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The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

The combined anticipated trends of vehicle sharing (ride-hailing), automated control, and powertrain electrification are poised to disrupt the current paradigm of predominately owner-driven gasoline vehicles with low levels of utilization. Shared, automated, electric vehicle (SAEV) fleets offer the potential for lower cost and emissions and have garnered significant interest among the research community. While promising, unmanaged operation of these fleets may lead to unintended negative consequences. One potentially unintended consequence is a high quantity of SAEVs charging during peak demand hours on the electric grid, potentially increasing the required generation capacity. This research explores the flexibility associated with charging loads demanded by SAEV fleets in response to servicing personal mobility travel demands. Travel demand is synthesized in four major United States metropolitan areas: Detroit, MI; Austin, TX; Washington, DC; and Miami, FL.

The Energy Independence and Security Act of 2007 requires the U.S. to use 36 billion gallons of renewable fuel per year by 2022. Domestic ethanol production has increased steadily in recent years, growing from less than 5 billion gallons per year (bgpy) in 2006 to over 13 bgpy in 2010. While there is interest in developing non-oxygenated renewable fuels for use in conventional vehicles as well as interest in expanding flex-fuel vehicle (FFV) production for increased E85 use, there remains concern that EISA compliance will require further use of oxygenated biofuels in conventional vehicles. The Environmental Protection Agency (EPA) recently granted partial approval to a waiver allowing the use of E15 in 2001 and newer light-duty vehicles.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.

The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Hydrogen fuel cell vehicles (FCVs) appear to be a promising solution for the future of clean and efficient personal transportation. Issues of how to generate the hydrogen and then store it on-board to provide satisfactory driving range must still be resolved before they can compete with conventional vehicles. Alternatively, FCVs could obtain hydrogen from on-board reforming of gasoline or other fuels such as methanol or ethanol. On-board reformers convert fuel into a hydrogen-rich fuel stream through catalytic reactions in several stages. The high temperatures associated with fuel processing present an engineering challenge to warm up the reformer quickly and efficiently in a vehicle environment. Without a special warmup phase or vehicle hybridization, the reformer and fuel cell system must provide all power to move the vehicle, including ¼ power in 30 s, and ½ power in 3 min to satisfy the Federal Test Procedure (FTP) cycle demands.

How much fuel does vehicle air conditioning actually use? This study attempts to answer that question to determine the national and state-by-state fuel use impact seen by using air conditioning in light duty gasoline vehicles. The study used data from US cities, representative of averages over the past 30 years, whose temperature, incident radiation, and humidity varied through time of day and day of year. National surveys estimated when people drive their vehicles during the day and throughout the year. A simple thermal comfort model based on Fanger's heat balance equations determined the percentage of time that a driver would use the air conditioning based on the premise that if a person were dissatisfied with the thermal environment, they would turn on the air conditioning. Vehicle simulations for typical US cars and trucks determined the fuel economy reduction seen with AC use.

In-use, light-duty vehicles were recruited in Cary, North Carolina for emissions testing on a transportable dynamometer in 1999. Two hundred forty-eight vehicles were tested in as received condition using the IM240 driving cycle. The study was conducted in two phases, a summer and winter phase, with half of the vehicles recruited during each phase. Regulated emissions, PM10, carbonaceous PM, aldehydes and ketones were measured for every test. PM2.5, individual volatile hydrocarbons, polycyclic aromatic hydrocarbons, sterane and hopane emissions were measured from a subset of the vehicles. Average light-duty gasoline PM10 emission rates increased from 6.5 mg/mi for 1993-97 vehicles to 53.8 mg/mi for the pre-1985 vehicles. The recruited fleet average, hot-stabilized IM240 PM10 emission rate for gasoline vehicles was 19.0 mg/mi.

Knock-limited loads for a set of surrogate gasolines all having nominal 100 research octane number (RON), approximately 11 octane sensitivity (S), and a heat of vaporization (HOV) range of 390 to 595 kJ/kg at 25°C were investigated. A single-cylinder spark-ignition engine derived from a General Motors Ecotec direct injection (DI) engine was used to perform load sweeps at a fixed intake air temperature (IAT) of 50 °C, as well as knock-limited load measurements across a range of IATs up to 90 °C. Both DI and pre-vaporized fuel (supplied by a fuel injector mounted far upstream of the intake valves and heated intake runner walls) experiments were performed to separate the chemical and thermal effects of the fuels’ knock resistance. The DI load sweeps at 50°C intake air temperature showed no effect of HOV on the knock-limited performance. The data suggest that HOV acts as a thermal contributor to S under the conditions studied.

A relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from direct injection spark ignition (DISI) vehicles. The fundamental cause of this observation is not well understood. One potential explanation is that increased evaporative cooling as a result of ethanol’s high HOV may slow evaporation and prevent sufficient reactant mixing resulting in the combustion of localized fuel rich regions within the cylinder. In addition, it is well known that ethanol when blended in gasoline forms positive azeotropes which can alter the liquid/vapor composition during the vaporization process. In fact, it was shown recently through a numerical study that these interactions can retain the aromatic species within the liquid phase impeding the in-cylinder mixing of these compounds, which would accentuate PM formation upon combustion.

This paper describes an experimental study to determine the potential for fuel efficiency improvements offered by dedicated, high compression E85 engines with optimized powertrain calibration strategies. The study involved a prototype variable fuel engine that could operate using either gasoline or E85, and a high compression version of the same engine that was suitable only for E85. Fuel consumption and engine-out emissions were evaluated using steady-state engine dynamometer tests to represent urban and highway speed/load conditions. For each fuel and engine combination, the fuel efficiency and emissions trade-offs provided by varying Exhaust Gas Recirculation (EGR) levels were determined. For the high compression engine, operation at lower speed/higher load conditions (producing the same power as the standard speed/load settings) was also investigated.

Evaporative cooling of the fuel-air charge by fuel evaporation is an important feature of direct-injection spark-ignition engines that improves fuel knock resistance and reduces pumping losses at intermediate load, but in some cases, may increase fine particle emissions. We have reported on experimental approaches for measuring both total heat of vaporization and examination of the evaporative heat effect as a function of fraction evaporated for gasolines and ethanol blends. In this paper, we extend this work to include other low-molecular-weight alcohols and present results on species evolution during fuel evaporation by coupling a mass spectrometer to our differential scanning calorimetry/thermogravimetric analysis instrument. The alcohols examined were methanol, ethanol, 1-propanol, isopropanol, 2-butanol, and isobutanol at 10 volume percent, 20 volume percent, and 30 volume percent.

This work explores the impact of the interaction of lubricant and fuel properties on the propensity for stochastic pre-ignition (SPI). Findings are based on statistically significant changes in SPI tendency and magnitude, as determined by measurements of cylinder pressure. Specifically, lubricant detergents, lubricant volatility, fuel volatility, fuel chemical composition, fuel-wall impingement, and engine load were varied to study the physical and chemical effects of fuel-lubricant interactions on SPI tendency. The work illustrates that at low loads, with fuels susceptible to SPI events, lubricant detergent package effects on SPI were non-significant. However, with changes to fuel distillation, fuel-wall impingement, and most importantly engine load, lubricant detergent effects could be observed even at reduced loads This suggests that there is a thermal effect associated with the higher load operation.

Several high octane number oxygenates that could be derived from biomass were blended with gasoline and examined for performance properties and their impact on knock resistance and fine particle emissions in a single cylinder direct-injection spark-ignition engine. The oxygenates included ethanol, isobutanol, anisole, 4-methylanisole, 2-phenylethanol, 2,5-dimethyl furan, and 2,4-xylenol. These were blended into a summertime blendstock for oxygenate blending at levels ranging from 10 to 50 percent by volume. The base gasoline, its blends with p-xylene and p-cymene, and high-octane racing gasoline were tested as controls. Relevant gasoline properties including research octane number (RON), motor octane number, distillation curve, and vapor pressure were measured. Detailed hydrocarbon analysis was used to estimate heat of vaporization and particulate matter index (PMI). Experiments were conducted to measure knock-limited spark advance and particulate matter (PM) emissions.