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Advances in NOx Reduction Technology, 2015

2015-04-14
This technical paper collection will focus on ‘Advances in NOx Reduction Technology’. The topics covered will include: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.
Technical Paper

Particulate Reinforced Aluminum Matrix Composites Obtained By Indirect Squeeze-Casting

1996-04-01
91A115
Indirect squeeze casting technology is one of the most attractive fabrication techniques of near net shape components constituted by aluminum matrix composite (AMC) materials. AMCs reinforced with both continuous and discontinuous ceramic elements have been mainly produced by infiltration of porous preforms. Nevertheless, a further promising production route offered by this technique is given by the possibility to employ ingots of pre-reinforced aluminum alloys containing ceramic particles (silicon carbide or alumina); ingots are remelted and, under suitable operative conditions, high quality composite castings of simple and complex shape are produced by squeeze casting. The present paper describes the results of an extensive experimental work carried out by Alures-Centro Tecnico Porcessi on a pilot plant scale employing a vertical squeeze casting machine with a clamping force of 315 tons.
Technical Paper

Thermomechanical Behavior and Wear Resistance of Whisker Or Particle Reinforced Ceramics

1996-04-01
91A107
Ceramic composite materials have been intensively studied during the last years. Particles and whisker reinforcement have shown the simultaneous advantage to allow the preparation of composite materials by conventional processing and to lead, when under optimum conditions, to dramatic toughening and strengthening. Since wear resistance of brittle material have been shown to be related to both hardness and toughness, composite materials with improved were resistance have been developed for cutting tools or bearing applications. However the mechanism responsible for toughening is of major important for wear resistance effectiveness. We have therefore reviewed the main mechanisms before presenting some examples of composites materials for wear resistance applications.
Technical Paper

Reliability Improvement of Automotive Components By Surface Modification

1996-04-01
91A104
In this paper, several detailed studies on the surface properties of coatings are explained in order to make function of surface modification become more effective. As surface coatings, eletroless nickel plating, organic thin film, nitriding and antireflection coating by ultra fine particles are examined. Discussion of optimum production conditions and surface conditions for each coating is introduced.
Technical Paper

Performance and Exhaust Emission in Spark Ignition Engine Fueled with Methanol-Butane Mixture

1988-03-01
871165
To improve the cold startability of methanol, methanol-butane mixed fuel was experimented. Engine performance and exhaust emissions are obtained with methanol-butane mixed fuel. These characteristics are compared with those of methanol and gasoline. The mixing ratios of methanol and butane are 50:50 (M50), 80:20 (M80), and 90:10 (M90) based on the calorific value. As a result, M90 produces more power than gasoline and more or less than methanol depending on the engine speed and the excess air ratio. Brake horse power of M90 is higher than that of gasoline by 5 - 10 %, and brake specific fuel consumption is smaller than that of gasoline by 17 % to the maximum based on the calorific value. NOx emission concentrations for M90 are lower than those for gasoline and higher than those for methanol because of the effect of butane, CO emission concentrations are somewhat lower than those for methanol and gasoline.
Technical Paper

Evaluation and Analysis of Strength of All-Ceramic Swirl Chamber for Diesel Engines

1988-03-01
871205
An all-ceramic swirl chamber has been developed and analyses and evaluations concerning the strength of silicon nitride ceramic (Si3N4) have been performed with a view to using it for the entire internal wall surface of the swirl chamber. The strength characteristics of Si3N4 and their effect and variation have been determined. On the basis of measurements and analyses of thermal stresses, assembling stresses, etc., investigation of the most suitable construction and assembling methods to reduce load stresses on ceramic, and various kinds of duration tests, the swirl chamber has been confirmed to have the required durability. This engine was found to comply with the 1987 U.S. diesel particulate regulation.
Technical Paper

A Procedure for Evaluating Cycle Emissions from Raw Exhaust Gas Analyses

1988-03-01
871194
A procedure has been developed for evaluating equivalent drive cycle emission results from raw exhaust gas emissions data obtained from an engine under test on a computer controlled Vehicle Simulator Engine Dynamometer. The emitted species data is integrated with the air intake flow rate to determine the total mass of emissions, after correcting for the reduction in exhaust gas mass due to precipitation of the moisture of combustion. This procedure eliminates the need for the Constant Volume Sample (CVS) System attached to the vehicle exhaust while undergoing simulated drive testing on a chassis dynamometer to evaluate compliance of the test vehicle with the Australian Design Rules, ADR27 and ADR37. Sources of error with the procedure are examined by comparing the fuel consumption measured using a volumetric technique during the test with that evaluated by a carbon balance procedure as given in the Australian Design Rules.
Technical Paper

Reconstruction of the Cylinder Pressure from Vibration Measurements for Prediction of Exhaust and Noise Emissions in Ethanol Engines

1999-05-17
1999-01-1658
There are growing demands for condition monitoring of IC engines, and therefore any method in order to improve the performance of the engines ought to be evaluated. This paper proposes a new approach for the prediction and optimisation of noise and exhaust emissions in IC engines. The idea is to reconstruct the cylinder pressure from vibration measurements on the engine surface by using the complex cepstrum method [3, 4]. The reconstructed cylinder pressure is further used as input in Multivariate models, based on cylinder pressure, for estimating noise and exhaust emissions. This paper demonstrates the applicability of the method for modelling of noise and exhaust emissions
Technical Paper

Effect of High Squish Combustion Chamber on Simultaneous Reduction of NOx and Particulate from a Direct-Injection Diesel Engine

1999-05-03
1999-01-1502
In this study it is tried to reduce NOx and particulate emissions simultaneously in a direct injection diesel engine based on the concept of two-stage combustion. At initial combustion stage, NOx emission is reduced with fuel rich combustion. At diffusion combustion stage, particulate emission is reduced with high turbulence combustion. The high squish combustion chamber with reduced throat diameter is used to realize two-stage combustion. This combustion chamber is designed to produce strong squish that causes high turbulence. When throat diameter of the high squish combustion chamber is reduced to some extent, simultaneous reduction of NOx and particulate emissions is achieved with less deterioration of fuel consumption at retarded injection timing. Further reduction of NOx emission is realized by reducing the cavity volume of the high squish combustion chamber. Analysis by endoscopic high speed photography and CFD calculation describes the experimental results.
Technical Paper

The Autoignition Behavior of Surrogate Diesel Fuel Mixtures and the Chemical Effects of 2-Ethylhexyl Nitrate (2-EHN) Cetane Improver

1999-05-03
1999-01-1504
The oxidation of surrogate diesel fuels composed of mixtures of three pure hydrocarbons with and without their cetane numbers chemically enhanced using 2-ethylhexyl nitrate (2-EHN) is studied in a variable pressure flow reactor over a temperature range 500 - 900 K, at 12.5 atmospheres and a fixed reaction time of 1.8 sec. Changes in both low temperature, intermediate temperature, and hot ignition chemical kinetic behavior are noted with changes in the fuel cetane number. Differences appear in the product distribution and in heat release generated in the low and intermediate temperature regimes as cetane number is increased. A chemically enhanced cetane fuel shows nearly identical oxidation characteristics to those obtained using pure fuel blends to produce the enhanced cetane value. The decomposition chemistry of 2-EHN was also studied. Pyrolysis data of 10% 2-EHN in n-heptane and toluene are reported.
Technical Paper

A Six-Stroke DI Diesel Engine Under Dual Fuel Operation

1999-05-03
1999-01-1500
A six-stroke DI diesel engine proposed by the authors had second compression and combustion processes which were added on a conventional four-stroke diesel engine. This engine had the first and second power strokes before the exhaust stroke. Numerical predictions and experiments previously carried out had shown that this six-stroke diesel engine could reduce NO exhaust emission. Further, the ignition delay of the second combustion process could be shortened by a high temperature effect in the second compression stroke. This advantage of short ignition delay could be utilized for an ignition improvement of a fuel with low cetane number. In the engine system reported here, a conventional diesel fuel was supplied as the fuel of first combustion process, and in the second combustion process, methanol was supplied.
Technical Paper

A Comparison of Gasoline Direct Injection and Port Fuel Injection Vehicles: Part II - Lubricant Oil Performance and Engine Wear

1999-05-03
1999-01-1499
Four 1998 Mitsubishi Carismas, two equipped with direct injection (GDI) and two with port fuel injection engines (PFI) were tested in a designed experiment to determine the effect of mileage accumulation cycle, engine type, fuel and lubricant type on engine wear and engine oil performance parameters. Fuel types were represented by an unadditised base fuel meeting EEC year 2000 specifications and the same base fuel plus synthetic deposit control additive packages. Crankcase oils were represented by two types (1) a 5W-30 API SJ/ILSAC GF-2 type engine oil and (2) a 10W-40 API SH/CF ACEA A3/ B3-96 engine oil. The program showed that specific selection of oil additive chemistry may reduce formation of intake valve deposits in GDI cars.. In general, G-DI engines produced more soot and more pentane insolubles and were found to be more prone to what appears to be soot induced wear than PFI engines.
Technical Paper

What Fuel Economy Improvement Technologies Could Aid the Competitiveness of Light-Duty Natural Gas Vehicles?

1999-05-03
1999-01-1511
The question of whether increasing the fuel economy of light-duty natural gas fueled vehicles can improve their economic competitiveness in the U.S. market, and help the US Department of Energy meet stated goals for such vehicles is explored. Key trade-offs concerning costs, exhaust emissions and other issues are presented for a number of possible advanced engine designs. Projections of fuel economy improvements for a wide range of lean-burn engine technologies have been developed. It appears that compression ignition technologies can give the best potential fuel economy, but are less competitive for light-duty vehicles due to high engine cost. Lean-burn spark ignition technologies are more applicable to light-duty vehicles due to lower overall cost. Meeting Ultra-Low Emission Vehicle standards with efficient lean-burn natural gas engines is a key challenge.
Technical Paper

Performance and Emissions of an LPG Lean-Burn Engine for Heavy Duty Vehicles

1999-05-03
1999-01-1513
Performance and emissions of an LPG lean burn engine for heavy duty vehicles were measured. The piston cavity, swirl ratio, propane - butane fuel ratio, and EGR were varied to investigate their effects on combustion, and thus engine performance. Three piston cavities were tested: a circular flat-bottomed cavity with sloped walls (called the “bathtub” cavity), a round bottomed cavity (called the “dog dish” cavity), and a special high-turbulence cavity (called the “nebula” cavity). Compared to the bathtub and dog dish cavities, the nebula type cavity showed the best performance in terms of cyclic variation and combustion duration. It was capable of maintaining leaner combustion, thus resulting in the lowest NOx emissions. High swirl improved combustion by achieving a high thermal efficiency and low NOx emissions. In general, as the propane composition increased, cyclic variation fell, NOx emissions increased, and thermal efficiency was improved.
Technical Paper

In-Use Emissions from Natural Gas Fueled Heavy-Duty Vehicles

1999-05-03
1999-01-1507
The objective of the work described here is to test the performance of closed-loop controlled, heavy-duty CNG engines in-use, on fuels of different methane content; and to compare their performance with similar diesel vehicles. Performance is measured in terms of pollutant emissions, fuel economy, and driveability. To achieve this objective, three buses powered by closed-loop controlled, dedicated natural gas engines were tested on the heavy-duty chassis dynamometer facility at the Colorado Institute for Fuels and High Altitude Engine Research (CIFER). Emissions of regulated pollutants (CO, NOx, PM, and THC or NMHC), as well as emissions of alde-hydes for some vehicles, are reported. Two fuels were employed: a high methane fuel (90%) and a low methane fuel (85%). It was found that the NOx, CO, and PM emissions for a given cycle and vehicle are essentially constant for different methane content fuels.
Technical Paper

Emissions from Buses with DDC 6V92 Engines Using Synthetic Diesel Fuel

1999-05-03
1999-01-1512
Synthetic diesel fuel can be made from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, synthetic diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. Previous engine laboratory and field tests using a heavy-duty chassis dynamometer indicate that synthetic diesel fuel made using the Fischer-Tropsch (F-T) catalytic conversion process is a promising alternative fuel because it can be used in unmodified diesel engines, and can reduce exhaust emissions substantially. The objective of this study was a preliminary assessment of the emissions from older model transit operated on Mossgas synthetic diesel fuel. The study compared emissions from transit buses operating on Federal no. 2 Diesel fuel, Mossgas synthetic diesel (MGSD), and a 50/50 blend of the two fuels.
Technical Paper

Effects of a Hybrid Fuel System with Diesel and Premixed DME/Methane Charge on Exhaust Emissions in a Small DI Diesel Engine

1999-05-03
1999-01-1509
Early stage combustion systems, with lean homogeneous charge compression ignition (HCCI), have been studied, with the intent to decrease the pollutant emission characteristics of DI diesel engines. Early stage combustion enables drastic reductions in both nitrogen oxides (NOx) and smoke emission, but the operating load range is restricted, due to combustion phenomena, such as unsteady combustion and knocking. In this study, we explored the possibility of broadening the operating load range in HCCI and reducing pollutant emissions using Dimethyl Ether (DME) fumigated through the intake pipe. However, the improvements in load range were found to be less than 0.1 MPa in brake mean effective pressure (BMEP), even when compression ratios were reduced and Methane with high octane number was mixed. Therefore, a DME premixed charge could be used only at light loads. At heavier loads a hybrid fuel system with a DME premixed charge and diesel fuel injection is necessary.
Technical Paper

Contribution of Soot Contaminated Oils to Wear-Part II

1999-05-03
1999-01-1519
Diesel soot interacts with the engine oil and leads to wear of engine parts. Engine oil additives play a crucial role in preventing wear by forming the anti-wear film between the wearing surfaces. The current study was aimed at investigating the interactions between engine soot and oil properties in order to develop high performance oils for diesel engines equipped with exhaust gas re-circulation (EGR). The effect of soot contaminated oil on wear of engine components was examined using a statistically designed experiment. To quantitatively analyze and simulate the extent of wear a three-body wear machine was designed and developed. The qualitative wear analysis was performed by examining the wear scars on an AISI 52100 stainless steel ball worn in the presence of oil test samples on a ball-on-flat disc setup. The three oil properties studied were base stock, dispersant level and zinc dithiophosphate level.
Technical Paper

Experimental and Simulation Approaches to Understanding Soot Aggregation

1999-05-03
1999-01-1516
During 1998, the US Federal authority introduced a requirement for vehicles powered by heavy duty diesel engines that NOx emissions shall be less than 4 g/bhp.h. This represents a 20% reduction over current levels and has prompted significant further hardware changes. As a result of these increasingly tighter NOx emission constraints, soot loading of diesel engine lubricants - due to retarded fuel injection, is becoming an ever more significant issue in crankcase lubricant formulation. For this reason, increased understanding is required of the mechanism of soot particle aggregation and resultant aggregate morphology - together with the likely consequences for the performance of soot-laden lubricants, for viscosity increase, filter blocking, sludging and (directly or indirectly) - soot-induced wear. We describe here a combined experimental and simulation approach to screening formulated lubricants and characterising soot aggregate structures.
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