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The need for light-weighting of automotive structures has spurred on a tremendous amount of interest in and development of low cost carbon fiber composite materials and manufacturing. This presentation provides a description of the commercial carbon fiber concept compared to traditional aerospace and specialty carbon fiber products. A specific update is presented on the development and commercialization of new low cost carbon fiber based on lignin / PAN precursor technology. The second focus of the presentation is on carbon fiber composite manufacturing processes, including carbon SMC, RTM, prepregs, and thermoplastic processes. Advantages and disadvantages of these processes are discussed, especially related to low cost manufacturing. Presenter George Husman, Zoltek Companies Inc.

This paper reports solubility, diffusivity and permeability data for soy and rapeseed methyl esters in polyethylene together with comparisons with methyl oleate and linoleate. These data were used to discuss the reliability of predictive models for diffusion and solubility of additive type molecules into semi-crystalline thermoplastic polymers. Presenter Emmanuel Richaud

The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon

This technical paper collection contains 25 papers on fuels for SI engines published from the 2011 Powertrain Fuels and Lubricants Conference.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Ford Motor Company is introducing “EcoBoost” gasoline turbocharged direct injection (GTDI) engine technology in the 2010 Lincoln MKS. A logical enhancement of EcoBoost technology is the use of E85 for knock mitigation. The subject of this paper is the optimal use of E85 by using two fuel systems in the same EcoBoost engine: port fuel injection (PFI) of gasoline and direct injection (DI) of E85. Gasoline PFI is used for starting and light-medium load operation, while E85 DI is used only as required during high load operation to avoid knock. Direct injection of E85 (a commercially available blend of ∼85% ethanol and ∼15% gasoline) is extremely effective in suppressing knock, due to ethanol's high inherent octane and its high heat of vaporization, which results in substantial cooling of the charge. As a result, the compression ratio (CR) can be increased and higher boost levels can be used.

Spray-guided gasoline direct injection SI engines attract as one of new generation lean-burn engines to promise CO2 reduction. These typically adopt “narrow-spacing” concept in which an injector is centrally mounted close to a spark plug. Therefore, geometric targets of the fuel spray and a position of the spark plug have to be exactly limited to maintain a proper mixture in the spark gap. In addition, the stable combustion window is narrow because the spark ignition is limited in a short time during and immediately after the injection. These spatial and temporal restrictions involve some intractable problems concerning the combustion robustness due to the complicate phenomena around the spark plug. The local mixture preparation near the spark plug significantly depends on the spray-induced charge motion. The intense flow induced by the motion blows out and stretches the spark, thereby affecting the spark discharge performance.

The challenges of flex-fuel vehicle (FFV) emissions measurements have recently come to the forefront for the emissions testing community. The proliferation of ethanol blended gasoline in fractions as high as 85% has placed a new challenge in the path of accurate measures of NMHC and NMOG emissions. Test methods need modification to cope with excess amounts of water in the exhaust, assure transfer and capture of oxygenated compounds to integrated measurement systems (impinger and cartridge measurements) and provide modal emission rates of oxygenated species. Current test methods fall short of addressing these challenges. This presentation will discuss the challenges to FFV testing, modifications made to Ford Motor Company’s Vehicle Emissions Research Laboratory test cells, and demonstrate the improvements in recovery of oxygenated species from the vehicle exhaust system for both regulatory measurements and development measurements.

A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.

This work intends to present a study about the application of a standard methodology for the evaluation of the mechanical components compromise as result of the use of biodiesel, based on the lubricating oil analyses. The fuel oil that will be analyzed is produced in PUCRS' Faculty of Chemistry. As we know, the physical-chemical analysis of lubricating oils can indicate a series of parameters that allow valuing the quality and the compromising degree of the mechanical engine components. The results of these analyses will be based on tests in an Electronic Microscopy. This type of analysis will allow us to determine the quality of the lubricating oil, degradation and contamination with metal materials (mechanical compromising). The work presupposes the functioning of Diesel engine cycle with several proportions of biodiesel (B2, B5, B10, B20 and B100).

Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

In this work, a quasi-dimensional, multi-zone combustion model is analytically presented, for the prediction of performance and nitric oxide (NO) emissions of a homogeneous charge spark ignition (SI) engine, fueled with biogas-H2 blends of variable composition. The combustion model is incorporated into a closed cycle simulation code, which is also fully described. Combustion is modeled on the basis of turbulent entrainment theory and flame stretch concepts. In this context, the entrainment speed, by which unburned gas enters the flame region, is simulated by the turbulent burning velocity of a flamelet model. A flame stretch submodel is also included, in order to assess the flame response on the combined effects of curvature, turbulent strain and nonunity Lewis number mixture. As far as the burned gas is concerned, this is treated using a multi-zone thermodynamic formulation, to account for the spatial distribution of temperature and NO concentration inside the burned volume.

The startability of SI engines, especially of DISI engines, is the greatest challenge when using ethanol blended fuels. The development of a suitable injection strategy is therefore the main engineering target when developing an ethanol engine with direct injection. In order to limit the test efforts of such a program, a vaporization model has been created that provides the quantity of vaporized fuel depending on pressure and on start and end, respectively number and split relation of injections. This model takes account of the most relevant fuel properties such as density, surface tension and viscosity. It also considers the interaction of the spray with cylinder liner, cylinder head and piston. A comparison with test results shows the current status and the need for action of this simulation model.

The present paper describes the first results of a cooperative research project between GM Powertrain Europe and Istituto Motori of CNR aimed at studying the impact of Fatty-Acid Methyl Esters (FAME) and gas-to-liquid (GTL) fuel blends on the performance, emissions and fuel consumption of modern automotive diesel engines. The tests were performed on the architecture of GM 1.9L Euro4 diesel engine for passenger car application, both on optical single-cylinder and on production four-cylinder engines, sharing the same combustion system configuration. Various blends of biodiesels as well as reference diesel fuel were tested. The experimental activity on the single-cylinder engine was devoted to an in-depth investigation of the combustion process and pollutant formation, by means of different optical diagnostics techniques, based on imaging multiwavelength spectroscopy.

A well balanced use of alternative fuels is an important objective for a sustainable development of individual transportation worldwide. Several countries have objectives to substitute a part of the energy of traffic by ethanol as the renewable energy source. Investigations of limited and unregulated emissions of two 2-S scooters with gasoline-ethanol blend fuels have been performed in the present work according to the measuring procedures, which were established in the previous research in the Swiss Scooter Network (since 2000). The investigated fuels contained ethanol (E), in the portion of 5, 10, 15 and 20% by volume. The investigated 2-S scooters represented a newer and an older 2-stroke technology with carburettor. The newer one was investigated with and without catalyst and the older one only in the original state without catalyst.

Although the use of alcohol fuels in spark-ignition engines has been investigated for over 100 years, consistent and thorough thermodynamic evaluations are few. The current work examines the detail thermodynamics of the use of methanol and ethanol by an automotive, spark-ignition engine. Overall engine performance parameters, detail instantaneous quantities, and second law parameters are determined as functions of engine design and operating conditions. In addition, the results for the alcohol fuels are compared to results for isooctane. Results include indicated and brake efficiencies, heat transfer, and exhaust gas temperatures as functions of engine speed and load. Operating conditions include constant equivalence ratio (stoichiometric), MBT spark timing, and constant burn duration. In general, the thermodynamic results are similar for the alcohol fuels and isooctane.

Recent developments in diesel fuel injection equipment coupled with moves to using ULSD and biodiesel blends has seen an increase in the number of reports, from both engine manufacturers and fleet operators, regarding fuel system deposit issues. Preliminary work performed to characterise these deposits showed them to be complicated mixtures, predominantly carbon like but also containing other possible carbon precursor materials. This paper describes the application of the combination of hydropyrolysis, gas chromatography and mass spectrometry to the analysis of these deposits. It also discusses the insights that such analysis can bring to the constitution and origin of these deposits.

Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

This paper investigates the performance, combustion characteristics, and emissions of a small single cylinder DI diesel engine with biodiesel fuel (BDF) derived from unused rape, soybean, and palm oils. Compared with ordinary gas oil, the BDFs showed similar brake thermal efficiencies, better ignitability, and considerably reduced smoke densities, while the NOx emissions were somewhat higher. The injection characteristics and engine performance were also examined using neat Methyl Oleate (OME) and OME-Methyl Palmitate (PME) blends. Basic experiments of suspended single droplets were performed to evaluate the differences in ignition, combustion, and soot formation characteristics of these fuels. The results showed shorter ignition lags and combustion durations for the OME droplets blended with PME and the soot formation rate with OME is about 13% that of gas oil droplets.