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Measurement of particle number was introduced in the Euro 5/6 light duty vehicle emissions regulation. Although particle number measurement systems have to be calibrated by the manufacturers, labs have to validate the proper operation of their systems within one year of the emissions test. The systems must achieve a >99% reduction of an aerosol containing 30 nm tetracontane (CH3(CH2)38CH3) particles (C40) with an inlet concentration >104 #/cm3. They must also include an initial heated dilution stage with dilution of at least 10 which outputs a diluted sample at a temperature of 150°C–400°C. The system as a whole must achieve a particle number concentration reduction factor for particles of 30 nm and 50 nm electrical mobility diameters, that is no more than 30% and 20% respectively higher, and no more than 5% lower than that for particles of 100 nm.

The 2007 Diesel particulate matter (DPM) standard of 0.01 g/bhp-hr represents a 90% reduction of the previous standard and corresponds to roughly 100 micrograms (μg) gained on the filter sample used to determine compliance. The factors that influence the accuracy and precision by which this filter can be weighed are analyzed and quantified. The total uncertainty, representing best and typical cases, is between 1 and 5 μg. These uncertainties are used to compute the total uncertainty of the brake specific emission calculation. This uncertainty also depends on flowrate uncertainty, face velocity, and secondary dilution ratio. For a typical case, the total fractional uncertainty is in the range of ∼5 – 70% at 10% of the standard and ∼1 – 10% at 90% of the standard.

EPA's 2007 Diesel particulate matter (DPM) standard requires a large reduction in total mass emissions. In practice, this amounts to a fractional reduction in elemental carbon emissions. The reduction is balanced by a fractional increase in the semi-volatile component, which is difficult to sample and quantify accurately at low concentrations using filter-based methods. In this work, we show how five imprecisely defined filter-sampling parameters influence the mass collected on a filter. These parameters are: dilution air quality, dilution conditions (dilution ratio and dilution air temperature), particle size classification, filter media and artifacts, and face velocity. Each factor has the potential to change the mass collected by a minimum of 5% of the standard, suggesting there is room for improvement.

The heavy duty Particle Measurement Programme (PMP) inter-laboratory exercise consists of three parts: 1) the exploratory work to refine the measurement protocol, 2) the validation exercise where each lab will measure the emissions of a “golden” engine with two “golden” particle number systems simultaneously sampling from full and partial flow dilution systems, and 3) the round-robin where the emissions of a “reference” engine will be determined with a lab’s own particle number instrumentation. This paper presents the results of the exploratory work and describes the final protocol for testing in the validation exercise (and round robin) along with the necessary facility modifications required for compliance with the protocol. Key aspects of the protocol (e.g. filter material, flow rates at the full and partial flow systems, the pre-conditioning etc.) are explained and justified.

Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.

Euro 5/6 light-duty vehicle emissions regulation introduced non-volatile particle number emission measurements. The particle number measurement system consists of a volatile removal unit followed by a particle number counter with a 50% cut-point diameter at 23 nm. The volatile removal unit must achieve a >99% concentration reduction of a monodisperse aerosol of tetracontane (CH 3 (CH 2 ) 38 CH 3 ) particles of diameter ≥30 nm with inlet concentration ≥10 4 cm −3 . In this paper the evaporation of tetracontane particles in the volatile removal unit is investigated theoretically. The temperature and the residence time in the evaporation tube are discussed, as well as the possibility of nucleation events of evaporated particles at the exit of the evaporation tube. In addition, sulfuric acid nucleation at the evaporation tube exit is analyzed. Theoretical calculations are, finally, compared to experimental data.

Diesel low temperature combustion (LTC) is an operational strategy that is effective at reducing soot and oxides of Nitrogen (NOx) emissions at low engine loads in-cylinder. A downside to LTC in diesel engines is increased hydrocarbon (HC) emissions. This study shows that semi-volatile species from LTC form the bulk of particulate matter (PM) upon dilution in the atmosphere. The nature of gas-to-particle conversion from high HC operating modes like LTC has not been well characterized. In this work, we explore engine-out PM and HC emissions from LTC and conventional diffusion combustion (CC) operation for two different engine load and speed modes using a modern light-duty diesel engine. An experimental method to investigate PM volatility was implemented. Raw exhaust was diluted under two dilution conditions. A tandem differential mobility analyzer (TDMA) was used to identify differences in volatility between particle sizes.

Diesel low temperature combustion (LTC) is an operational strategy that effectively limits soot and oxides of nitrogen (NOx) emissions in-cylinder. Unfortunately, LTC results in increased hydrocarbon emissions as compared to conventional diesel combustion (CDC). Previous work has shown that exhaust conditions resulting from LTC inhibit oxidation of HC within a diesel oxidation catalyst (DOC). Further, these elevated HC emissions result in engine-out particulate matter (PM) that primarily consists of semi-volatile organic material. The current work shows that a DOC incompletely oxidizes this PM forming material. These results investigated the effectiveness of both a DOC and a diesel particulate filter (DPF) in reducing particle emissions for LTC. In this work, engine-out, DOC-out, and DPF-out exhaust were sampled using a micro-dilution system. Particle distributions were determined with a scanning mobility particle sizer (SMPS) and engine exhaust particle sizer (EEPS).

Human health and the environment are heavily impacted by air pollution. Air quality standards for Nitrogen dioxide (NO2) and particulate matter (PM) are commonly exceeded in Europe, particularly in urban areas with high density of traffic. Road transport contributed to 39% of NOx emissions, and 11% of PM emissions in the European Union (EU) in 2017. Measurements with Portable Emissions Measurement Systems (PEMS) showed that most Euro 5 and Euro 6b diesel vehicles emitted significantly more NOx on the road than their permissible limit in the laboratory type-approval test. In that context, EU Real Driving Emissions (EU-RDE) regulation aims at securing low on-road emissions of light duty vehicles under normal conditions of use. This paper assesses the tailpipe emissions performance of Euro 6d-TEMP gasoline and diesel passenger cars, type-approved after the entry into force of the RDE regulation in September 2017.

Particle number (PN) emission limits were introduced in the European Union’s regulations for light-duty and heavy duty vehicles in the years 2011-2014. Since then, PN measurements have become a common practice in the automotive sector. Many studies showed that the current methodology, which counts particles >23 nm, misses a large fraction of particles for some engine technologies, such as port fuel injection vehicles or vehicles fueled with compressed natural gas (CNG). However, data for the latest technology vehicles are lacking. For this reason, we measured PN emissions >23 nm and >10 nm of >30 CNG, gasoline and diesel-fueled vehicles. Two systems were measuring in parallel from the full dilution tunnel; one with an evaporation tube and the other with a catalytic stripper. The PN emission levels spanned over three orders of magnitude depending on whether there was a particulate filter installed or not.

In 2011 a particle number (PN) limit was introduced in the European Union's vehicle exhaust legislation for diesel passenger cars. The PN method requires measurement of solid particles (i.e. those that do not evaporate at 350 °C) with diameters above 23 nm. In 2013 the same approach was introduced for heavy duty engines and in 2014 for gasoline direct injection vehicles. This decision was based on a long evaluation that concluded that there is no significant sub-23 nm fraction for these technologies. In this paper we examine the suitability of the current PN method for L-category vehicles (two- or three-wheel vehicles and quadri-cycles). Emission levels of 5 mopeds, 9 motorcycles, 2 tricycles (one of them diesel) and 1 quad are presented. Special attention is given to sub-23 nm emission levels. The investigation was conducted with PN legislation compliant systems with particle counters measuring above 23 nm and 10 nm.

To ensure reliable starting under cold weather conditions (< 0 oC ambient), gasoline engines use fuel enrichment, leading to higher soot formation and greater tailpipe particle number (PN) emissions. In gasoline direct injection (GDI) engines, PN emissions are higher due to liquid fuel impingement on cold surfaces of the combustion chamber and piston. This study characterizes solid (mostly elemental carbon) and semi-volatile (organic) particle number, mass, and size distributions during cold-cold engine start-up from light duty vehicles. Particle emissions were sampled from vehicles upon engine start-up after an overnight soak, with an average ambient temperature of -8 ± 7 oC. The average PN emitted during 180 seconds by GDI and PFI vehicles were 3.09E+13 and 2.12E+13 particles respectively.

Since 2011 a particle number (PN) limit was introduced in the European light-duty diesel vehicles legislation. The PN measurement systems consist of i) a hot diluter and an evaporation tube at 300-400°C for the removal of the volatiles (Volatile Particle Remover, VPR) and ii) a particle number counter (PNC) with a 50% cut-point (cut-off) at 23 nm. The PN measurement systems are calibrated and validated annually with monodisperse aerosol: The VPR for the particle concentration reduction factor (PCRF) and the PNC for the linearity and the cut-off size. However, there are concerns that the PN measurement systems can drift significantly over this period of time, raising concerns regarding the validity of the previous measurements, especially if the yearly validation fails.

Recently, a particle number (PN) limit was introduced in the European light-duty vehicles legislation. The legislation requires measurement of PN, and particulate mass (PM), from the full dilution tunnel with constant volume sampling (CVS). Furthermore, PN measurements will be introduced in the next stage of the European Heavy-Duty regulation. Heavy-duty engine certification can be done either from the CVS or from a partial flow dilution system (PFDS). For research and development purposes, though, measurements are often conducted from the raw exhaust, thereby avoiding the high installation costs of CVS and PFDS. Although for legislative measurements requirements exist regarding sampling and transport of the aerosol sample, such requirements do not necessarily apply for raw exhaust measurements. Thus, measurement differences are often observed depending on where in the experimental set up sampling occurs.

Particulate emissions cause adverse health effects and for this reason they are regulated since the 80s. Vehicle regulations cover particulate emission measurements of a model before its sale, known as type approval or homologation. For heavy-duty engines the emissions are measured on an engine dynamometer with steady state points and transient cycles. For light-duty vehicles (i.e. the full power train) the particulate emissions are assessed on a chassis dynamometer. The measurement of particulate emissions is conducted either by diluting the whole exhaust in a dilution tunnel with constant volume sampling or by extracting a small proportional part of the exhaust gas and diluting it. Particulate emissions are measured by passing part of the diluted exhaust aerosol through a filter paper. The increase of the weight of the filter is used to calculate the particulate matter mass (PM) emissions.

The objective of this work is to improve the understanding of variables like dilution and sampling conditions that contribute to particle-based emission measurements by assessing and comparing the nucleation tendency of diesel aerosols when diluted with a porous wall dilutor or an air ejector in a laboratory setting. An air-ejector dilutor and typical dilution conditions were used to establish the baseline sensitivity to dilution conditions for the given engine operating condition. A porous tube dilutor was designed and special attention was given to integrating the dilutor with the exhaust pipe and residence time chamber. Results from this system were compared with the ejector dilutor. Exhaust aerosols were generated by a Deere 4045 diesel engine running at low speed (1400 rpm) and low load (50 Nm, ~10% of rated). Primary dilution parameters that were varied included dilution air temperature (25 and 47°C) and dilution ratio (5, 14, and 55).

The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.

In the current diesel vehicle exhaust emissions legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014. Target of this paper was to investigate whether smaller than 23 nm solid particles are emitted from engines in considerable concentration focusing on G-DI engines. The literature survey and the experimental investigation of >15 vehicles showed that engines emit solid sub-23 nm particles. The average percentage over a test cycle for G-DIs (30-40%) is similar to diesel engines. These percentages are relatively low considering the emission limit levels (6×1011 p/km) and the repeatability (10-20%) of the particle number method. These percentages are slightly higher compared to the percentages expected theoretically not to be counted due to the 23 nm cut-off size (5-15%).

In the current heavy-duty engine and light-duty diesel vehicle exhaust emission legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014 and will be applied to Non-Road Mobile Machinery engines in the future. However there are concerns transferring the same methodology to other engine technologies, where higher concentration of sub-23 nm particles might exist. This paper focuses on the capabilities of existing PN measurement equipment on measuring solid particles smaller than 23 nm.

Diesel fuel injection systems are operating at increasingly higher pressure (up to 250 MPa) with smaller clearances, making them more sensitive to diesel fuel contaminants. Most liquid particle counters have difficulty detecting particles <4 μm in diameter and are unable to distinguish between solid and semi-solid materials. The low conductivity of diesel fuel limits the use of the Coulter counter. This raises the need for a new method to characterize small (<4 μm) fuel contaminants. We propose and evaluate an aerosolization method for characterizing solid particulate matter in diesel fuel that can detect particles as small as 0.5 μm. The particle sizing and concentration performance of the method were calibrated and validated by the use of seed particles added to filtered diesel fuel. A size dependent correction method was developed to account for the preferential atomization and subsequent aerosol conditioning processes to obtain the liquid-borne particle concentration.