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Transesterification of Waste Cooking Oil in Presence of Crushed Seashell as a Support for Solid Heterogeneous Catalyst

2011-12-05
Developing relatively cheap and widely available resources for heterogeneous solid catalyst synthesis is a promising approach for biodiesel fuel industry. Seashell which is essentially calcium carbonate can be used as a basic support for transesterification heterogeneous catalysts. In the present investigation, the alcoholysis of waste frying oil has been carried out using seashell-supported K3 PO4 as solid catalyst. Presenter Essam Oun Al-Zaini, PhD student, UNSW
Video

Development of DPF/SCR System for Heavy Duty Diesel Engine

2012-06-15
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).
Collection

Diesel Exhaust Emission Control, 2010

2010-06-01
The 57 papers in this technical paper collection describe technology developments and the integration of these technologies into new emission control systems. Topics include DPF substrates and systems, selective catalytic reduction (SCR), HC-DeNOx, and system integration and durability.
Collection

Powertrain Performance, Emissions & Controls, Commercial Vehicle 2015

2015-09-29
This technical paper collection covers advanced technologies and analysis/design/testing techniques related to powertrain performance, emissions, and electronic controls. Topics include system-level and component-level integration and optimization, emissions, fuel economy, combustion, air charging, EGR systems, fuel systems, valvetrains, engine brakes, waste heat recovery, calibration, steady-state and transient performance, engine/powertrain/drivetrain controls, model-based controls, sensors, OBD, and HIL.
Collection

Fuel Economy Improved & CO2 Reduction, Commercial Vehicle 2015

2015-09-29
This technical paper collection explores total vehicle and powertrain technologies for on and off-road commercial vehicles aimed at reduction of CO2 emissions through design, analysis, and testing techniques. The topics may include energy analysis/management/optimization, current and proposed emission legislation, certification techniques, powertrain integration, weight reduction, idle reduction, and friction/parasitic reduction.
Journal Article

Methodology for Developing a Diesel Exhaust After Treatment Simulation Tool

2017-09-16
Abstract A methodology for the development of catalyst models is presented. Also, a methodology of the implementation of such models into a modular simulation tool, which simulates the units in succession, is presented. A case study is presented illustrating how suitable models can be found and used for simulations. Such simulations illustrate the behavior of the individual units and the overall system. It is shown how, by simulating the units in succession, the entire after treatment system can be tested and optimized, because the integration makes it possible to observe the effect of the modules on one another.
Journal Article

Vibration Response Properties in Frame Hanging Catalyst Muffler

2018-07-24
Abstract Dynamic stresses exist in parts of a catalyst muffler caused by the vibration of a moving vehicle, and it is important to clarify and predict the vibration response properties for preventing fatigue failures. Assuming a vibration isolating installation in the vehicle frame, the vibration transmissibility and local dynamic stress of the catalyst muffler were examined through a vibration machine. Based on the measured data and by systematically taking vibration theories into consideration, a new prediction method of the vibration modes and parameters was proposed that takes account of vibration isolating and damping. A lumped vibration model with the six-element and one mass point was set up, and the vibration response parameters were analyzed accurately from equations of motion. In the vibration test, resonance peaks from the hanging bracket, rubber bush, and muffler parts were confirmed in three excitation drives, and local stress peaks were coordinate with them as well.
Journal Article

Aging Effects of Catalytic Converters in Diesel Exhaust Gas Systems and Their Influence on Real Driving NOx Emissions for Urban Buses

2018-06-18
Abstract The selective catalytic reduction (SCR) of nitrogen oxides seems to be the most promising technique to meet prospective emission regulations of diesel-driven commercial vehicles. In the case of developing cost-effective catalytic converters with comparably high activity, selectivity, and resistance against aging, ion-exchanged zeolites play a major role. This study presents, firstly, a brief literature review and subsequently a discussion of an extensive conversion analysis of exemplary Cu/ and Fe/zeolites, as well as a homogeneous admixture of both. The aging stages of SCR catalysts deserve particular attention in this study. In addition, the aging condition of the diesel oxidation catalyst (DOC) was analyzed, which influences the nitrogen dioxide (NO2) formation, because the NO2/nitrogen oxides (NOx) ratio upstream from the SCR converter could be identified as a key factor for low temperature NOx conversion.
Journal Article

Onboard Natural Gas Reforming for Heavy Duty Vehicles

2019-01-07
Abstract Powertrain simulations and catalyst studies showed the efficiency credits and feasibility of onboard reforming as a way to recover waste heat from heavy duty vehicles (HDVs) fueled by natural gas (NG). Onboard reforming involves 1) injecting NG into the exhaust gas recycle (EGR) loop of the HDV, 2) reforming NG on a catalyst in the EGR loop to hydrogen and carbon monoxide, and 3) combusting the reformed fuel in the engine. The reformed fuel has increased heating value (4-10% higher LHV) and flame speed over NG, allowing stable flames in spark ignition (SI) engines at EGR levels up to 25-30%. A sulfur-tolerant reforming catalyst was shown to reform a significant amount of NG (15-30% conversion) using amounts of precious metal near the current practice for HDV emissions control (10 g rhodium). Engine simulations showed that the high EGR levels enabled by onboard reforming are used most effectively to control engine load instead of waste-gating or throttling.
Collection

Commercial Vehicle Engine Exhaust Aftertreatment & Integration, 2011

2011-09-13
The 12 papers in this technical paper collection discuss technologies that address the treatment of engine exhaust emissions to meet commercial vehicle requirements. The scope covers developments in catalysis, materials, controls, and integration with the complete engine/vehicle system.
Journal Article

Field Evaluation of Biodiesel (B20) Use by Transit Buses

2009-10-06
2009-01-2899
The objective of this research project was to compare B20 (20% biodiesel fuel) and ultra-low-sulfur (ULSD) diesel-fueled buses in terms of fuel economy, vehicle maintenance, engine performance, component wear, and lube oil performance. We examined 15 model year (MY) 2002 Gillig 40-foot transit buses equipped with MY 2002 Cummins ISM engines. The engines met 2004 U.S. emission standards and employed exhaust gas recirculation (EGR). For 18 months, eight of these buses operated exclusively on B20 and seven operated exclusively on ULSD. The B20 and ULSD study groups operated from different depots of the St. Louis (Missouri) Metro, with bus routes matched for duty cycle parity. The B20- and ULSD-fueled buses exhibited comparable fuel economy, reliability (as measured by miles between road calls), and total maintenance costs. Engine and fuel system maintenance costs were also the same for the two groups after correcting for the higher average mileage of the B20 group.
Journal Article

Analysis of EGR Effects on the Soot Distribution in a Heavy Duty Diesel Engine using Time-Resolved Laser Induced Incandescence

2010-10-25
2010-01-2104
The soot distribution as function of ambient O₂ mole fraction in a heavy-duty diesel engine was investigated at low load (6 bar IMEP) with laser-induced incandescence (LII) and natural luminosity. A Multi-YAG laser system was utilized to create time-resolved LII using 8 laser pulses with a spacing of one CAD with detection on an 8-chip framing camera. It is well known that the engine-out smoke level increases with decreasing oxygen fraction up to a certain level where it starts to decrease again. For the studied case the peak occurred at an O₂ fraction of 11.4%. When the oxygen fraction was decreased successively from 21% to 9%, the initial soot formation moved downstream in the jet. At the lower oxygen fractions, below 12%, no soot was formed until after the wall interaction. At oxygen fractions below 11% the first evidence of soot is in the recirculation zone between two adjacent jets.
Journal Article

Development of SCR on High Porosity Substrates for Heavy Duty and Off-Road Applications

2014-04-01
2014-01-1521
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.
Journal Article

Comparative Study of Hybrid Powertrains on Fuel Saving, Emissions, and Component Energy Loss in HD Trucks

2014-09-30
2014-01-2326
Two hybrid powertrain configurations, including parallel and series hybrids, were simulated for fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving conditions. A comprehensive set of component models describing engine fuel consumption, emissions control, battery energy, and accessory power demand interactions was developed and integrated with the simulated hybrid trucks to identify heavy-duty (HD) hybrid technology barriers. The results show that series hybrid is absolutely negative for fuel-economy improvement of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical).
Journal Article

Effects of Charge Motion, Compression Ratio, and Dilution on a Medium Duty Natural Gas Single Cylinder Research Engine

2014-09-30
2014-01-2363
Recent advances in natural gas (NG) recovery technologies and availability have sparked a renewed interest in using NG as a fuel for commercial vehicles. NG can potentially provide both reduced operating cost and reductions in CO2 emissions. Commercial NG vehicles, depending on application and region, have different performance and fuel consumption targets and are subject to various emissions regulations. Therefore, different applications may require different combustion strategies to achieve specific targets and regulations. This paper summarizes an evaluation of combustion strategies and parameters available to meet these requirements while using NG in a spark ignited engine. A single-cylinder research engine using a modified diesel cylinder head was employed for this study. Both stoichiometric combustion with cooled exhaust gas recirculation (EGR) and lean-burn were evaluated.
Journal Article

Numerical Study of the Influence of EGR on In-Cylinder Soot Characteristics in a Heavy-Duty Diesel Engine using CMC

2014-04-01
2014-01-1134
This paper presents numerical simulations of in-cylinder soot evolution in the optically accessible heavy-duty diesel engine of Sandia Laboratories performed with the conditional moment closure (CMC) model employing a reduced n-heptane chemical mechanism coupled with a two-equation soot model. The influence of exhaust gas recirculation (EGR) on in-cylinder processes is studied considering different ambient oxygen volume fractions (8 - 21 percent), while maintaining intake pressure and temperature as well as the injection configuration unchanged. This corresponds to EGR rates between 0 and 65 percent. Simulation results are first compared with experimental data by means of apparent heat release rate (AHRR) and temporally resolved in-cylinder soot mass, where a quantitative comparison is presented. The model was found to fairly well reproduce ignition delays as well as AHRR traces along the EGR variation with a slight underestimation of the diffusion burn portion.
Journal Article

In-Situ Emissions Performance of EPA2010-Compliant On-Highway Heavy-Duty Diesel Engines

2013-09-24
2013-01-2430
Implementation of EPA's heavy-duty engine NOx standard of 0.20 g/bhp-hr has resulted in the introduction of a new generation of emission control systems for on-highway heavy-duty diesel engines. These new control systems are predominantly based around aftertreatment systems utilizing urea-based selective catalytic reduction (SCR) techniques, with only one manufacturer relying solely on in-cylinder NOx emission reduction techniques. As with any new technology, EPA is interested in evaluating whether these systems are delivering the expected emissions reductions under real-world conditions and where areas for improvement may lie. To accomplish these goals, an in-situ gaseous emissions measurement study was conducted using portable emissions measurement devices. The first stage of this study, and subject of this paper, focused on engines typically used in line-haul trucking applications (12-15L displacement).
Journal Article

A Study on Operation Fluid Consumption for Heavy Duty Diesel Engine Application using both, EGR and SCR

2013-09-24
2013-01-2474
This paper describes a method for optimization of engine settings in view of best total cost of operation fluids. Under specific legal NOX tailpipe emissions requirements the engine out NOX can be matched to the current achievable SCR NOX conversion efficiency. In view of a heavy duty long haul truck application various specific engine operation modes are defined. A heavy duty diesel engine was calibrated for all operation modes in an engine test cell. The characteristics of engine operation are demonstrated in different transient test cycles. Optimum engine operation mode (EOM) selection strategies between individual engine operation modes are discussed in view of legal test cycles and real world driving cycles which have been derived from on-road tests.
Journal Article

Secondary Fuel Injection Layout Influences on DOC-DPF Active Regeneration Performance

2013-09-24
2013-01-2465
Catalysts and filters continue to be applied widely to meet particulate matter regulations across new and retrofit diesel engines. Soot management of the filter continues to be enhanced, including regeneration methodologies. Concerns regarding in-cylinder post-injection of fuel for active regeneration increases interests in directly injecting this fuel into the exhaust. Performance of secondary fuel injection layouts is discussed, and sensitivities on thermal uniformity are measured and analyzed, providing insight to packaging challenges and methods to characterize and improve application designs. Influences of end cone geometries, mixers, and injector mounting positions are quantified via thermal distribution at each substrate's outlet. A flow laboratory is applied for steady state characterization, repeated on an engine dynamometer, which also provides transient results across the NRTC.
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