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Premixed Charge Compression Ignition (PCCI), a Low Temperature Combustion (LTC) strategy for diesel engines is of increasing interest due to its potential to simultaneously reduce soot and NOx emissions. However, the influence of mixture preparation on combustion phasing and heat release rate in LTC is not fully understood. In the present study, the influence of injection timing on mixture preparation, combustion and emissions in PCCI mode is investigated by experimental and computational methods. A sequential coupling approach of 3D CFD with a Stochastic Reactor Model (SRM) is used to simulate the PCCI engine. The SRM accounts for detailed chemical kinetics, convective heat transfer and turbulent micro-mixing. In this integrated approach, the temperature-equivalence ratio statistics obtained using KIVA 3V are mapped onto the stochastic particle ensemble used in the SRM.

The mixing and combustion processes of short double Diesel injections are investigated by optical diagnostics. A single hole Common Rail Diesel injector allowing high injection pressure up to 120MPa is used. The spray is observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a Diesel engine during injection. Three configurations are studied: a single short injection serving as a reference case and two double short injections with short and long dwell time (time between the injections). Several optical diagnostics were performed successively. The mixing process is studied by normalized Laser Induced Exciplex Fluorescence giving access to the vapor fuel concentration fields. In addition, the flow fields both inside and outside the jets are characterized by Particle Imaging Velocimetry.

A production version of a V-8 engine was redesigned to run on partially premixed charge compression ignition (PCCI) combustion mode with conventional diesel fuel. The objective of the PCCI combustion experiments was to obtain low engine-out nitrogen oxide (NOx) and after-treatment tolerant soot emission level. Two fuel injection strategies were used during the PCCI combustion experiments: a) pilot-with-main injection strategy (Pil-M), b) pilot-with-main-and-post (PMP) injection strategy. In the Pil-M injection strategy, a significant fraction of the fuel was delivered early during the compression stroke. The early pilot helped to prepare a lean-mixture of enhanced homogeneity before the combustion was initiated. The combustion of this pilot injection followed by the main combustion helped to reduce soot for a constant NOx value. The pilot-injection timing and quantity had to be selected appropriately to retain the fuel-efficiency.

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.

This work intends to present a study about the application of a standard methodology for the evaluation of the mechanical components compromise as result of the use of biodiesel, based on the lubricating oil analyses. The fuel oil that will be analyzed is produced in PUCRS' Faculty of Chemistry. As we know, the physical-chemical analysis of lubricating oils can indicate a series of parameters that allow valuing the quality and the compromising degree of the mechanical engine components. The results of these analyses will be based on tests in an Electronic Microscopy. This type of analysis will allow us to determine the quality of the lubricating oil, degradation and contamination with metal materials (mechanical compromising). The work presupposes the functioning of Diesel engine cycle with several proportions of biodiesel (B2, B5, B10, B20 and B100).

In this work, a quasi-dimensional, multi-zone combustion model is analytically presented, for the prediction of performance and nitric oxide (NO) emissions of a homogeneous charge spark ignition (SI) engine, fueled with biogas-H2 blends of variable composition. The combustion model is incorporated into a closed cycle simulation code, which is also fully described. Combustion is modeled on the basis of turbulent entrainment theory and flame stretch concepts. In this context, the entrainment speed, by which unburned gas enters the flame region, is simulated by the turbulent burning velocity of a flamelet model. A flame stretch submodel is also included, in order to assess the flame response on the combined effects of curvature, turbulent strain and nonunity Lewis number mixture. As far as the burned gas is concerned, this is treated using a multi-zone thermodynamic formulation, to account for the spatial distribution of temperature and NO concentration inside the burned volume.

Single cylinder optical engines are used for internal combustion (IC) engine research as they allow for the application of qualitative and quantitative non-intrusive, diagnostic techniques to study in-cylinder flow, mixing, combustion and emissions phenomena. Such experimental data is not only important for the validation of computational models but can also provide a detailed insight into the physical processes occurring in-cylinder which is useful for the further development of new combustion strategies such as gasoline homogeneous charge compression ignition (HCCI) and Diesel low temperature combustion (LTC). In this context, it is therefore important to ensure that the performance of optical engines is comparable to standard all-metal engines. A comparison of optical and all-metal engine combustion and emissions performance was performed within the present study.

This study deals with the development of compression ignition DI alcohol engine with higher efficiency and lower emissions comparing to the conventional internal combustion engines. In order to establish such high performance alcohol engines, development of controlled ignition technology is required. This paper focuses on the main factors that govern auto-ignition phenomenon of alcohol spray from the view point of fuel properties. The reason of poor auto-ignition quality of alcohol spray was theoretically and experimentally revealed. That is difficulty of simultaneous attainments of ignition-suitable concentration and temperature in a spray mixture formation due to their smaller stoichiometric air/fuel ratio and larger latent heat for evaporation in comparison with conventional diesel fuels.

The present study investigates cold start at very low temperatures, down to −29 deg C. The experiments were conducted in an optical light duty diesel engine using a Swedish class 1 environmental diesel fuel. In-cylinder imaging of the natural luminescence using a high speed video camera was performed to get a better understanding of the combustion at very low temperature conditions. Combustion in cold starting conditions was found to be asymmetrically distributed in the combustion chamber. Combustion was initiated close to the glow plug first and then transported in the swirl direction to the adjacent jets. A full factorial study was performed on low temperature sensitivity for cold start. The effects of cooling down the engine by parts on stability and noise were studied. Furthermore, different injection strategies were investigated in order to overcome the limited fuel evaporation process at very low temperatures.

This study describes tests with a fast clocked multispark ignition system intended to improve the stability of inflammation during charge stratification. The advantage of this ignition system is the capability it provides to adjust the number of sparks, the duration of single sparks and the intensity of the primary current. The basic engine test parameters were first set in an optically accessible pressure chamber under conditions approximating an engine. Two strategies were examined to analyze their effect on inflammation in stratified charge mode. On the one hand, the multispark ignition (MSI) system allows implementing an intermittent spark sequence in the spark gap between the spark plug electrodes. On the other hand, precisely timed pulsing of spark energy into the plasma channel during charge motion can generate a very large deflection of the ignition spark.

The present paper describes the first results of a cooperative research project between GM Powertrain Europe and Istituto Motori of CNR aimed at studying the impact of Fatty-Acid Methyl Esters (FAME) and gas-to-liquid (GTL) fuel blends on the performance, emissions and fuel consumption of modern automotive diesel engines. The tests were performed on the architecture of GM 1.9L Euro4 diesel engine for passenger car application, both on optical single-cylinder and on production four-cylinder engines, sharing the same combustion system configuration. Various blends of biodiesels as well as reference diesel fuel were tested. The experimental activity on the single-cylinder engine was devoted to an in-depth investigation of the combustion process and pollutant formation, by means of different optical diagnostics techniques, based on imaging multiwavelength spectroscopy.

Recent developments in diesel fuel injection equipment coupled with moves to using ULSD and biodiesel blends has seen an increase in the number of reports, from both engine manufacturers and fleet operators, regarding fuel system deposit issues. Preliminary work performed to characterise these deposits showed them to be complicated mixtures, predominantly carbon like but also containing other possible carbon precursor materials. This paper describes the application of the combination of hydropyrolysis, gas chromatography and mass spectrometry to the analysis of these deposits. It also discusses the insights that such analysis can bring to the constitution and origin of these deposits.

This paper describes the set-up and testing of a single cylinder 25cc, air cooled, 4-stroke Spark Ignition (SI) engine converted to run in Homogeneous Charge Compression Ignition (HCCI) mode with the aid of various combustion control systems. The combustion control systems were investigated regarding their effects on combustion stability and heat release phasing. Engine operation was compared with unique findings from previous work done on a very small 2-stroke HCCI engine. HCCI engine operation was possible between 1000 - 4000 rpm when using Diethyl Ether (DEE) as the test fuel. Maximum operational fuel-air equivalence ratio (Φ) was 0.75 when operating without Exhaust Gas Recirculation (EGR). This relatively high equivalence ratio was attainable due to thermal gradients induced by the high surface area to volume ratio of the small engine combustion chamber, resulting in high chamber heat transfer.

The continual reduction of diesel engine heavy-duty nitrous oxides and particulate matter emissions due to Environmental Protection Agency (EPA) regulations has resulted in significant changes to engine hardware since 1998. Such changes have included use of cooled exhaust gas recirculation, clean gas induction, oxidation catalysts, variable geometry turbochargers, lean nitrous oxide traps, urea selective catalytic reduction, passive and catalyzed particulate matter filters, and engine design changes to reduce oil consumption while allowing use of low sulfur diesel fuel (DF-2) and maintaining oil change intervals and subsystem durability levels of previous model years. The net result from a propulsion system perspective is increased heat rejection, additional induction and exhaust system volume, increased system weight, and less tolerance to military fuels and lubricants.

Ion sensors have been shown to be a low-cost and robust method of measuring start of combustion (SOC) in Homogeneous Charge Compression Ignition (HCCI) engines. The combustion event in an HCCI engine is governed by temperature sensitive chemical-kinetics and is highly fuel dependent. Autoignition variability between various fuels can also affect emissions, efficiency, and overall operating range of the HCCI engine. Ion sensors (i.e. modified spark-plugs) can be used pragmatically to detect the combustion event for various fuels in HCCI engines over a wide range of operating conditions. An investigation of the ion currents produced from the combustion of gasoline, ethanol, and n-heptane in a 1.9L 4-cylinder VW TDI diesel engine (converted to run in HCCI mode) is conducted over a range of equivalence ratios, intake temperatures, and intake pressures. Gasoline, ethanol and n-heptane have diverse autoignition characteristics which affect the overall operation of the HCCI engine.

In this work, heat loss was investigated in two different HCCI single cylinder engines. Thermocouples were adapted to the surfaces of the cylinder heads and the temperature oscillations were detected in a wide range of the engine operation conditions. The local heat transfer is analyzed with port fuel and direct injection, for different engine parameters and operating points. It is shown that the spatially averaged measured heat loss in HCCI operation represents the global heat loss well. The spatial variations are small in the operation map presuming stable operating points with low cyclic variations and good engine performance. Furthermore, the heat loss measured in HCCI operation is compared to the heat loss detected in homogeneous and stratified DI-SI operation in the same engine. It is shown that the local heat losses in stratified DI-SI operation show large variations, depending on the direction of the flame propagation.

It is generally accepted that emissions of nitrogen oxides (NOx) increase as the volume fraction of bio diesel increases in blends with conventional diesel fuel. While many mechanisms based on bio diesel effects on in-cylinder processes have been proposed to explain this observation, a clear understanding of the relative importance of each has remained elusive. To gain further insight into the cause(s) of the bio diesel NOx increase, experiments were conducted in a single-cylinder version of a heavy-duty diesel engine with extensive optical access to the combustion chamber. The engine was operated using two bio diesel fuels and two hydrocarbon reference fuels, over a wide range of loads, and using undiluted air as well as air diluted with simulated exhaust gas recirculation.

Direct Injection (DI) is believed to be one of the key strategies for maximizing the thermal efficiency of Spark Ignition (SI) engines and meet the ever-tightening emissions regulations. This paper explores the use of Liquefied Petroleum Gas (LPG) liquid phase fuel in a 1.5 liter SI four cylinder gasoline engine with double over head camshafts, four valves per cylinder, and centrally located DI injector. The DI injector is a high pressure, fast actuating injector enabling precise multiple injections of the finely atomized fuel sprays. With DI technology, the injection timing can be set to avoid fuel bypassing the engine during valve overlap into the exhaust system prior to combustion. The fuel vaporization associated with DI reduces combustion chamber and charge temperatures, thereby reducing the tendency for knocking. Fuel atomization quality supports an efficient combustion process.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The use of butanol as an alternative biofuel blend component for conventional diesel fuel has been under extensive investigation. However, some fuel properties such as cetane number and lubricity fall below the accepted values as described by the ASTM D 975 diesel specifications. Blending 10% butanol with #2 ULSD decreases the cetane number by 7% (from 41.6 to 39.0). At higher butanol blend levels, i.e., 20% v/v, the cetane number decrease cannot be compensated for; even with the addition of a 2000 ppm level commercial cetane improver. The decreased cetane number, or in other words, increased ignition delay, can be attributed to the increased blend level of low cetane butanol as well as the critical physical properties for better atomization of fuels during auto ignition such as viscosity. The kinematic viscosity dropped sharply with increasing butanol blend level up to 25 % v/v, then increased with further increase of butanol blend level.