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Several studies have shown that NO has a strong influence on engine knock. This paper reports an experimental study that addresses the connection between SI engine knock and the level of nitric oxide, NO, in the intake manifold gas under various conditions of engine operation. Some theories explain the second ion-current peak as thermal ionisation of NO. Both temperature and NO concentration is of importance. By advancing the ignition angle the NO concentration can be increased, but the temperature is also increased. Addition of NO in the inlet manifold increases the NO concentration but has less effect on the temperature. SI engine experiments were conducted over a number of different ignition timings, air/fuel ratios, engine speeds and intake manifold pressures. The NO level in the intake manifold was altered from 100 to 1600 ppm, increasing the amount by doubling. The study confirms that there is an increasing tendency of early knock when the NO amount increases.

A 0.5 liter optical HCCI engine firing a mixture of n-heptane (50%) and iso-octane (50%) with air/fuel ratio of 3 is studied using large eddy simulation (LES) and laser diagnostics. Formaldehyde and OH LIF and in-cylinder pressure were measured in the experiments to characterize the ignition process. The LES made use of a detailed chemical kinetic mechanism that consists of 233 species and 2019 reactions. The auto-ignition simulation is coupled with LES by the use of a renormalized reaction progress variable. Systematic LES study on the effect of initial temperature inhomogeneity and turbulence intensity has been carried out to delineate their effect on the ignition process. It was shown that the charge under the present experimental condition would not be ignited without initial temperature inhomogeneity. Increasing temperature inhomogeneity leads to earlier ignition whereas increasing turbulence intensity would retard the ignition.