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Journal Article

Development of Trivalent Chromium Passivation for Zn Platng with High Corrosion Resistance after Heating

2016-04-05
2016-01-0542
Trivalent chromium passivation is used after zinc plating for enhancing corrosion resistance of parts. In the passivating process, the amount of dissolved metal ions (for example zinc and iron) in the passivation solution increases the longer the solution is used. This results in a reduced corrosion resistance at elevated temperatures. Adding a top coat after this process improves the corrosion resistance but has an increased cost. To combat this, we strove to clarify the mechanism of decreased corrosion resistance and to develop a trivalent chromium passivation with a higher corrosion resistance at elevated temperatures. At first, we found that in parts produced from an older solution, the passivation layer has cracks which are not seen in parts from a fresh/new solution. These cracks grow when heated at temperatures over 120 degrees Celsius.
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