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Measurements of the soot emissions and engine operating parameters from a diesel engine during transient operation were used to investigate the influence of transient operation on the soot emissions, as well as to validate a realtime mean value soot model (MVSM, [1]) for transient operation. To maximize the temporal resolution of the soot emission and engine parameter measurements (in particular EGR), fast instruments were used and their dynamic responses characterized and corrected. During tip-in transients, an increase in the soot emissions was observed due to a short term oxygen deficit compared to steady-state operation. No significant difference was seen between steady-state and transient operation for acceleration transients. When the MVSM was provided with inputs of sufficient temporal resolution, it was capable of reproducing the qualitative and, in part, quantitative soot emission trends.

This paper presents numerical simulations of in-cylinder soot evolution in the optically accessible heavy-duty diesel engine of Sandia Laboratories performed with the conditional moment closure (CMC) model employing a reduced n-heptane chemical mechanism coupled with a two-equation soot model. The influence of exhaust gas recirculation (EGR) on in-cylinder processes is studied considering different ambient oxygen volume fractions (8 - 21 percent), while maintaining intake pressure and temperature as well as the injection configuration unchanged. This corresponds to EGR rates between 0 and 65 percent. Simulation results are first compared with experimental data by means of apparent heat release rate (AHRR) and temporally resolved in-cylinder soot mass, where a quantitative comparison is presented. The model was found to fairly well reproduce ignition delays as well as AHRR traces along the EGR variation with a slight underestimation of the diffusion burn portion.

Future engine emission legislation regulates soot from Diesel engines strictly and requires improvements in engine calibration, fast response sensor equipment and exhaust gas aftertreatment systems. The in-cylinder phenomena of soot formation and oxidation can be analysed using a pyrometer with optical access to the combustion chamber. The pyrometer collects the radiation of soot particles during diffusion combustion, and allows the calculation of soot temperature and a proportional value for the in-cylinder soot density (KL). A four-cylinder heavy-duty Diesel engine was equipped in all cylinders with prototype pyrometers and state of the art pressure transducers. The cylinder specific data was recorded crank angle-resolved for a set of steady-state and transient operating conditions, as well as exhaust gas recirculation (EGR) addition and over a wide range of soot emissions.

Numerical simulations of a heavy-duty diesel engine fuelled with n-heptane have been performed with the conditional moment closure (CMC) combustion model and an embedded two-equation soot model. The influence of exhaust gas recirculation on the interaction between post- and main- injection has been investigated. Four different levels of EGR corresponding to intake ambient oxygen volume fractions of 12.6, 15, 18 and 21% have been considered for a constant intake pressure and temperature and unchanged injection configuration. Simulation results have been compared to the experimental data by means of pressure and apparent heat-release rate (AHRR) traces and in-cylinder high-speed imaging of natural soot luminosity and planar laser-induced incandescence (PLII). The simulation was found to reproduce the effect of EGR on AHRR evolutions very well, for both single- and post-injection cases.

This study investigates n-dodecane split injections of “Spray A” from the Engine Combustion Network (ECN) using two different turbulence treatments (RANS and LES) in conjunction with a Conditional Moment Closure combustion model (CMC). The two modeling approaches are first assessed in terms of vapor spray penetration evolutions of non-reacting split injections showing a clearly superior performance of the LES compared to RANS: while the former successfully reproduces the experimental results for both first and second injection events, the slipstream effect in the wake of the first injection jet is not accurately captured by RANS leading to an over-predicted spray tip penetration of the second pulse. In a second step, two reactive operating conditions with the same ambient density were investigated, namely one at a diesel-like condition (900K, 60bar) and one at a lower temperature (750K, 50bar).

The sooting propensity of dual-fuel combustion with n-dodecane pilot injection in a lean-premixed methane-air charge has been investigated using an optically accessible Rapid Compression-Expansion Machine (RCEM) to achieve engine-relevant pressure and temperature conditions at the start of pilot injection. A Diesel injector with a 100 μm single-hole coaxial nozzle, mounted at the cylinder periphery, has been employed to admit the pilot fuel. The aim of this study was to enhance the fundamental understanding of soot formation and oxidation processes of n-dodecane in the presence of methane in the air charge by parametric variation of methane equivalence ratio, charge temperature, and pilot fuel injection duration. The influence of methane on ignition delay and flame extent of the pilot fuel jet has been determined by simultaneous excited-state hydroxyl radical (OH*) chemiluminescence and Schlieren imaging.

Emission and performance parameters of a medium size, and medium speed D.I. diesel engine equipped with a Miller System, a new developed High Pressure Exhaust Gas Recirculation System (HPEGR), a Common Rail (CR) system and a Turbocharger with Variable Turbine Geometry (VTG) have been measured and compared to the standard engine. While power output, fuel consumption, soot and other emissions are kept constant, nitric oxide emissions could be reduced by 30 to 50% depending on load and for the optimal combination of methods. Heat release rate analysis provides the reasons for the optimised engine behaviour in terms of soot and NOx emissions: The variable Nozzle Turbocharger helps deliver more oxygen to the combustion process (less soot) and lower the peak gas temperature (less NOx).

A mean value soot model (MVSM) was developed and validated for the realtime prediction of the raw, engine-out soot emissions from common rail diesel engines. Through the consideration of five representative states during the combustion cycle, the developed MVSM determines the engine out soot emissions based on the soot formation and oxidation processes, using only parameters available from a standard engine control unit. 16 model parameters are used to describe the engine, fuel, and combustion characteristics, and must be determined for each engine and fuel combination. The MVSM was parameterized and validated using the measured soot emissions from two different engines operating with a total of three different fuels. After parameterization, the MVSM was capable of qualitatively and quantitatively reproducing the soot emissions for operating points throughout the entire operating map, including for operating regimes not considered during the parameterization.

At the Internal Combustion Engines and Combustion Laboratory of the Swiss Federal Institute of Technology in Zurich we are currently developing low emission strategies for heavy duty diesel engines that engine manufacturers can implement to meet stringent emissions regulations. The technologies being studied include high-pressure fuel injection (with common-rail injection system), multiple injection strategies (with pilot or post injections), turbo charging, exhaust gas recirculation (cooled EGR), oxygenated fuels and the optimization of the air management system. This paper focuses on the effects of exhaust gas recirculation (cooled EGR) in combination with very high injection pressure. Measurements were carried out on a heavy-duty diesel single-cylinder research engine equipped with a modern common rail fuel injection. The engine investigations were conducted in different operating points in the engine map covering wide speed and load ranges.

The findings presented in this paper result from a collaboration between two Federal Laboratories in Switzerland. In this research project the characteristics of the particulates from internal combustion engines were investigated in detail. Measurements were carried out on a single-cylinder research engine focusing on exhaust particulate matter emissions. The single-cylinder diesel engine is supercharged and features a common-rail direct injection system. This work analyzes the influence of fuel properties and injection parameters on the particulate number size distribution. For the fuel composition, five different fuels including low sulfur diesel, zero-sulfur and zero-aromatics diesel, two blending portions of oxygenated diesel additive and rapeseedmethylester were used. For the injection parameters the injection pressure, the start of injection and the fuel amount in the pilot- and in the post-injection phases were varied.

This paper deals with the influence of a wall soot layer of varying thickness on the unsteady heat transfer between the fluid and the engine cylinder wall during a full cycle of a four-stroke Diesel engine operation. For that purpose a computational investigation has been carried out, using a one-dimensional model of a multi-layer solid wall for simulating the transient response within the confinement of the combustion chamber. The soot layer is thereby of varying thickness over time, depending on the relative rates of deposition and oxidation. Deposition is accounted for due to a thermophoretic mechanism, while oxidation is described by means of an Arrhenius type expression. Results of the computations obtained so far show that the substrate wall temperature has a significant effect on the soot layer dynamics and thus on the wall heat flux to the combustion chamber wall.

The relative amounts of heat released by premixed and by diffusion controlled combustion is varied in a compression-ignition engine run on the test bench through variation of four operating parameters. Exhaust gas is led to a differential mobility particle sizer and to filters that are loaded for gravimetric analysis. Particle size distributions are acquired in the 16÷630 nm range of electrical mobility diameters. Opacity readings of the exhaust gas are taken, cylinder pressure is indicated, a value for the combustion noise is computed; gaseous emissions are recorded and heat release rates based on cylinder pressure analysis are evaluated. Two full factorial experiments at 2 bar bmep 2000 rpm are run as 24 combinations of four factors: Injection pressure 400 and 1200 bar, with and without pilot injection, 1/3 and 1/4 mass-fraction exhaust gas recirculation, late, middle and early start of injection.

Past research has shown that post injections have the potential to reduce Diesel engine exhaust PM concentration without any significant influence in NOx emissions. However, an accurate, widely applicable rule of how to parameterize a post injection such that it provides a maximum reduction of PM emissions does not exist. Moreover, the underlying mechanisms are not thoroughly understood. In past research, the underlying mechanisms have been investigated in engine experiments, in constant volume chambers and also using detailed 3D CFD-CMC simulations. It has been observed that soot reduction due to a post injection is mainly due to two reasons: increased turbulence from the post injection during soot oxidation and lower soot formation due to lower amount of fuel in the main combustion at similar load conditions. Those studies do not show a significant temperature rise caused by the post injection.

Past research has shown that post injections have the potential to reduce Diesel engine exhaust PM concentration without any significant influence in the NOx emissions. In earlier research it was observed that soot reduction due to a post injection is based on three reasons: increased turbulence (1) and heat (2) from the post injection during soot oxidation and lower soot formation due to smaller main injection for similar load conditions (3). The second effect of heat addition during the soot oxidation is debated in the literature. The experimental investigation presented in the current work provides insight into the underlying mechanisms of soot formation and reduction using post injections under different operating conditions. The experimental data have been obtained using a cylindrical constant volume chamber with high optical access. The soot evolution has been obtained using 2-color-pyrometry.

In this study, numerical simulations of in-cylinder processes associated to fuel post-injection in a diesel engine operated at Low Temperature Combustion (LTC) have been performed. An extended Conditional Moment Closure (CMC) model capable of accounting for an arbitrary number of subsequent injections has been employed: instead of a three-feed system, the problem has been described as a sequential two-feed system, using the total mixture fraction as the conditioning scalar. A reduced n-heptane chemical mechanism coupled with a two-equation soot model is employed. Numerical results have been validated with measurements from the optically accessible heavy-duty diesel engine installed at Sandia National Laboratories by comparing apparent heat release rate (AHRR) and in-cylinder soot mass evolutions for three different start of main injection, and a wide range of post injection dwell times.

Oxygenated fuel additives are currently an important research topic for particulate emissions reduction in diesel engines with direct injection (DI) to meet future emission regulations. In this work more than twenty oxygenated hydrocarbons from the literature were considered as diesel fuel additives. Butylal (an acetal compound, chemical formula C9H20O2) offers significant advantages over most other oxygenates in that its physical properties are very close to those of common diesel fuel. Wear scar measurements were conducted to evaluate the lubricity characteristics of diglyme (C6H14O3), ethyldiglyme (C8H18O3), butylal and different diesel-butylal mixtures. The results reveal the low lubricity of all oxygenated compounds. Thus, for the engine tests, a lubricity improver has been added to the diesel-butylal mixtures.

Formation of soot in an auto-igniting n-dodecane spray under diesel engine relevant conditions has been investigated numerically. As opposed to research addressing turbulence-chemistry interaction (TCI) by coupling diffusive turbulence models with more sophisticated models in the context of Reynolds-Averaged Navier-Stokes equations (RANS), this study employs the advanced sub-grid scale k-equation model in the framework of a Large Eddy Simulation (LES) together with the uninvolved Direct Integration (DI) approach. A reduced n-heptane chemical mechanism has been employed and artificially accelerated in order to predict the ignition for n-dodecane accurately. Soot processes have been modelled with an extended version of the semi-empirical, two-equation model of Leung, which considers C2H2 as the soot precursor and accounts for particle inception, surface growth by C2H2 addition, oxidation by O2, oxidation by OH and particle coagulation.