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Pending reductions in light duty vehicle PM emissions standards from 10 to 3 mg/mi and below will push the limits of the gravimetric measurement method. At these levels the PM mass collected approaches the mass of non-particle gaseous species that adsorb onto the filter from exhaust and ambient air. This introduces an intrinsic lower limit to filter based measurement that is independent of improvements achieved in weighing metrology. The statistical variability of back-up filter measurements at these levels makes them an ineffective means for correcting the adsorption artifact. The proposed subtraction of a facility based estimate of the artifact will partially alleviate the mass bias from adsorption, but its impact on weighing variability remains a problem that can reach a significant fraction of the upcoming 3 and future 1 mg/mi standards. This paper proposes an improved PM mass method that combines the gravimetric filter approach with real time aerosol measurement.

In order to meet more stringent evaporative emissions requirements, multiple advancements in vehicle fuel system and carbon canister technologies have been made. Regardless of technological advancements, the vapor pressure of the fuel remains a vital property in controlling evaporative emissions. A series of tests were performed to explore the effects of vapor pressure on multiday diurnal evaporative emissions for 9 and 10 psi Reid Vapor Pressure (RVP) 10% ethanol (E10) gasoline-blend fuels, followed by tests with 7 psi RVP E10 gasoline on a subset of the same vehicles. A test procedure was developed to monitor evaporative emissions, canister loading profiles and breakthrough emissions for each of the fuels. A total of five vehicles were tested on all 3 fuels, blended to represent 7, 9, and 10 psi at sea level. Tests were run over 14 days using the United States (U.S.)

U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.

Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).

A great deal of current automotive engineering effort involves the development of three-way catalyst-based emission control systems that seek to minimize fuel consumption while simultaneously meeting stringent exhaust emission standards. Mitigation of emissions is enhanced in a three-way catalyst system when the system air-fuel ratio (A/F) is in proximity to ideal burning or stoichiometry. This paper is concerned with extending methods used for determining engine calibrations to closed-loop systems with three-way catalysts. The paper presents a simulation model that employs experimentally obtained data to characterize the A/F control loop.