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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

A physics based, lumped thermal capacity model of a 1litre, 3 cylinder, turbocharged, directly injected spark ignition engine has been developed to investigate the effects of cylinder deactivation on the thermal behaviour and fuel economy of small capacity, 3 cylinder engines. When one is deactivated, the output of the two firing cylinders is increased by 50%. The largest temperature differences resulting from this are between exhaust ports and between the upper parts of liners of the deactivated cylinder and the adjacent firing cylinder. These differences increase with load. The deactivated cylinder liner cools to near-coolant temperature. Temperatures in the lower engine structure show little response to deactivation. Temperature response times following deactivation or reactivation events are similar. Motoring work for the deactivated cylinder is a minor loss; the net benefit of deactivation diminishes with increasing load.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

The oil distribution system of an automotive light duty engine typically has an oil pump mechanically driven through the front-endancillaries-drive or directly off the crankshaft. Delivery pressure is regulated by a relief valve to provide an oil gallery pressure of typically 3 to 4 bar absolute at fully-warm engine running conditions. Electrification of the oil pump drive is one way to decouple pump delivery from engine speed, but this does not alter the flow distribution between parts of the engine requiring lubrication. Here, the behaviour and benefits of a system with an electrically driven, fixed displacement pump and a distributor providing control over flow to crankshaft main bearings and big end bearings is examined. The aim has been to demonstrate that by controlling flow to these bearings, without changing flow to other parts of the engine, significant reductions in engine friction can be achieved.

Soot formation and distribution inside the cylinder of a light-duty direct injection diesel engine, have been predicted using Kiva-3v CFD software. Pathlines of soot particles traced from specific in-cylinder locations and crank angle instants have been explored using the results for cylinder charge motion predicted by the Kiva-3v code. Pathlines are determined assuming soot particles are massless and follow charge motion. Coagulation and agglomeration have not been taken into account. High rates of soot formation dominate during and just after the injection. Oxidation becomes dominant after the injection has terminated and throughout the power stroke. Computed soot pathlines show that soot particles formed just below the fuel spray axis during the early injection period are more likely to travel to the cylinder wall boundary layer. Soot particles above the fuel spray have lesser tendency to be conveyed to the cylinder wall.

The largest contribution to engine rubbing friction is made by the piston and piston rings running in the cylinder liner. The magnitude and characteristics of the friction behaviour and the influence on these of factors such as surface roughness, piston design and lubricant properties are of keen interest. Investigating presents experimental challenges, including potential problems of uncontrolled build-to-build variability when component changes are made. These are addressed in the design of a new motored piston and floating liner rig. The design constrains transverse movement of a single liner using cantilevered mounts at the top and bottom. The mounts and two high stiffness strain gauged load cells constrain vertical movement. The outputs of the load cells are processed to extract the force contribution associated with friction. The liner, piston and crankshaft parts were taken from a EuroV-compliant, HPCR diesel engine with a swept capacity of 550cc per cylinder.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

Surface heat transfer measurements have been taken in the intake port of a single cylinder four valve SI engine running on isooctane fuel. The objective has been to establish how fuel characteristics affect trends in surface heat transfer rates for a range of engine operating conditions. The heat transfer measurements were made using heat flux gauges bonded to the intake port surface in the region where highest rates of fuel deposition occur. The influence on heat transfer rates of the deposited fuel and its subsequent behaviour has been examined by comparing fuel-wetted and dry-surface heat transfer measurements. Heat transfer changes are consistent with trends predicted by convective mass transfer over much of the range of surface temperatures from 20°C to 100°C. Towards the upper temperature limit heat transfer reaches a maximum limited by the rate and distribution of fuel deposition.

A correlation for total gas-side heat transfer rate has been derived from the analysis of engine data for measured heat rejection rate, frictional dissipation, and published data on exhaust port heat transfer. The correlation is related to the form developed by Taylor and Toong, and the analysis draws on this. However, cylinder and exhaust port contributions are separated. Two empirical constants are fixed to best match predicted to measured results for heat rejection to coolant and oil cooler under steady-state conditions, and also for exhaust port heat transfer rates. The separated contributions also defined a correlation for exhaust port heat transfer rate. The description of gas-side heat transfer is suited to needs for the analysis of global thermal behaviour of engines.

Experimental studies of fuel utilisation during the early stages of engine warm-up after cold-starts are reported. The investigation has been carried out on a 1.81, 4 cylinder spark-ignition engine with port electronic fuel injection. The relationship between fuel supplied and fuel accounted for by the analysis of exhaust gas composition shows that a significant mass of fuel supplied is temporarily stored or permanently lost. An interpretation of data is made which allows time-dependent variations of these to be separately resolved and estimates of fuel quantities made. The data covers a range of cold-start conditions down to -5°C at which, on a per cylinder basis, fuel stored peaks typically at around 0.75g and a total of 1g is returned over 100 seconds of engine running. Fuel lost past the piston typically accounts for 2g over 200 to 300 seconds of running.

The thermal efficiency of an internal combustion engine at steady state temperatures is typically in the region of 25-35%[1]. In a cold start situation, this reduces to be between 10% and 20% [2]. A significant contributor to the reduced efficiency is poor performance by the engine lubricant. Sub optimal viscosity resulting from cold temperatures leads to poor lubrication and a subsequent increase in friction and fuel consumption. Typically, the engine lubricant takes approximately twenty minutes [3] to reach steady state temperatures. Therefore, if the lubricant can reach its steady state operating temperature sooner, the engine's thermal efficiency will be improved. It is hypothesised that, by decoupling the lubricant from the thermal mass of the surrounding engine architecture, it is possible to reduce the thermal energy loss from the lubricant to the surrounding metal structure in the initial stages of warm-up.

Characterization of soot nanoparticle morphology can be used to develop understanding of nanoparticle interaction with engine lubricant oil and its additives. It can be used to help direct modelling of soot-induced thickening, and in a more general sense for combatting reductions in engine efficiency that occur with soot-laden oils. Traditional 2D transmission electron microscopy (TEM) characterization possesses several important shortcomings related to accuracy that have prompted development of an alternative 3D characterization technique utilizing electron tomography, known as 3D-TEM. This work details progress made towards facilitating semi-automated image acquisition and processing for location of structures of interest on the TEM grid. Samples were taken from a four cylinder 1.4 L gasoline turbocharged direct injection (GTDI) engine operated in typically extra-urban driving conditions for 20,284 km, with automatic cylinder deactivation enabled.

The influence of size and concentration of carbon nanoparticle on the viscosity of an SAE 5W-30 lubricant oil has been investigated experimentally. Data were collected for oil samples drawn from sump of light duty automotive diesel engines. The average size of soot particles in the used oil samples was in the range of 180-320nm with concentrations ranging from 0 to 2 percentage by weight (wt. %.). A Brookfield DV-II Pro rotary viscometer was used to measure dynamic viscosity at low shear rates and temperatures of 40°C and 90°C. Nanoparticle concentration and particle size distribution were evaluated using Thermo-Gravimetric Analysis (TGA) and Dynamic Light Scattering (DLS) respectively. The viscosity of suspensions of graphite powder in lubricant oil was also investigated for concentrations ranging from 0 to 2 wt. %. The results show that dynamic viscosity increases with increasing soot content and decreasing temperature.

The dilution of lubricating oil by fuel has adverse effects on engine wear, oil lubricity, air/fuel ratio control and feedgas emissions. Dilution is one of the factors limiting oil change intervals. The level and rate of accumulation depend on engine operating conditions and patterns of vehicle use. The work reported here develops and evaluates an empirical model to predict accumulation characteristics. This is aligned to requirements for predictions of dilution build-up in service. Predictions are shown to be in good agreement with data given in the literature. The model is used to investigate the influence of patterns of vehicle use on dilution.