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Lead-acid batteries have dominated the automotive conventional electric system, particularly in the functions of starting (S), lighting (L) and ignition (I) for decades. However, the low energy-to-weight ratio and the low energy-to-volume ratio makes the lead-acid SLI battery relatively heavy, large, and shallow Depth of Discharge (DOD). This could be improved by replacing the lead-acid battery by the lithium-ion polymer battery. The lithium-ion polymer battery can provide the same power with lightweight, compact volume, and deep DOD for engine idle elimination using start-stop function that is a basic feature in electric-drive vehicles. This paper presents the modeling and validation of a lithium-ion battery for SLI application. A lithium-metal-oxide based cell with 3.6 nominal voltage and 20Ah capacity is used in the study. A simulation model of lithium-ion polymer battery pack (14.4V, 80Ah) with battery management system is built in the MATLAB/Simulink environment.