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Active regeneration experiments were performed on a production diesel aftertreatment system containing a diesel oxidation catalyst and catalyzed particulate filter (CPF) using blends of soy-based biodiesel. The effects of biodiesel on particulate matter oxidation rates in the filter were explored. These experiments are a continuation of the work performed by Chilumukuru et al., in SAE Technical Paper No. 2009-01-1474, which studied the active regeneration characteristics of the same aftertreatment system using ultra-low sulfur diesel fuel. Experiments were conducted using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Particulate matter loading of the filter was performed at the rated engine speed of 2100 rpm and 20% of the full engine load of 1120 Nm. At this engine speed and load the passive oxidation rate is low. The 17 L CPF was loaded to a particulate matter level of 2.2 g/L.

A diesel exhaust sampling system was specially designed to measure and collect emissions from a ceramic wall-flow particulate trap during periods of controlled electric regeneration with the exhaust emissions bypassing the trap. This resulted in the regeneration emissions being independent of those produced during either baseline (no control) or trap (exhaust filtration) sampling conditions. This system provided data regarding the physical, chemical, and biological character of regeneration emissions relative to baseline and trap emissions. Selected emission levels measured continuously during the regeneration process were also used to define the particle combustion process in the trap core. Variations in hydrocarbons (HC), oxides of nitrogen (NOx), and particulate volume concentrations during the regeneration process were used to define four stages of the combustion process: preheat; combustion wave formation; combustion wave propagation; and combustion wave extinction.

Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.

Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.

A Cummins ISB 5.9 liter medium-duty engine with cooled EGR has been used to study an early extrusion of an advanced ceramic uncatalyzed diesel particulate filter (DPF). Data for the advanced ceramic material (ACM) and an uncatalyzed cordierite filter of similar dimensions are presented. Pressure drop data as a function of mass loadings (0, 4, and 6 grams of particulate matter (PM) per liter of filter volume) for various flow rate/temperature combinations (0.115 - 0.187 kg/sec and 240 - 375 °C) based upon loads of 15, 25, 40 and 60% of full engine load (684 N-m) at 2300 rpm are presented. The data obtained from these experiments were used to calibrate the MTU 1-D 2-Layer computer model developed previously at MTU. Clean wall permeability determined from the model calibration for the ACM was 5.0e-13 m2 as compared to 3.0e-13 m2 for cordierite.

A methodology to estimate the mass of particulate retained in a catalyzed particulate filter as a function of measured total pressure drop, volumetric flow rate, exhaust temperature, exhaust gas viscosity and cake and wall permeability applicable to real-time computation is discussed. This methodology is discussed from the view point of using it to indicate when to initiate active regeneration and as an On-Board Diagnostic tool to detect filter failures. Steady-state loading characterization experiments were conducted on a catalyzed diesel particulate filter (CPF) in a Johnson Matthey CCRT® (catalyzed continuously regenerating trap) system. The experiments were performed using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Experiments were conducted at 20, 60 and 75% of full engine load (1120 Nm) and rated speed (2100 rpm) to measure the pressure drop, transient filtration efficiency, particulate mass balance, and gaseous emissions.

A quasi-steady 1-dimensional computer model of a catalyzed particulate filter (CPF) capable of simulating active regeneration of the CPF via diesel fuel injection upstream of a diesel oxidation catalyst (DOC) or other means to increase the exhaust gas temperature has been developed. This model is capable of predicting gaseous species concentrations (HC's, CO, NO and NO2) and exhaust gas temperatures within and after the CPF, for given input values of gaseous species and PM concentrations before the CPF and other inlet variables such as time-varying temperature of the exhaust gas at the inlet of the CPF and volumetric flow rate of exhaust gas.

Active regeneration of a catalyzed particulate filter (CPF) is affected by a number of parameters specifically particulate matter loading and inlet temperature. The MTU 1-D 2-Layer CPF model [1] was used to analyze these effects on the pressure drop, oxidation and filtration characteristics of a CPF during active regeneration. In addition, modeling results for post loading experiments were analyzed to understand the difference between loading a clean filter as compared to a partially regenerated filter. Experimental data obtained with a production Cummins regenerative particulate filter for loading, active regenerations and post loading experiments were used to calibrate the MTU 1-D 2-Layer CPF model. The model predicted results are compared with the experimental data and were analyzed to understand the CPF characteristics during active regeneration at 1.1, 2.2 and 4.1 g/L particulate matter (PM) loading and CPF inlet temperatures of 525, 550 and 600°C.

Active regeneration experiments were performed on a Cummins 2007 aftertreatment system by hydrocarbon dosing with injection of diesel fuel downstream of the turbocharger. The main objective was to characterize the thermal oxidation rate as a function of temperature and particulate matter (PM) loading of the catalyzed particulate filter (CPF). Partial regeneration tests were carried out to ensure measureable masses are retained in the CPF in order to model the oxidation kinetics. The CPF was subsequently re-loaded to determine the effects of partial regeneration during post-loading. A methodology for gathering particulate data for analysis and determination of thermal oxidation in a CPF system operating in the engine exhaust was developed. Durations of the active regeneration experiments were estimated using previous active regeneration work by Singh et al. 2006 [1] and were adjusted as the experiments progressed using a lumped oxidation model [2, 3].

Steady state loading characterization experiments were conducted at three different engine load conditions and rated speed on the cracked catalyzed particulate filter (CPF). The experiments were performed using a 10.8 L 2002 Cummins ISM-330 heavy duty diesel engine. The CPF underwent a ring off failure, commonly seen in particulate filters, due to high radial and axial temperature gradients. The filters were cracked during baking in an oven which was done to regenerate PM collected after every loading characterization experiment. Two different configurations i.e. with and without a diesel oxidation catalyst (DOC) upstream of the CPF were studied. The data were compared with that on an un-cracked CPF at similar engine conditions and configurations. Pressure drop, transient filtration efficiency by particle size and PM mass and gaseous emissions measurements were made during each experiment.

The effects of a catalyzed particulate filter (CPF) and Exhaust Gas Recirculation (EGR) on heavy-duty diesel engine emissions were studied in this research. EGR is used to reduce the NOx emissions but at the same time it can increase total particulate matter (TPM) emissions. CPF is technology available for retrofitting existing vehicles in the field to reduce the TPM emissions. A conventional low sulfur fuel (371 ppm S) was used in all the engine runs. Steady-state loading and regeneration experiments were performed with CPF I to determine its performance with respect to pressure drop and particulate mass characteristics at different engine operating conditions. From the dilution tunnel emission characterization results for CPF II, at Mode 11 condition (25% load - 311 Nm, 1800 rpm), the TPM, HC and vapor phase emissions (XOC) were decreased by 70%, 62% and 62% respectively downstream of the CPF II.

A study of particle size distributions was conducted on a Cummins M11 1995 engine using the Scanning Mobility Particle Sizer (SMPS) instrument in the baseline and downstream of the Catalyzed Particulate Filter (CPF). Measurements were made in the dilution tunnel to investigate the effect of primary dilution ratio and mixture temperature on the nuclei and accumulation mode particle formation. Experiments were conducted at two different engine modes namely Mode 11 (25% load - 311 Nm, 1800 rpm) and Mode 9 (75% load - 932 Nm, 1800 rpm). The nanoparticle formation decreased with increasing dilution ratios for a constant mixture temperature in the baseline as well as downstream of the CPF II for Mode 11 condition. At Mode 9 condition in the baseline, the dilution ratio had a little effect on the nanoparticle formation, since the distribution was not bimodal and was dominated by accumulation mode particles.

A one-dimensional, two layer computational model was developed to predict the behavior of a clean and particulate-loaded catalyzed wall-flow diesel particulate filter (CPF). The model included the mechanisms of particle deposition inside the CPF porous wall and on the CPF wall surface, the exhaust flow field and temperature field inside the CPF, as well as the particulate catalytic oxidation mechanisms accounting for the catalyst-assisted particulate oxidation by the catalytic coating in addition to the conventional particulate thermal oxidation. The paper also develops the methodology for calibrating and validating the model with experimental data. Steady state loading experiments were performed to calibrate and validate the model.

A 2-dimensional numerical model (MTU-FILTER) for a single channel of a honeycomb ceramic diesel particulate trap has been developed. The mathematical modeling of the filtration, flow, heat transfer and regeneration behavior of the particulate trap is described. Numerical results for the pressure drop and particulate mass were compared with existing experimental results. Parametric studies of the diesel particulate trap were carried out. The effects of trap size and inlet temperature on the trap performance are studied using the trap model. An approximate 2-dimensional analytical solution to the simplified Navier-Stokes equations was used to calculate the velocity field of the exhaust flow in the inlet and outlet channels. Assuming a similarity velocity profile in the channels, the 2-dimensional Navier-Stokes equations are approximated by 1-dimenisonal conservation equations, which is similar to those first developed by Bissett.

A computational lumped parameter model (MTU-Filter-Lumped) was developed to describe the performance of diesel particulate filters (DPFs) during loading and regeneration processes. The model was formulated combining three major sub-models: a filtration model, a pressure drop model, and a mass and an energy balance equation for the total filter volume. The first two sub-models have been widely validated in the literature, while the third sub-model is introduced and combined with the first two sub-models in the present study. The three sub-models combined can give a full description of diesel particulate filter behavior during loading and regeneration processes, which was the objective of the present work. The total combined lumped parameter model was calibrated using experimental data from the literature covering a range of experimental conditions, including different catalytic regeneration means and engine operating conditions.

New Particulate Matter (PM) and Particulate Number (PN) regulations throughout the world have created a need for aftertreatment solutions that include particulate control as an option to comply with the legislation. However, limitations in other criteria emissions cannot be sacrificed to accomplish the reduction of PM/PN. For this work, three-way washcoat catalyzed wall-flow Gasoline Particulate Filters (GPF) and similarly catalyzed flow-through catalysts of common defined volume were tested. Their catalytic performance was determined by measuring NOx, CO and HC conversion efficiencies and CO2 levels over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) cycles. Analysis of the impact on CO2 emissions was also evaluated in relation to backpressure from 1-D modeling analysis. All exhaust systems used the same loading and ratio of Platinum Group Metals (PGM), but employed different cell structures in their substrates.

The catalyzed particulate filter (CPF), used in conjunction with a diesel oxidation catalyst (DOC) is an important aftertreatment device used to meet Environmental Protection Agency (EPA) heavy-duty diesel emission standards for particulate matter (PM). Numerical modeling of these exhaust after-treatment devices decreases the time and cost of development involved. Modeling CPF active regeneration gives insight into the PM oxidation kinetics, which helps in reducing the regeneration fuel penalty. As seen from experimental data, active regeneration of the CPF results in a significant temperature increase into the CPF (up to 8°C/sec) which affects the oxidation rate of particulate matter (PM). PM oxidation during active regeneration was determined to be a function of filter PM loading, inlet temperature and inlet hydrocarbon concentration.

A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.