Journal Article
Counter-Flow Silica-Titania Reactor for the Simultaneous Treatment of Air and Water Contaminated with VOCs
2009-07-12
2009-01-2524
The photocatalytic oxidation of VOCs was investigated using a novel countercurrent flow reactor designed to enable the treatment of toluene present in the gas and the aqueous phases simultaneously. The reactor was packed with silica-titania composites commingled with plastic pall rings. Using this mixed packing style was advantageous as it resulted in a higher UV penetration throughout the reactor. The average UV intensity in the reactor was determined to be 220 μW/g irradiated TiO2. It was found that under dry conditions, the STCs had a high adsorption capacity for toluene; however, this adsorption was completely hindered by the wetting of the STCs when the two phases were flowing simultaneously. The destruction of toluene in the aqueous phase was determined to follow a linear trend as a function of the contaminant concentration.