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Advances in Catalyst Substrates, 2018

2018-04-03
Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.
Collection

Advances in NOx Reduction Technology, 2015

2015-04-14
This technical paper collection will focus on ‘Advances in NOx Reduction Technology’. The topics covered will include: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.
Collection

Emission Measurement and Testing, 2014

2014-04-01
This technical paper collection covers emissions measuring techniques and testing regimes including new analysis techniques and the novel application of existing techniques, the comparison of existing and proposed testing regimes with real world experience, including modeling.
Technical Paper

The Modeling of Mold Filling in Structural Reaction Injection Molding

1996-04-01
91A118
The main use of FRC in automobiles, with the exception of a few specialized low volume vehicles, has been until now in semistructural parts. One of the most promising process in development today, that may play major role in future structural composite fabrication, is based on SRIM technology. The rapid and extensive introduction of this process goes also through the development of deeper theoretical knowledge of the process and the development of computer simulation to aid mold design and choice of proper processing parameters. To contribute SRIM advancement, a preliminary model has been developed for viscosity changes, extent of the reaction and temperature rises, associated with the mold filling stage, as well as a simple software to evaluate the pressure drop through different combinations of reinforcements.
Technical Paper

Manufacture of Automotive Components By Semi-Liquid Forming Process

1996-04-01
91A113
Semi-liquid forming process, applied to pressure die-casting, permits to obtain low cost components with high qualitative characteristics and adequate mechanical performances. The technology is based on the employment of material with globular microstructure (flow-cast alloys) obtained subjecting a metal alloy at the time of solidification to an elevated shear rate. Such microstructure permits the accomplishment of conventional forming processes at temperatures in solidification range. The particular fluid-dynamic properties of the semi-liquid slurry and the lower injection temperature allow to obtain casting with improved soundness, without need of impregnation, and to extend die life. The present work describes the Weber (Magneti Marelli) activity of the process industrialization and some applications for the manufacture of automotive components.
Technical Paper

U.S. and California Vehicle Emissions Control Programs Effectiveness and Application of Experience

1988-03-01
871148
Many areas of the world are in various stages of development which frequently includes a rapid increase in the motor vehicle population. As a result, some areas are beginning to show the effect of increased motor vehicle use on air pollution. The vehicle's contribution to California's air pollution has long been recognized and studied, and measures have been implemented to reduce emissions from motor vehicles. The history of light duty vehicle emission control in the South Coast Air Basin of California is reviewed. Emission reductions achieved, current levels, projected future emissions and the need for further emissions reductions from light duty vehicles are discussed. For other areas of the world where motor vehicles contribute to air pollution, suggestions are made which can improve the effectiveness of emission control efforts; which should be consistent with political and economic realities, and efforts to achieve international harmonization of standards.
Technical Paper

Correlation of Bending Strength and Errors of Helical Gear

1988-03-01
871223
CORRELATION OF BENDING STRENGTH AND ERRORS OF HELICAL GEAR has not been clarified sufficiently even now. As the investigation by using only experimental method is not sufficient and so the analytical method of obtaining gear bending strength has been developed by one of the authors. Hence, the correlation of bending strength and errors, especially in the aspect of the direction of pressure angle error and tooth trace error, is clarified by this analytical method which was verified by some experiments. And by further investigations, it is confirmed that the helical gear is tougher against the negative pressure angle error, and the fine module gear is sensitive against the errors.
Technical Paper

Tire/Pavement Interaction Noise Source Identification Using Multi-Planar Nearfield Acoustical Holography

1999-05-17
1999-01-1733
In this study, multi-planar Nearfield Acoustical Holography (NAH) is used to investigate noise radiated from the front, side and rear areas of single tires on a two-wheel trailer. Contributions to the radiated noise from the leading edge, trailing edge, and sidewall of the tire are identified. Two tires - an experimental monopitch tire and a production passenger car tire - are evaluated on a smooth asphalt pavement at 58 km/hr. From the measured complex pressure, acoustic intensity is reconstructed on three planes surrounding the tire using modified NAH procedures. Additionally, sound power levels are presented in tabulated and spectra forms. Tire noise generating mechanisms are inferred based on the results.
Technical Paper

Transfer Matrix Approach to the Estimation of the Fundamental Acoustical Properties of Noise Control Materials

1999-05-17
1999-01-1667
A new method for evaluating the acoustical properties of porous materials is described here. To implement the procedure, a two-microphone standing wave tube was modified to include: a new sample holder; a section that accommodated a second pair of microphones downstream of the sample holder; and an approximately anechoic termination. A four-point sound pressure method was then used to estimate the two-by-two transfer matrix of the material. The transfer matrix can then be used to determine the wave number and characteristic impedance of the material. The procedure has been used to estimate the acoustical properties of two glass fiber materials.
Technical Paper

Acoustical Advantages of a New Polypropylene Absorbing Material

1999-05-17
1999-01-1669
Sound absorption is one way to control noise in automotive passenger compartments. Fibrous or porous materials absorb sound in a cavity by dissipating energy associated with a propagating sound wave. The objective of this study was to evaluate the acoustic performance of a cotton fiber absorbing material in comparison to a new polypropylene fibrous material, called ECOSORB ®. The acoustical evaluation was done using measurements of material properties along with sound pressure level from road testing of a fully-assembled vehicle. The new polypropylene fibrous material showed significant advantages over the cotton fiber materials in material properties testing and also in-vehicle measurements. In addition to the performance benefits, the polypropylene absorber provided weight savings over the cotton fiber material.
Technical Paper

Reconstruction of the Cylinder Pressure from Vibration Measurements for Prediction of Exhaust and Noise Emissions in Ethanol Engines

1999-05-17
1999-01-1658
There are growing demands for condition monitoring of IC engines, and therefore any method in order to improve the performance of the engines ought to be evaluated. This paper proposes a new approach for the prediction and optimisation of noise and exhaust emissions in IC engines. The idea is to reconstruct the cylinder pressure from vibration measurements on the engine surface by using the complex cepstrum method [3, 4]. The reconstructed cylinder pressure is further used as input in Multivariate models, based on cylinder pressure, for estimating noise and exhaust emissions. This paper demonstrates the applicability of the method for modelling of noise and exhaust emissions
Technical Paper

The Autoignition Behavior of Surrogate Diesel Fuel Mixtures and the Chemical Effects of 2-Ethylhexyl Nitrate (2-EHN) Cetane Improver

1999-05-03
1999-01-1504
The oxidation of surrogate diesel fuels composed of mixtures of three pure hydrocarbons with and without their cetane numbers chemically enhanced using 2-ethylhexyl nitrate (2-EHN) is studied in a variable pressure flow reactor over a temperature range 500 - 900 K, at 12.5 atmospheres and a fixed reaction time of 1.8 sec. Changes in both low temperature, intermediate temperature, and hot ignition chemical kinetic behavior are noted with changes in the fuel cetane number. Differences appear in the product distribution and in heat release generated in the low and intermediate temperature regimes as cetane number is increased. A chemically enhanced cetane fuel shows nearly identical oxidation characteristics to those obtained using pure fuel blends to produce the enhanced cetane value. The decomposition chemistry of 2-EHN was also studied. Pyrolysis data of 10% 2-EHN in n-heptane and toluene are reported.
Technical Paper

Contribution of Soot Contaminated Oils to Wear-Part II

1999-05-03
1999-01-1519
Diesel soot interacts with the engine oil and leads to wear of engine parts. Engine oil additives play a crucial role in preventing wear by forming the anti-wear film between the wearing surfaces. The current study was aimed at investigating the interactions between engine soot and oil properties in order to develop high performance oils for diesel engines equipped with exhaust gas re-circulation (EGR). The effect of soot contaminated oil on wear of engine components was examined using a statistically designed experiment. To quantitatively analyze and simulate the extent of wear a three-body wear machine was designed and developed. The qualitative wear analysis was performed by examining the wear scars on an AISI 52100 stainless steel ball worn in the presence of oil test samples on a ball-on-flat disc setup. The three oil properties studied were base stock, dispersant level and zinc dithiophosphate level.
Technical Paper

A Non-Averaging Method of Determining the Rheological Properties of Traction Fluids

1999-05-03
1999-01-1518
Traction machines have been frequently used to study the rheological properties of lubricants in elasto-hydrodynamic lubrication (EHL) contacts. Fundamental properties are inferred from EHL traction measurements based on the average pressures and temperatures in the contact. This average approach leads to uncertainty in the accuracy of the results due to the highly nonlinear response of fluid rheological behavior to both pressure and temperature. A non-averaging method is developed in this paper to determine the elastic and plastic properties of traction fluids operating in EHL contacts at small slide-to-roll ratios. A precision line-contact traction rig is used to measure the EHL traction at a given oil temperature and Hertz pressure. By choosing a sensible pressure-property expression, the parameters of the expression can be determined through the initial slope and peak traction coefficient of the traction measurements.
Technical Paper

Effects of Load on Emissions and NOx Trap/Catalyst Efficiency for a Direct Injection Spark Ignition Engine

1999-05-03
1999-01-1528
A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.
Technical Paper

Engine-Out Emissions from a Direct-Injection Spark-Ignition (DISI) Engine

1999-05-03
1999-01-1529
The effects of operating parameters (speed, load, spark-timing, EGR, and end of fuel injection timing [EOI]) on engine-out, regulated (total HC, NOx, and CO) and speciated HC emissions have been investigated for a 1.83 L direct-injection, spark-ignition (DISI) engine. As the EOI is varied over the range from high to low stratification with other engine parameters held constant, the mole fractions of all regulated emissions vary sharply over relatively small (10-20 crank angle degrees [CAD]) changes in EOI, suggesting that emissions are very sensitive to the evaporation, mixing, and motion of the stratified fuel cloud prior to ignition. The contribution of unburned fuel to the HC emissions decreases while the olefinic partial oxidation products increase as the fuel stratification increases, increasing the smog reactivity of the HC in the exhaust gas by 25%.
Technical Paper

Neural Network-Based Diesel Engine Emissions Prediction Using In-Cylinder Combustion Pressure

1999-05-03
1999-01-1532
This paper explores the feasibility of using in-cylinder pressure-based variables to predict gaseous exhaust emissions levels from a Navistar T444 direct injection diesel engine through the use of neural networks. The networks were trained using in-cylinder pressure derived variables generated at steady state conditions over a wide speed and load test matrix. The networks were then validated on previously “unseen” real-time data obtained from the Federal Test Procedure cycle through the use of a high speed digital signal processor data acquisition system. Once fully trained, the DSP-based system developed in this work allows the real-time prediction of NOX and CO2 emissions from this engine on a cycle-by-cycle basis without requiring emissions measurement.
Technical Paper

Interaction of Sulfur with Automotive Catalysts and the Impact on Vehicle Emissions-A Review

1999-05-03
1999-01-1543
The requirement to meet more stringent emission standards has focused attention on the effects of gasoline sulfur on automotive emissions. Numerous studies have shown that three-way catalyst performance is severely inhibited by sulfur. A literature review of laboratory studies on the interaction of sulfur with automotive catalyst components provides the basis for understanding impacts on catalyst activity under the variety of conditions encountered in vehicle operation. Under stoichiometric and rich conditions, SO2 formed during combustion is dissociatively adsorbed on platinum group metal surfaces to form strongly bound Sad. Sulfur inhibition results from both physical blockage and electronic effects of Sad, such that low coverage of Sad results in disproportionately higher levels of reaction site blockage. This is responsible for the nonlinear effects observed with increasing fuel sulfur level.
Technical Paper

Effects of Fuel Properties on Combustion and Emission Characteristics of a Direct-Injection Diesel Engine

2000-06-19
2000-01-1851
This study investigates the effects of fuel properties on combustion characteristics and emissions such as NOx, smoke, THC and particulates in a direct-injection diesel engine. Fuel properties, such as cetane number and aromatic content, are varied independently in the experiments to separate their effects. The engine tests are carried out at steady operation with changed load, injection timing and injection pressure. The results show that reducing cetane number results in the increase of NOx and decrease of particulate emission at high load. This is because the low cetane number fuel has the long ignition delay and causes the high maximum heat release rate and the short combustion duration. However, high THC emission is produced at low load for the low cetane number fuel.
Technical Paper

EC-Diesel Technology Validation Program Interim Report

2000-06-19
2000-01-1854
ARCO has developed diesel fuel called Emission Control Diesel (EC-D) that results in substantially lower exhaust emissions compared to a typical California diesel fuel. EC-D has ultra-low sulfur content, low aromatics, and has a high cetane number. EC-D is produced from typical crude oil using a conventional refining process. Initial engine laboratory tests and vehicle tests indicated that EC-D reduced regulated emissions while maintaining fuel economy, compared to a typical California diesel fuel. Ultra-low sulfur diesel fuels such as EC-D may enable the widespread use of passive catalyzed particulate filters for both new and existing diesel engines. The use of catalyzed particulate filters could allow large reductions of particulate matter emitted from vehicles. A one-year technology validation program is being run to evaluate EC-D and catalyzed particulate filters using diesel vehicles operating in Southern California.
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