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The capabilities of the JPL Electronic Nose have been expanded to include characteristics required for a Technology Demonstration schedule on the International Space Station (ISS) in 2008-2009 [1,2]. Concurrently, to accommodate specific needs on ISS, the processes, tools and analyses which influence all aspects of development of the device have also been expanded. The Third Generation ENose developed for this program uses two types of sensor substrates, newly developed inorganic and organic sensor materials, redesigned electronics, onboard near real-time data analysis and power and data interfaces specifically for ISS. This paper will discuss the Third Generation ENose with a focus on detection of mercury in the parts-per-billion range.

We have elicited a reliable Raman spectral signature for glucose in rabbit aqueous humor across mammalian physiological ranges in a rabbit model stressed by recent myocardial infarction. The technique employs near infrared Raman laser excitation at 785 nm, multivariate analysis, non-linear artificial neural networks and an offset spectra subtraction strategy. Aqueous humor glucose levels ranged from 37 to 323 mg/dL. Data were obtained in 80 uL samples to anticipate the volume constraints imposed by the human and rabbit anterior chamber of the eye. Total sample collection time was 10 seconds with total power delivered to sample of 30 Mw. Spectra generated from the aqueous humor were compared qualitatively to artificial aqueous samples and an excitation offset technique was devised to counteract broadband background noise partially obscuring the glucose signature.

A miniaturized electronic nose has been constructed at JPL in collaboration with Caltech. This array of conductometric sensors has been trained to detect and quantify the presence of vapors in the air; the compounds detected have been found as contaminants in shuttle air. This device has potential application as a miniature, distributed device for monitoring and controlling the constituents in air.

The Mars Scout Phoenix Lander successfully landed in the Martian northern latitude on May 25, 2008. The Robotic Arm, which was designed to dig and to transfer soil samples to other Lander instruments, contained a number of actuators that had specific operational windows on the Martian surface due to the bearing lubricant. The deployment of the Robotic Arm was planned for Sol 2 (Mars days are referred to “Sols”). A few weeks before Mars landing, the Robotic Arm operations team learned that a strict flight rule had been imposed. It specified that the deployment shall be accomplished when the actuators were at or above −25°C since the deployment activity was qualified with the actuators at −40°C. Furthermore, the deployment plan identified a window of opportunity between 13:00 Local Solar Time (LST, equivalent to dividing the Sol into 24 equal Martian hours) and 15:30 LST.

Simultaneous measurements were made for particle releases and off-gassing products produced by heating electrical wires. The wire samples in these experiments were heated to selected temperatures in a heating chamber and responses to vapor releases were recorded by the JPL Electronic Nose (ENose) and an Industrial Scientific ITX gas-monitor; particles released were detected by a TSI P-Trak particle counter. The temperature range considered for the experiment is room temperature (24−26°C) to 500 °C. The results were analyzed by overlapping responses from the ENose, ITX gas sensors and P-Trak, to understand the events (particle release/off-gassing) and sequence of events as a function of temperature and to determine qualitatively whether ENose may be used to detect pre-combustion event markers.

This paper describes results acquired from E-Tongue 2 and E-Tongue 3 which are arrays of planar three-element electrochemical cells and pH sensors. The approach uses ASV (Anodic Stripping Voltammery) to achieve a detection limit, which in the case of Pb, is below one μM which is needed for water quality measurements. The richness of the detectable species is illustrated with Fe where seven species are identified using the Pourbiax diagram. The detection of multiple species is illustrated using Pb and Cu. The apparatus was used to detect the electroactivity of the metabolic-surrogate, PMS (phenazine-methosulphate). Finally, four types of pH sensors were fabricated and characterized for linearity, sensitivity, and responsiveness.

A technology demonstration propylene Loop Heat Pipe (LHP) has been tested extensively in support of the implementation of this two-phase thermal control technology on NASA’s Earth Observing System (EOS) Tropospheric Emission Spectrometer (TES) instrument. This cryogenic instrument is being developed at the Jet Propulsion Laboratory (JPL) for NASA. This paper reports on the transient characterization testing results showing low frequency temperature oscillations. Steady state performance and model correlation results can be found elsewhere. Results for transient startup and shutdown are also reported elsewhere. In space applications, when LHPs are used for thermal control, the power dissipation components are typically of large mass and may operate over a wide range of power dissipations; there is a concern that the LHP evaporator may see temperature oscillations at low powers and over some temperature range.

The Mars Exploration Rover (MER) flight system uses mechanical, paraffin-actuated heat switches as part of its secondary battery thermal control system. This paper describes the design, flight qualification, and performance of the heat switch. Although based on previous designs by Starsys Research Corporation1,2, the MER mission requirements have necessitated new design features and an extensive qualification program. The design utilizes the work created by the expansion of a paraffin wax by bringing into contact two aluminum surfaces, thereby forming a heat conduction path. As the paraffin freezes and contracts, compression springs separate the surfaces to remove the conduction path. The flight qualification program involved extensive thermal performance, structural, and life testing.

Phoenix, NASA's first Mars Scouts mission, will be launched in 2007 and will soft-land inside the Martian Arctic Circle, between north 65° and 72° North latitude, in 2008 to study the water history and to search for habitable zones. Similar to the IDD (Instrument Deployment Device) on the Mars Exploration Rovers (MER), Phoenix has a Robotic Arm (RA) which is equipped with a scoop to dig into the icy soil and to deliver the soil samples to instruments for scientific observations and measurements. As with MER, the actuators and the bearings of the Phoenix RA in a non-operating condition can survive the cold Martian night without any electrical power or any thermal insulation. The RA actuators have a minimum operating allowable flight temperature (AFT) limit of -55°C, so, warm-up heaters are required to bring the temperatures of all the RA actuators above the operating AFT limit prior to early morning operation.

An array-based sensing system based on polymer-carbon composite conductometric sensors is under development at JPL for use as an environmental monitor in the International Space Station. Sulfur dioxide has been added to the analyte set for this phase of development. Using molecular modeling techniques, the interaction energy between SO2 and polymer functional groups has been calculated, and polymers selected as potential SO2 sensors. Experiment has validated the model and two selected polymers have been shown to be promising materials for SO2 detection.

An array-based sensing system based on 32 polymer/carbon composite conductometric sensors is under development at JPL. Until the present phase of development, the analyte set has focused on organic compounds (common solvents) and a few selected inorganic compounds, notably ammonia and hydrazine. The present phase of JPL ENose development has added two inorganics to the analyte set: mercury and sulfur dioxide. Through models of sensor-analyte response developed under this program coupled with a literature survey, approaches to including these analytes in the ENose target set have been determined.

Certain Eubacteria enter a viable but nonculturable (VBNC) state upon encountering unfavorable environmental conditions. VBNC cells do not divide on conventional media yet remain viable and in some cases retain virulence. Here, we describe the VBNC state of two opportunistic pathogens previously isolated from ISS potable waters, Burkholderia cepacia and Stenotrophomonas maltophilia. Artificially inoculated microcosms were exposed to the biocidal agents copper (CuSO4) and iodine (I2) in an attempt to induce nonculturablility. Viability was assessed via fluorescent microscopy (direct viable count assay coupled with BacLight™ staining) and metabolic activity was monitored by quantifying both intracellular ATP and transcribed rRNA (reverse transcriptase quantitative PCR). Culturablility was lost in both B. cepacia and S. maltophilia within two days of exposure to copper or high concentrations of iodine (6 or 8 ppm).

The Mars Science Laboratory will be the next Martian mobility system that is scheduled to launch in the fall of 2011. The ChemCam Instrument is a part of the MSL science payload suite. It is innovative for planetary exploration in using a technique referred to as laser breakdown spectroscopy to determine the chemical composition of samples from distances of up to about 9 meters away. ChemCam is led by a team at the Los Alamos National Laboratory and the Centre d'Etude Spatiale des Rayonnements in Toulouse, France. The portion of ChemCam that is located inside the Rover, the ChemCam Body Unit contains the imaging charged-coupled device (CCD) detectors. Late in the design cycle, the ChemCam team explored alternate thermal design architectures to provide CCD operational overlap with the Rover's remote sensing instruments. This operational synergy is necessary to enable planning for subsequent laser firings and geological context.

As a result of the Viking missions in 1970s, the presence of a strong oxidant in Martian soil was suggested. Here we present a testable, by near-term missions, hypothesis that iron(VI) contributes to that oxidizing pool. Ferrate(VI) salts were studied for their spectral and oxidative properties and biological activities. Ferrate(VI) has distinctive spectroscopic features making it available for detection by remote sensing reflectance spectra and contact measurements via Mössbauer spectroscopy. The relevant miniaturized instrumentation has been developed or is underway, while XANES spectroscopy is shown to be a method of choice for the returned samples. Ferrate(VI) is capable of splitting water to yield oxygen, and oxidizing organic carbon to CO2. Organic oxidation was strongly abated after pre-heating ferrate, similar to the observations with Mars soil samples.

The development of tunable diode laser systems in the 2 - 5 μm spectral region will have numerous applications for trace gas detection. To date, the development of such systems has been hampered by the difficulties of epitaxial growth, and device processing in the case of the Sb-based materials system. One of the compounding factors in this materials system is the use of aluminum containing compounds in the laser diode cladding layers. This makes the regrowth steps used in traditional lasers very difficult. As an alternative approach we are developing laterally coupled antimonide based lasers structures that do not require the regrowth steps. In this paper, the materials growth, device processing and development of the necessary drive electronics for an antimony based tunable diode laser system are discussed.

A flight experiment to test the operation of an Electronic Nose developed and built at JPL and Caltech was done aboard STS-95 in October-November, 1998. This ENose uses conductometric sensors made of insulating polymer-carbon composite films; it has a volume of 1.7 liters, weighs 1.4 kg including the operating computer and operates on 1.5 W average power. In the flight experiment, the ENose was operated continuously for 6 days and recorded the sensors' response to changes in air in the mid-deck of the orbiter. The ENose had been trained to identify and quantify ten common contaminants at the 24-hour Spacecraft Maximum Allowable Concentration (SMAC) level. Most SMACs are on the order of 10-100 ppm. The experiment was controlled by collecting air samples daily and analyzing them using standard analytical techniques after the flight. The device is microgravity insensitive.

The Jet Propulsion Laboratory Mars Exploration Program Office is currently planning a series of exciting missions to the Red Planet. During each launch opportunity, the missions to Mars will include a Rover mission. During the earlier Rover missions to Mars such as the Mars Pathfinder mission carrying the Sojourner Rover in 1997, the main rover power source was a solar array. The power subsystem of the Sojourner Rover included a solar panel for power during the day, a non-rechargeable lithium battery for power during the night, and a power electronics board for power conditioning and distribution. Starting with the year 2003 the rover missions to Mars will incorporate a rechargeable energy storage device rather than a non-rechargeable power source. Included in the power electronics board, will be a battery controller/charger. The battery controller/charger will be able to monitor and control three parallel 4-cell battery strings.

The power produced by an AMTEC is dependent on the porosity of the electrode layers deposited on the surface of the BASE tubes. The elevated temperatures at which these power generators operate result in a slow growth or coalescence of the grains that comprise the electrode layers thereby reducing porosity and effective surface area. The lifetime of AMTEC electrodes is therefore related to the rate of grain growth of the electrode material. A preliminary model has been developed to determine the rate of grain growth over the operational lifetime of an AMTEC. This model examines the conditions for continuous growth as a function of the relative sizes, boundary and activation energies and mobilities of the grains. An assumption of strain-free growth has been made in determining the factors for normal growth. Experimental measurements for titanium nitride alloy electrodes are compared with this model. Predictions are made for performance lifetimes out to 10 years.

The lifetime of an AMTEC electrode is predicted from the rate of grain growth in the electrode. The rate of growth depends on several physical characteristics of each material, including the rate of diffusion of the material on itself. Grain growth rates for rhodium-tungsten and titanium nitride electrodes have been determined, and have been used to predict operating lifetimes of AMTEC electrodes. For lifetimes of 10 years or more, RhxW electrodes may be used at any operating temperature supportable by the electrolyte. TiN electrodes may be used in AMTEC cells only at operating temperatures under 1150 K.

This paper reports several slow reversible and quasi-reversible processes which occur in the porous electrode/solid electrolyte combination at AMTEC operating temperatures. These processes help to elucidate the evolution of the electrode and electrolyte characteristics with time. They also demonstrate that the atomic constituents of the electrode/electrolyte engage in significant dynamic motion. We report the stability of the sodium beta“-alumina phase in low pressure sodium vapor at 1173K up to 3000 hours, and the decomposition of the sodium meta-aluminate (NaAlO2) phase present at about 1% in the BASE ceramic, which gives rise to transient local increases in the solid electrolyte resistivity due to local micro-cracking. We also report slow apparent morphological changes, possibly surface or grain boundary reconstruction, in TiN and RhW electrodes driven by changes in the local sodium activity.