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The selection of parameters during friction stir spot welding of Al-alloys and Mg-alloys is discussed. The role of tool rotation speed, plunge rate, and dwell time is examined in relation to the tool heating rate,temperature, force, and torque that occur during spot welding. In order to reduce the cycle time and tool force during Al- alloy spot welding, it is necessary to increase the tool rotation speed >1500 RPM. The measured peak temperature in the stir zone is determined by the rotation speed and dwell time, and is ultimately limited by the solidus of the alloy. When tool rotation speeds >1500 RPM are employed during AZ91 Mg-alloy spot welding, the tendency for melted film formation and cracking are greatly increased.

A novel processing method for fabricating high porosity microcellular ceramic foams for sound absorption applications has been developed. The strategy for fabricating the ceramic foams involves: (i) forming some shapes using a mixture of preceramic polymer and expandable microspheres by a conventional ceramic forming method, (ii) foaming the compact by heating, (iii) cross-linking the foamed body, and (iv) transforming the foamed body into ceramic foams by pyrolysis. By controlling the microsphere content and that of the base elastomer, it was possible to adjust the porosity with a very high open-cell content (ranging between 43 - 95%), high microcellular cell densities (9 × 108 - 1.6 × 109 cells/cm3) and desired expansion ratios (3 - 6 folds). Sound absorption testing has been performed using ASTM C-384 standard test. The preliminary results show that ceramic foams are candidate sound absorption materials.

We have studied the effects of water droplets presence in the PEM Fuel cell channel and the way they influence dynamics of the two-phase flow in the channel numerically. Dynamic behavior of a droplet on the surface of a channel has been modeled under the influence of surrounding fluid. Optimal conditions for the displacement of water droplet in the channel flow sought. For this purpose, the yield conditions for the displacement of liquid droplet on the surface of the channel under the influence of channel fluid are determined. The numerical solution is based on solving Navier-Stokes equations for Newtonian liquids. The study includes the effect of interfacial forces with constant surface tension, also effect of adhesion between the wall and droplet accounted by implementing contact angle at the wall. The Volume-Of-Fluid method is used to numerically determine the deformation of free surface.

Friction stir spot welding of Mg-alloy AZ91 is investigated. The temperature cycles within the stir zone and in the TMAZ region are examined using thermocouples, which are located within the tool itself and also by locating thermocouples in drilled holes at specific locations relative to the bottom of the tool shoulder and the periphery of the rotating pin. The measured temperatures in the stir zone range from 437°C to 460°C (0.98Ts, where Ts is the solidus temperature in degrees Kelvin) in AZ91 spot welds produced using plunge rates from 2.5 and 25 mm/s. The thermal cycle within the stir zone formed during AZ91 spot welding could not be measured by locating thermocouples within the workpiece in drilled holes adjacent to the periphery of the rotating pin.

In this work hemp fibers were chemically treated in order to improve the fiber/matrix interaction in hemp fiber/unsaturated polyester composites prepared by a Resin Transfer Molding (RTM) process. Chemicals used for paper sizing (AKD, ASA, Rosin Acid and SMA) as well as a silane compound and sodium hydroxide were used to modify the fibers' surface. The tensile, flexural and impact properties of the resulting materials were measured. A slight improvement in mechanical properties was observed for the SMA, silane and alkali treated specimens. However close analysis of these tests and of the fracture surface of the samples showed that there was no amelioration of the fiber/matrix adhesion. It was found that predicted tensile strengths using the rule of mixture were very close to the experimental values obtained in this work. Finally the properties of an hybrid glass fiber/hemp fiber composite were found to be very promising

Large-scale emergency or off-grid power generation is typically achieved through diesel or natural gas generators. To meet governmental emission requirements, emission control systems (ECS) are required. In operation, effective control over the generator’s acoustic emission is also necessary, and can be accomplished within the ECS system. Plug flow mufflers are commonly used, as they provide a sufficient level of noise attenuation in a compact structure. The key design parameter is the transmission loss of the muffler, as this dictates the level of attenuation at a given frequency. This work implements an analytically decoupled solution, using multiple perforate impedance models, through the transfer matrix method (TMM) to predict the transmission loss based on the muffler geometry. An equivalent finite element model is implemented for numerical simulation. The analytical results and numerical results are then evaluated against experimental data from literature.

Thermoplastic Vulcanizate (TPV) is a special class of Thermoplastic Elastomers (TPEs) made of a rubber/plastic polymer mixture in which the rubber phase is highly vulcanized. It is prepared by melt mixing a thermoplastic with an elastomer and by in-situ crosslinking of the rubber phase. Currently, TPV is replacing EPDM rubber dramatically because of the impressive advantages for automotive sealing applications. Some of the advantages of TPV compared to that of EPDM rubber are good gloss, recyclability, improved colorability, shorter cycle time and design flexibility. The development of TPV foaming technology is to fulfill the requirement of achieving lower cost, lighter weight and better fuel economy. Foaming of TPV has not been investigated extensively.

Energy generation and utilization during friction stir spot welding of Al 6061-T6 and AM50 sheet materials are investigated. The dimensions of the stir zones during plunge testing are largely unchanged when the tool rotational speed increases from 1500 RPM to 3000 RPM (for a plunge rate of 1 mm/s) and when the rate of tool penetration increases from 1 mm/s to 10 mm/s (for a tool rotational speed of 3000 RPM). The energy resulting from tool rotation is also unaffected when higher tool rotational speeds are applied. The rotating pin accounts for around 70% and 66% of the energy generated when 6.3 mm thick Al 6061-T6 and AM50 sheet materials are spot welded without the application of a dwell period. In direct contrast, the contribution made by the tool shoulder increases to around 48% (Al 6061-T6) and to 65% (AM50) when a four second long dwell period is incorporated during spot welding of 6.3 mm thick sheets.

Particulate matter emissions from gasoline direct injection engines are a concern due to the health effects associated with ultrafine particles. This experimental study investigated sources of particulate matter emissions variability observed in previous tests and also examined the effect of ethanol content in gasoline on particle number (PN) concentrations and particle mass (PM) emissions. FTIR measurements of gas phase hydrocarbon emissions provided evidence that changes in fuel composition were responsible for the variability. Exhaust emissions of toluene and ethanol correlated positively with emitted PN concentrations, while emissions of isobutylene correlated negatively. Exhaust emissions of toluene and isobutylene were interpreted as markers of gasoline aromatic content and gasoline volatility respectively.

The increasing use of natural gas as a vehicle fuel has generated considerable research activity to characterize the performance and emissions of engines utilizing this fuel. However, virtually all of the results reported have been for pushrod OHV spark ignition engines or SI conversions of heavy-duty diesel engines. Because of the pressure to improve fuel economy imposed by CAFE requirements, passenger cars are increasingly tending toward high specific output, small displacement engines. These engines employ such features as four valves per cylinder and centrally located spark plugs which give them a different dependence on operating variables than traditional pushrod OHV engines. In this study, experiments were carried out with a two-liter four-cylinder Nissan SR20DE engine representative of modern design practice. The engine was operated on gasoline and natural gas at six different loads and three different speeds. Some tests were also done with isooctane.

As a result of CAFE (corporate average fuel economy) requirements, the trend in passenger car engine design is to smaller displacement engines of higher specific output which provide reductions in vehicle driving cycle fuel consumption without an accompanying decrease in maximum power output. Design features such as four valves per cylinder and compact combustion chambers give these engines significantly different combustion characteristics than traditional pushrod OHV (overhead valve) engines. In general, their combustion chambers are fast burning, enabling the use of higher compression ratios without knock on unleaded gasoline. Since fuel consumption decreases with increasing compression ratio, and since natural gas has a substantially higher octane rating than the best unleaded gasoline, it would appear to be desirable to operate with even higher compression ratios in a dedicated natural gas engine.

Some current aftermarket natural gas closed loop carburetion systems use an integral control strategy to maintain a fuel-air equivalence ratio centered in the peak conversion window of a three-way catalytic converter. Fuel control system performance under steady-state engine operating conditions can be characterized by the time-averaged value of the fuel-air equivalence ratio, the rich and lean excursion limits, and a skewness parameter that represents the non-symmetry of the time varying fuel-air equivalence ratio about the control value (ϕaverage). Using a representative aftermarket feedback control system, the effect of these parameters on the exhaust emissions of a natural-gas fueled four-cylinder engine has been investigated. In addition, the effect of EGO sensor characteristics on control system performance has been examined.

Methanol, in common with other alternative fuels including natural gas and LPG, has autoignition characteristics which are poorly suited for use in compression ignition engines. Some sort of ignition assist has proven to be necessary. Considerable work has been carried out with hot surface (glow plug) ignition. The geometric relationship between the fuel injection nozzle and the glow plug is critical to achieving high efficiency and low emissions. Moreover, it is difficult to establish a single geometry which provides reliable ignition and stable operation over the entire range of engine speeds and loads. The work described in this paper investigated extending the range of operation of a particular glow plug/fuel injection nozzle geometry by placing the glow plug in the wake of a bluff body. Bluff-body flame stabilization is a well-known technique in continuous combustors. Experiments were carried out in a single-cylinder CFR cetane rating engine fueled with methanol.

A study was performed to determine the effects of engine operating variables and piston and ring parameters on the crevice hydrocarbon emissions from a spark-ignition engine. Natural gas was used as the test fuel in an effort to isolate crevice mechanisms as the only major source of unburned hydrocarbons in the test engine's exhaust. The largest of the in-cylinder crevices, the piston ring pack crevices, were modified, both in size and accessibility, by altering the piston top land height and the number of piston rings and their end gaps. Each piston and ring configuration was subjected to a series of test sweeps of engine operating variables known to affect exhaust hydrocarbon emissions. None of the physical crevice modifications had any significant effect on the level of the exhaust hydrocarbon emissions, although the cycle-to-cycle repeatability of these emissions, measured with a fast hydrocarbon analyzer, was found to vary between the different configurations.

The effects of engine operating parameters on the speciated engine-out hydrocarbon emissions from a natural gas fueled spark ignition 16 valve four-cylinder engine were examined. Total hydrocarbon emissions were dominated by methane, the main component of natural gas. The non-methane hydrocarbons consisted primarily of ethane, ethene, and acetylene. Except for changes in the fuel-air equivalence ratio rich of the stoichiometric condition, emissions of unsaturated species were found to be less sensitive to engine operating parameters than were the fuel components. A single species, ethene, dominated the engine-out hydrocarbon reactivity, accounting for over 80% of the NMHC reactivity.

Charge dilution is commonly used to reduce emissions of nitrogen oxides (NOx) from internal combustion engine exhaust gas. The question of whether to use air or exhaust gas recirculation (EGR) as a charge diluent for the natural gas-fuelled test engine is addressed first. The decision to use EGR is based on the potentially lower NOx and unburned hydrocarbon emissions that could be achieved if a three-way catalyst were applied to the engine. The effect of EGR on the spark advance for maximum brake torque (MBT), NOx, and unburned hydrocarbon emissions is then examined in detail. The effect on fuel efficiency is discussed briefly.

Many current aftermarket natural gas conversions of gasoline fuelled spark ignited engines use an air-valve type mixer with closed loop control of the gas pressure. This control is often provided by an electronic integral controller that uses the output from an exhaust gas oxygen (EGO) sensor to control the duty cycle of a solenoid valve. By varying the duty cycle of this fuel control valve (FCV), the average pressure in the low pressure regulator (LPR) reference chamber and thus the gas pressure can be varied. The transient behaviour of these fuel systems is affected mainly by the mechanical response of the gas mixer and the LPR. The electronic controller can provide compensation only after the EGO sensor has detected an air-fuel ratio excursion. The main weaknesses of this type of fuel system seems to be associated with the finite response of the mixer and the LPR and by the use of an airflow dependent vacuum signal strength for control.

An experiment was conducted to evaluate the efficiency and emissions of an engine fuelled with a mixture of natural gas and approximately 15% hydrogen by volume. This mixture, called Hythane™, was compared with natural gas fuel using engine efficiency and engine-out emissions at various engine operating conditions as the basis of comparison. Throughout most of the experiment, fuel mixtures were slightly rich of stoichiometry. It was found that at low engine loads, using the same spark timing, engine efficiency increased under HythaneTM fuelling but at higher engine loads, natural gas and Hythane™ had the same efficiency. At low engine speed and load conditions with the same spark timing, engine-out total hydrocarbon (THC) emissions were lower for Hythane™ fuelling. When compared on a carbon specific basis, however, natural gas hydrocarbon emissions were lower. At some test conditions, engine-out carbon monoxide (CO) emissions were lower under Hythane™.

Measurements were taken of the speciated aldehyde and ketone exhaust emissions from a modern four-cylinder engine fuelled with natural gas. The effect on these emissions of varying the engine operating parameters spark timing, exhaust gas recirculation rate, engine speed, and fuel/air equivalence ratio was examined. The influence of these operating parameters on the complete reactivity-weighted emissions with natural gas fuelling is predicted. With stoichiometric fuel/air mixtures, both the total hydrocarbons and formaldehyde emissions declined with increasing exhaust gas temperature and increasing in-cylinder residence time, suggesting that formaldehyde burn-up in the exhaust process largely controls its emissions levels. Closer examination of the aldehyde emissions shows they follow trends more like those of the non-fuel, intermediate hydrocarbon species ethane and acetylene, than like the trends of the fuel components methane and ethane.

The hydrogen-fueled engine has been identified as a viable power unit for ultra-low emission senes-hybrid vehicles The absence of carbon in hydrogen fuel eliminates exhaust emissions of CO, CO2, and hydrocarbons, with the exception of small contributions from the combustion of lubricating oil Thus, the only regulated emission of a hydrogen-fueled engine is NOx, and the engine may be optimized to minimize NOx since the usual constraint of the NOx -hydrocarbon trade-off is not applicable Hydrogen-fueled homogeneous charge piston engines have, however, generally suffered from a variety of combustion difficulties, most notably a proclivity to ignition on hot surfaces such as exhaust valves, spark plug electrodes and deposits on combustion chamber walls The Wankel engine is particularly well suited to the use of hydrogen fuel, since its design minimizes most of the combustion difficulties In order to evaluate the possibilities offered by the hydrogen fueled rotary engine, dynamometer tests were conducted with a small (2 2kW) Wankel engine fueled with hydrogen Preliminary results show an absence of the combustion difficulties present with hydrogen-fueled homogenous charge piston engines The engine was operated unthrottled and power output was controlled by quality governing, i.e. by varying the fuel-air equivalence ratio on the lean side of stoichiometric The ability to operate with quality governing is made possible by the wide flammability limits of hydrogen-air mixtures NOx emissions are on the order of 5 ppm for power outputs up to 70% of the maximum attainable on hydrogen fuel Thus, by operating with very lean mixtures, which effectively derates the engine, very low NOx emissions can be achieved Since the rotary engine has a characteristically high power to weight ratio and a small volume per unit power compared to the piston engine, operating a rotary engine on hydrogen and derating the power output could yield an engine with extremely low emissions which still has weight and volume characteristics comparable to a gasoline-fueled piston engine Finally, since engine weight and volume affect vehicle design, and consequently in-use vehicle power requirements, those factors, as well as engine efficiency, must be taken into account in evaluating overall hybnd vehicle efficiency