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Technical Paper

The Variation of Functional Characteristics of a Euro VI Selective Catalytic Reduction Reactor after Ageing

2020-09-15
2020-01-2205
The selective catalytic reduction (SCR) of nitrogen oxides by ammonia is commonly applied as a method of exhaust aftertreatment for lean burn compression ignition (CI) engines. The catalytic reactor of an SCR system, like all catalytic emission control devices, is susceptible to partial deactivation as its operating time progresses. Long-term exposure of an SCR reactor to exhaust gas of fluctuating temperature and composition results in variations of the characteristics of its catalytically active layer. The aim of this study was to observe and investigate the variation of parameters characterizing the SCR reactor as a result of its ageing. Attention was paid to changes in ammonia storage capacity, selectivity of chemical reactions and maximum achievable NOx conversion efficiency. The experimental setup was a heavy duty (HD) Euro VI-compliant engine and its aftertreatment system (ATS). The setup was installed on a transient engine dyno instrumented with emission measurement devices.
Technical Paper

Particulate Matter (PM) Emissions of Euro 5 and Euro 6 Vehicles Using Systems with Evaporation Tube or Catalytic Stripper and 23 nm or 10 nm Counters

2020-09-15
2020-01-2203
Particle number (PN) emission limits were introduced in the European Union’s regulations for light-duty and heavy duty vehicles in the years 2011-2014. Since then, PN measurements have become a common practice in the automotive sector. Many studies showed that the current methodology, which counts particles >23 nm, misses a large fraction of particles for some engine technologies, such as port fuel injection vehicles or vehicles fueled with compressed natural gas (CNG). However, data for the latest technology vehicles are lacking. For this reason, we measured PN emissions >23 nm and >10 nm of >30 CNG, gasoline and diesel-fueled vehicles. Two systems were measuring in parallel from the full dilution tunnel; one with an evaporation tube and the other with a catalytic stripper. The PN emission levels spanned over three orders of magnitude depending on whether there was a particulate filter installed or not.
Technical Paper

An Analysis of Emissions at Low Ambient Temperature from Diesel Passenger Cars Using the WLTP Test Procedure

2020-09-15
2020-01-2186
The aim of this paper is to analyse the results of regulated and unregulated emissions and carbon dioxide (CO2) emissions of passenger cars equipped with compression-ignition engines that meet the emission Euro 6d standards. Both test vehicles featured selective catalytic reduction (SCR) systems for control of oxides of nitrogen (NOx) and one vehicle also featured a passive NOx absorber (PNA). Research was performed using the current European Union exhaust emission test methods for passenger cars (Worldwide harmonized Light vehicles Test Procedures (WLTP)). Emission testing was performed on a chassis dynamometer, within a climatic chamber, at two different ambient temperatures: 23°C (i.e. Type I test) and -7°C (known as a Type VI test - currently not required for this engine type according to EU legislative requirements).
Technical Paper

RDE-Compliant PEMS Testing of a Gasoline Euro 6d-TEMP Passenger Car at Two Ambient Temperatures with a Focus on the Cold Start Effect

2020-04-14
2020-01-0379
European Union RDE (real driving emissions) legislation requires that new vehicles be subjected to emissions tests on public roads. Performing emissions testing outside a laboratory setting immediately raises the question of the impact of ambient conditions - especially temperature - on the results. In the spirit of RDE legislation, a wide range of ambient temperatures are permissible, with mathematical moderation (correction) of the results only permissible for ambient temperatures <0°C and >+30°C. Within the standard range of temperatures (0°C to +30°C), no correction for temperature is applied to emissions results and the applicable emissions limits have to be met. Given the well-known link between the thermal state of an engine and its emissions following cold start, ambient temperature can be of great importance in determining whether a vehicle meets emissions requirements during an RDE test.
Technical Paper

Investigation of Exhaust Emissions from DI Diesel Engine During Cold and Warm Start

2001-03-05
2001-01-1260
This paper reviews the emissions from direct injection (DI) diesel engine in the initial period of controlled engine operation following start-up. The tests were undertaken in „cold start” mode (temperature of cooling water and lube oil equal to ambient temperature) and „warm start” mode* (after attaining a state of equilibrium). Both results were compared.
Technical Paper

Exhaust Emission from Passenger Cars During Engine Cold Start and Warm-Up

1997-02-24
970740
An increased of carbon monoxide and hydrocarbons emissions from gasoline engines in ambient temperatures at or below 0°C is a key issue, not only in Scandinavia or northern parts of the USA and Canada, but also in countries of Central and Eastern Europe. It is typical of Poland and neighbouring countries that for six to seven months (from October to April) air temperature fails to about 0°C at night, while in winter months this temperature often fails below -10 to even -20°C. Due to this, in these countries the cars are started in the morning when the engine and all other parts of the car are considerably cool. This paper presents a special climatic conditions in view of their effect on the actual exhaust emission from a car with SI engine and results of emission tests for such gaseous pollutants as CO, HC and NOx, achieved during tests performed on a chassis dynamometer according to ECE and FTP 75 cycles.
Technical Paper

Exhaust Emissions from Two Euro 6d-Compliant Plug-In Hybrid Vehicles: Laboratory and On-Road Testing

2021-04-06
2021-01-0605
This paper discusses the legislative situation regarding type approval of plug-in hybrid vehicles (also known as off-vehicle charging hybrid-electric vehicles, OVC-HEV) in the range of exhaust emissions and fuel consumption. A range of tests were conducted on two Euro 6d-complaint OVC-HEVs to quantify emissions. Procedures were based on EU legislative requirements. For laboratory (chassis dyno) testing, two different test cycles and three different ambient temperatures were used for testing. Furthermore, in some cases additional measurements were performed, including measurement of emissions of particulate matter and continuous analysis of regulated and unregulated pollutants in undiluted exhaust. Consumption of electrical energy was also monitored. On-road testing was conducted on the test vehicle tested on the chassis dyno in the tests mentioned above, as well as on a second OVC-HEV test vehicle.
Technical Paper

The Formation of Ammonia in Three-Way Catalysts Fitted to Spark Ignition Engines - Mechanisms and Magnitudes

2022-08-30
2022-01-1026
Exhaust gas aftertreatment systems can, under certain conditions, create undesired chemical species as a result of their elimination reactions. A prime example of this is ammonia (NH3), which is not formed in the combustion reaction, but which can be formed within a three-way catalyst (TWC) when physicochemical conditions permit. The elimination of NOx in the TWC thus sometimes comes at the cost of significant emissions of NH3. Ammonia is a pollutant and a reactive nitrogen compound (RNC) and NH3 emissions should be analyzed in this context, alongside other RNC species. Examination of the literature on the subject published over the past two decades shows that ammonia, a species which is currently not subject to systematic emissions requirements for road vehicles in any market, is often identified as forming the majority of the RNC emissions under a range of operating conditions.
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