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This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

The distribution of fuel-air mixtures in many L-head engines is not homogeneous. If local mixture is too rich or lean, incomplete combustion occurs. This can play a major role in unburned hydrocarbon and carbon monoxide emissions. Fuel-air mixture distribution depends on in-cylinder swirl and turbulence and is directly related to intake manifold configuration, fuel delivery system design and combustion chamber shape. Understanding the spatial mixture distribution may help improve the design of these aforementioned components. Consequently, a more complete combustion process may result, and emissions reduced. A method that measures the emission of CH and C2 radicals via the use of an optical fiber bundle was used in this research to map the mixture uniformity in the combustion chamber. The intensity ratio (IC2/ICH) was correlated to the fuel-air equivalence ratio. The mixture distribution measured was then correlated with the hydrocarbon emission sequence.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.

A laboratory test reactor has been used to determine the rates of oxidation of carbon monoxide (CO), hydrocarbons (HCs) as a class, and hydrogen (H2). The feed was supplied from the exhaust of a single-cylinder engine, with additions of H2 and CO in some runs. The test reactor was designed to be well mixed, and this was verified experimentally for mixing on macroscopic and microscopic scales. Wall effects were found to be unimportant. Kinetic data from 157 runs were correlated with global reaction rate expressions containing Arrhenius temperature dependence and power law concentration dependence. CO oxidation was found to be approximately 1/4 order in CO with an activation energy of 28,200 cal/g-mole. HC oxidation was found to be approximately 1/4 order in HC and 1/2 order in each of O2, CO, and NO with an activation energy of 29,800 cal/g-mole. H2 oxidation rates were not well correlated, but a zero-order rate with an activation energy of 52,000 cal/g-mole is reasonable.

This paper considers the influence of the properties of gasolines and testing fluids on metering by carburetors. Since the fuel metering is controlled by orifices, the effects of fuel properties on orifice flow are analyzed. The results of an orifice testing program are presented, using the Reynolds number as the primary correlation parameter. The influences of fuel type, fuel temperature, and orifice geometry on the discharge coefficient are discussed, and the effect of a given fuel property change is shown. Experimental values for the variations in fluid properties with fuel type and temperature are presented for commercial gasolines, carburetor testing fluids, and pure hydrocarbons. The variation of carbon-to-hydrogen ratio among gasolines is shown to cause a change in stoichiometry, which is the equivalent of an error in metering.