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An automated process was developed for the calibration of numerical aftertreatment models. The chemical kinetic mechanism examined in this case was part of a simplified SCR model. The process adopted for calibrating the SCR model was based on a micro-population multi-objective genetic algorithm. The algorithm developed was used to calibrate the SCR model using data derived from another, more detailed model to ensure that the evaluation focused only on the effectiveness of the calibration process and was not affected by issues of experimental inaccuracies or details of the model chemistry involved.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

Ford Motor Company is introducing “EcoBoost” gasoline turbocharged direct injection (GTDI) engine technology in the 2010 Lincoln MKS. A logical enhancement of EcoBoost technology is the use of E85 for knock mitigation. The subject of this paper is the optimal use of E85 by using two fuel systems in the same EcoBoost engine: port fuel injection (PFI) of gasoline and direct injection (DI) of E85. Gasoline PFI is used for starting and light-medium load operation, while E85 DI is used only as required during high load operation to avoid knock. Direct injection of E85 (a commercially available blend of ∼85% ethanol and ∼15% gasoline) is extremely effective in suppressing knock, due to ethanol's high inherent octane and its high heat of vaporization, which results in substantial cooling of the charge. As a result, the compression ratio (CR) can be increased and higher boost levels can be used.

The internal combustion engine and associated powertrain are likely to remain the mainstay of mobility over the next twenty years and to remain a significant portion of the portfolio of technologies employed over a much longer period of time. Efficient combustion of all fuels (petroleum based or alternative) requires copious amounts of air particularly with downsized engines. Turbocharging technology thus becomes an even more critical part of reducing both global warming gas and urban pollutant emissions from IC engines. Gasoline engine downsizing and turbocharging have been shown to improve fuel economy by ∼20% in production vehicles. In addition to data over a wide range of engines/vehicles, the results of a simple analysis done on vehicles/engines/drive cycles are presented to show the benefits of turbocharging and downsizing in a parametric variation of downsizing in combination with other technologies.

Diesel engines have been used in large vehicles, locomotives and ships as more efficient alternatives to the gasoline engines. They have also been used in small passenger vehicle applications, but have not been as popular as in other applications until recently. The two main factors that kept them from becoming the major contender in the small passenger vehicle applications were the low power outputs and the noise levels. A combination of improved mechanical technologies such as multiple injection, higher injection pressure, and advanced electronic control has mostly mitigated the problems associated with the noise level and changed the public notion of the Diesel engine technology in the latest generation of common-rail designs. The power output of the Diesel engines has also been improved substantially through the use of variable geometry turbines combined with the advanced fuel injection technology.

Selective catalytic reduction (SCR) is allowing diesel engines to reach NOx emission levels which are unachievable in-cylinder. This technology is still evolving, and new catalyst formulations which provide higher performance and greater durability continue to be developed. Usually, their performance is measured on a flow reactor using ammonia as the reductant. However, in mobile applications a urea-water solution is used instead, and urea decomposition by thermolysis and hydrolysis provides the required ammonia to the catalyst. It is well known that urea decomposition is incomplete by the inlet face of the converter, and this is at least one reason why on-engine performance is generally lower than would be expected from reactor tests. Previous modeling of urea-water droplets has focused on developing detailed sub-models that can be implemented into computational fluid dynamics (CFD) codes.

The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.

Diesel Particulate Filters (DPF) are widely used to meet 2007 and beyond EPA Particulate Matter (PM) emissions requirements. During the soot loading process, soot is collected inside a porous wall and eventually forms a soot cake layer on the surface of the DPF inlet channel walls. A densely packaged soot layer and reduced pore size due to Particulate Matter (PM) deposition will reduce overall DPF wall permeability which results in increasing pressure drop across the DPF substrate. A regeneration process needs to be enacted to burn out all the soot collected inside the DPF. Soot mass is not always evenly distributed as the distribution is affected by the flow and temperature distribution at the DPF inlet. As a result, the heat release which is determined by the burn rate is locally dependent. High temperature gradients are often found inside DPF substrate as a result of these locally dependent burn rates.

Recent measurements in transient diesel jets have shown that fuel in the wake of the injection pulse mixes with ambient gases more rapidly than in a steady jet. This rapid mixing after the end of injection (EOI) can create fuel-lean regions near the fuel injector. These lean regions may not burn to completion for conditions where autoignition occurs after EOI, as is typical of low-temperature combustion (LTC) diesel engines. In this study, transient diesel jets are analyzed using a simple one-dimensional jet model. The model predicts that after EOI, a region of increased entrainment, termed the “entrainment wave,” travels downstream at twice the initial jet propagation rate. The entrainment wave increases mixing by up to a factor of three. This entrainment wave is not specific to LTC jets, but rather it is important for both conventional diesel combustion and LTC conditions.

Automotive engines are regularly utilized in the material handling market where LPG is often the primary fuel used. When compared to gasoline, the use of gaseous fuels (LPG and CNG) as well as alcohol based fuels, often result in significant increases in valve seat insert (VSI) and valve face wear. This phenomenon is widely recognized and the engine manufacturer is tasked to identify and incorporate appropriate valvetrain material and design features that can meet the ever increasing life expectations of the end-user. Alternate materials are often developed based on laboratory testing – testing that may not represent real world usage. The ultimate goal of the product engineer is to utilize accelerated lab test procedures that can be correlated to field life and field failure mechanisms, and then select appropriate materials/design features that meet the targeted life requirements.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

Spray-guided gasoline direct injection SI engines attract as one of new generation lean-burn engines to promise CO2 reduction. These typically adopt “narrow-spacing” concept in which an injector is centrally mounted close to a spark plug. Therefore, geometric targets of the fuel spray and a position of the spark plug have to be exactly limited to maintain a proper mixture in the spark gap. In addition, the stable combustion window is narrow because the spark ignition is limited in a short time during and immediately after the injection. These spatial and temporal restrictions involve some intractable problems concerning the combustion robustness due to the complicate phenomena around the spark plug. The local mixture preparation near the spark plug significantly depends on the spray-induced charge motion. The intense flow induced by the motion blows out and stretches the spark, thereby affecting the spark discharge performance.

The challenges of flex-fuel vehicle (FFV) emissions measurements have recently come to the forefront for the emissions testing community. The proliferation of ethanol blended gasoline in fractions as high as 85% has placed a new challenge in the path of accurate measures of NMHC and NMOG emissions. Test methods need modification to cope with excess amounts of water in the exhaust, assure transfer and capture of oxygenated compounds to integrated measurement systems (impinger and cartridge measurements) and provide modal emission rates of oxygenated species. Current test methods fall short of addressing these challenges. This presentation will discuss the challenges to FFV testing, modifications made to Ford Motor Company’s Vehicle Emissions Research Laboratory test cells, and demonstrate the improvements in recovery of oxygenated species from the vehicle exhaust system for both regulatory measurements and development measurements.

A production version of a V-8 engine was redesigned to run on partially premixed charge compression ignition (PCCI) combustion mode with conventional diesel fuel. The objective of the PCCI combustion experiments was to obtain low engine-out nitrogen oxide (NOx) and after-treatment tolerant soot emission level. Two fuel injection strategies were used during the PCCI combustion experiments: a) pilot-with-main injection strategy (Pil-M), b) pilot-with-main-and-post (PMP) injection strategy. In the Pil-M injection strategy, a significant fraction of the fuel was delivered early during the compression stroke. The early pilot helped to prepare a lean-mixture of enhanced homogeneity before the combustion was initiated. The combustion of this pilot injection followed by the main combustion helped to reduce soot for a constant NOx value. The pilot-injection timing and quantity had to be selected appropriately to retain the fuel-efficiency.

The upcoming Euro VI emission legislation for Heavy Duty Diesel engines can be complied with by using a combination of a wall flow DPF and a UREA SCR-system. This paper describes investigations of NOx and PM reduction by a combination of SCR-catalyst and an (uncoated) Diesel particulate filter (DPF), performed on a fully transient heavy-duty test bench. Soot loading and passive regeneration of the DPF for different configurations of both components and active regeneration by fuel injection into the exhaust gas line were investigated. The impact of DPF on SCR-catalyst as well as SCR-catalyst impact on DPF was analyzed in terms of NOx-conversion and regeneration efficiency of the filter under steady-state and transient operating conditions. The NOx-conversions for the configuration SCR-catalyst in front of DPF were higher for all operating conditions than for the combination DPF in front of SCR-catalyst.

A promising SCR-only solution is presented to meet post-2010 NOx emission targets for heavy duty applications. The proposed concept is based on an engine from a EURO IV SCR application, which is considered optimal with respect to fuel economy and costs. The addition of advanced SCR after treatment comprising a standard and a close-coupled SCR catalyst offers a feasible emission solution, especially suited for EURO VI. In this paper, results of a simulation study are presented. This study concentrates on optimizing SCR deNOx performance. Simulation results of cold start FTP and WHTC test cycles are presented to demonstrate the potential of the close-coupled SCR concept. Comparison with measured engine out emissions of an EGR engine shows that a close-coupled SCR catalyst potentially has NOx reduction performance as good as EGR. Practical issues regarding the use of an SCR catalyst in close-coupled position will be addressed, as well as engine and exhaust layout.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as effective for controlling NOx emissions from diesel engines, maintaining high NOx conversion even after the extended high temperature exposure encountered in systems with active filter regenerations. As future diesel emission regulations are expected to be further reduced, packaging a large volume of SCR catalysts in diesel exhaust systems, along with DOC and particulate filter catalysts, will be challenging. One method to reduce the total volume of catalysts in diesel exhaust systems is to combine the SCR and DPF catalysts by coating SCR catalyst technology on particulate filters. In this work, engine evaluation of SCR coated filters has been conducted to determine the viability of the technology. Steady-state engine evaluations demonstrated that high NOx conversions can be achieved for SCR coated filters after high temperature oven aging.

A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.

A laboratory study was performed to assess the effects of SO2 poisoning on the NOx conversion of iron (Fe) and copper (Cu) SCR catalysts. Thermally aged samples of the catalysts were poisoned with SO2 under lean conditions. At various times during the poisonings, the samples were evaluated for NOx conversion with NO and NH3 using lean temperature ramps. The low temperature NOx conversions of both catalysts decreased by 10 to 20% after 1 to 4 hours of poisoning but were stable with continued exposure to the SO2. The poisoned Cu SCR catalyst could be desulfated repeatedly with 5 minutes of lean operation at 600°C. Initially, the poisoned Fe SCR catalyst required 5 minutes of lean operation at 750°C to recover its maximum NOx conversion.