Search Results

Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.

Experimentally obtained energy release results, a semi-empirical ignition model, and an empirical energy release equation developed during this research were used to evaluate the combustion of compression-ignited homogeneous mixtures of fuel, air, and exhaust products in a CFR engine. A systematic study was carried out to evaluate the response of compression-ignited homogeneous charge (CIHC) combustion to changes in operating parameters with emphasis being placed on the phenomena involved rather than the detailed chemical kinetics. This systematic study revealed that the response of the combustion process to changes in operating parameters can be explained in terms of known chemical kinetics, and that through the proper use of temperature and species concentrations the oxidation kinetics of hydrocarbon fuels can be sufficiently controlled to allow an engine to be operated in a compression-ignited homogeneous charge combustion mode.