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Thin-walled structures have been widely used in automobile body design because of its good lightweight and superior mechanical properties. For the energy-absorbing box of the automobile, it is necessary to consider its working conditions under the axial and oblique impact. In this paper, a novel hierarchical honeycomb is proposed and used as filler for thin-walled structures. Meanwhile, the crashworthiness performances of the conventional honeycomb-filled and the hierarchical honeycomb-filled thin-walled structures under different impact conditions are systematically studied. The results indicate the energy absorption of the hierarchical honeycomb-filled thin-walled structure is higher than that of the conventional honeycomb-filled thin-walled structure, and the impact angle has significant effects on the energy absorption performance of the hierarchical honeycomb-filled structure.