original Rh loading.
Technical Paper

Analysis of Sophisticated DPNR Catalyst, Focused on PM Particle Number Emissions

2009-04-20
2009-01-0290
Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.
Technical Paper

Impact Study of High Biodiesel Blends on Performance of Exhaust Aftertreatment Systems

2008-10-06
2008-01-2494
Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.
Technical Paper

Development of a New DPNR Catalyst

2004-03-08
2004-01-0578
We, at Toyota, have been working to develop a new DPNR (Diesel Particulate-NOx Reduction) system to decrease both PM and NOx emissions by combining the NOx storage-reduction catalyst for direct injection gasoline engines with the most advanced engine control technologies. The purpose of the DPNR catalyst is to decrease PM and NOx in order to purify automotive exhaust gas. To reduce PM emissions, the PM trapping rate and PM oxidizing performance must be improved. Since the deposition of PM increases the pressure drop across the catalytic converter, it should also be suppressed. To attain these objectives, we have developed a new DPNR catalyst by the adoption of a new porous substrate structure and the improvement of the catalyst coating technique. The new DPNR catalyst will be mounted on the Avensis for commercial use in the European market.
Technical Paper

New Cordierite Diesel Particulate Filter Material for the Diesel Particulate - NOx Reduction System.

2004-03-08
2004-01-0953
The regulation of emissions discharged from diesel engines has become stricter worldwide. The regulatory values allowed for particulate matter (PM) as well as NOx will be lowered, especially in the Europe Euro 5, the U.S. EP 07, and the new Japanese long-term regulations. Since there is a tradeoff between the PM and NOx that are discharged from diesel engines, new emission reduction measures will be needed in order to greatly reduce both at the same time. By coating DPFs (Diesel Particulate Filters), which have been studied before, with NOx storage reduction catalysts, it has been found that simultaneous reduction of PM and NOx is possible, and so research was carried out in order to optimize a DPF for this type of system use. The DPF developed was used in the European DPNR (Diesel Particulate-NOx Reduction System) subject vehicles by Toyota Motor Corporation, and actual trial runs in Europe were performed.
Technical Paper

Joining Technologies for Aluminum Body-Improvement of Self-piercing Riveting

2003-10-27
2003-01-2788
The experimental research vehicle ES3 body was realized by using various aluminum-joining technologies: MIG welding, laser welding, self-piercing riveting. These technologies were applied selectively to make full use of their individual characteristics, according to the body structure and joined materials. Of these technologies, self-piercing riveting is advantageous in several respects. Aiming to expand the application range of riveting technology, we developed a die that prevents cracks in joining aluminum casting, and a method to improve rivet driving in thick, multi-pile portion. We further studied the feasibility of aluminum rivets. This paper outlines the ES3 body structure and it's joining technologies used and introduces the further improvements we developed concerning self-piercing riveting.
Technical Paper

A Study of Car Body Structure to Reduce Environmental Burdens

2003-10-27
2003-01-2833
In the initial design stage, it is important to discuss what kind of body concept is effective from a viewpoint of environment burden reduction. This paper describes the importance of both weight reduction and recycling through conducting LCA (Life Cycle Assessment) for four kinds of body structures. In addition, using each software, DFMA (Design for Manufacture and Assembly), DFE (Design for Environment) and LCA to parts unit, each effectiveness was discussed through the assessment of the material-hybrid body.
Technical Paper

Analysis of FEM Results Based upon FOA

2004-03-08
2004-01-1729
In FOA (First Order Analysis) any vehicle body structure might be interpreted as a collective simple structure that can be decomposed into 3 fundamental structure types. The first structure is the “BEAM”, whose cross sectional properties as well as its material dominates the mechanical behavior, the second is the “PANEL (shear panel, plate, and shell)”, whose mechanical behavior can be varied by changing its geometrical properties in the thickness direction, i.e. adding beads or flanges. The third structure is the “JOINT”, which connects the proceeding structures, and transfer complex three-dimensional loads with three-dimensional deformation. In the present work, we shall propose a methodology to identify a portion of an arbitrary FE model of an automotive body structure, with a “BEAM” structure in the FOA approach. In the latter chapter of this paper, cross section loads will be related with cross sectional properties in the aspect of the element strain energy concept.
Technical Paper

Simultaneous PM and NOx Reduction System for Diesel Engines

2002-03-04
2002-01-0957
A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.
Technical Paper

Experimental and Numerical Analysis for a Urea-SCR Catalytic Converter

2016-04-05
2016-01-0973
Urea-SCR (Selective Catalytic Reduction) systems are getting a lot of attention as the most promising NOx reduction technology for heavy-duty diesel engine exhaust. In order to promote an effective development for an optimal urea-SCR after-treatment system, it is important to clarify the decomposition behavior of the injected urea and a detailed reaction chemistry of the reactants on the catalyst surface in exhaust gases. In this paper we discuss experimental and numerical studies for the development of a numerical simulation model for the urea-SCR catalyst converter. As a first step, in order to clarify the behavior of reductants in an urea-SCR converter, two types of diagnostic technique were developed; one is for measuring the amount of NH3, and the other is for measuring the amount of total reductants including unreacted urea and iso-cyanic acid. These techniques were applied to examine the behavior of reductants at the inlet and inside the SCR converter.
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