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Nitrogen oxides, collectively called NOx, from diesel vehicles are considered to be accumulated by particular area of roadsides, so-called "Hot-spot," and result in harmful influence to pedestrians and residents by roadsides. Japanese regulations over emissions of diesel vehicles have been tightened year by year and adopting regulations, emissions in mode test on chassis dynamometer or engine dynamometer have reduced. In this research, it was investigated the effect of introduce of transient mode test, Japanese JE05 mode, to NOx emission in real world and to roadside NOx pollution by road test using on-board measurement system. As test vehicles, 2 ton diesel vehicle which is adopted for Long Term Regulation (steady-state mode test, Diesel 31 mode test, 1998) and 3 ton diesel vehicle adopted for New Long Term Regulation (transient mode test, Japanese JE05 mode, 2005) with on-board measurement system was used.

For the reduction of greenhouse gas emission in the transportation sector, various countermeasures against CO₂ emission have been taken. The eco-driving has been paid attention because of its immediate effect on the CO₂ reduction. Eco-driving is defined as a driving method with various driving techniques to save fuel economy. The eco-driving method has been promoted to the common drivers as well as the drivers of carriers. Additionally, there are many researches about improvement of fuel efficiency and CO₂ reduction. However, the eco-driving will have the reduction effect of CO₂ emission, the influence of the eco-driving on air pollutant emission such as NOx is not yet clear. In this study, the effect of the eco-driving on real-world emission has been analyzed using the diesel freight vehicle with the on-board measurement system.

An on-board measurement system that simultaneously measures road traffic, vehicle running conditions and exhaust emissions was installed in a diesel freight vehicle with two tons payload. Actual NOx mass emissions were compared with that measured in a typical test mode for urban cities on a chassis dynamometer. The frequency of vehicle accelerations in actual urban cities was found to exceed that of a typical test mode for urban cities on a chassis dynamometer, which resulted in increased NOx from actual running conditions compared with the typical test mode for urban cities. The dynamics of NOx emissions at an actual roadside was also analyzed. It was observed that NOx emission based on distance with an actual city route test was about two times higher than that of a free way route and a typical test mode for urban cities. The reason for high NOx with the city route was explained by the higher frequency of lower gears at which higher NOx is emitted.

It is necessary to clarify the influence on NOx emissions by driver's operation for analyzing of NOx pollution mechanism at roadside. Simple on-board measurement system for vehicle running condition and actual NOx emissions was developed to evaluate local NOx pollution caused by vehicles. The measurement system was installed in a freight vehicle whose payload is two tons, and actual driving test was conducted to evaluate the effectiveness of the system. The tests on chassis dynamometer including steady state and transient mode indicated enough accuracy to evaluate NOx emissions from a vehicle at local roadsides.

CNG/diesel dual-fuel engine is using CNG as a main fuel, and injects diesel only a little as an ignition priming. In this study, remodeling an existing diesel engine into dual-fuel engine that can inject diesel with high pressure by CRDI (Common Rail Direct Injection), and injecting CNG at intake port for premixing. The results show that CNG/diesel dual-fuel engine satisfied coordinate torque and power with conventional diesel engine. And CNG alternation rate is over 89% in all operating ranges of CNG/diesel dual-fuel engine. PM emission is lower 94% than diesel engine, but NOx emission is higher than diesel engine. The output of dual fuel mode is 95% by the diesel mode. At this time, amount of CO₂ and PM are decreased while CO, NOx, and THC are increased. In NEDC mode, exhaust gases except NOx are decreased.

This work experimentally investigates how the dwell time between pilot injection and main injection influences combustion characteristics and emissions (NOx, CO, THC and Smoke) in a single-cylinder DI diesel engine. Additionally, results from diesel injection are compared with those shown in dimethyl ether (DME) injection under the identical injection strategy to demonstrate the sensitivity of the combustion characteristics and emissions to changes of the fuel type. Two fuel injection systems are applied for this experiment due to the differences of fuel characteristic with regard to physical and chemical properties. The injection strategy is accomplished by varying the dwell time (10°CA, 16°CA and 22°CA) between injections at five main injection timings (-4°CA aTDC, -2°CA aTDC, TDC, 2°CA aTDC and 4°CA aTDC). It was found that pilot injection offers good potential to lower the heat-release rate with reduced pressure traces regardless of the dwell time between injections and fuel type.

In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.

High pressure fuel injection and a micro-hole nozzle were used with a rapid compression machine to study soot and nitrogen oxide reduction by creating a uniform and lean fuel distribution in the combustion chamber. The rapid compression machine was optically accessible, which allowed high-speed photography and subsequent two-color flame temperature and soot concentration measurements to be made. In addition, band spectrum radical luminescence images were also observed.

In order to clarify the reason why NOx emissions factor becomes higher at vehicle acceleration at intersections etc, two freight vehicles, that have EGR system for the reduction of NOx, were tested by an on-board NOx measurement system. Higher NOx emissions factor was observed in operations in lower-gear operation for each vehicle. Since the engine speed change was higher in the operation of lower gears, NOx emissions characteristics were analyzed in view of engine torque, NOx mass emissions and EGR rate, considering engine speed change. It was found that lower-gear operations made the engine speed change higher and the EGR rate lower. This seems to be one of the factors to engender the intensive NOx pollution at roadsides.

Auto-ignition, which is observed in homogeneous and premixed charge compression ignition engines, allows expansion of the lean flammability limit of engine operation and realization of stable ignition and combustion over a range of ultra-lean conditions, where NOx emissions are very low. In this study, the basic combustion mechanism of auto-ignition and combustion was studied with initial mixture temperatures and compression speeds for n-butane and dimethyl ether. A single-mode type heat release process was observed with n-butane in the homogeneous charge compression ignition test engine.

Homogeneous Charge Compression Ignition (HCCI) is good method to be higher efficiency and to reduce NOx emission and particular matter together than conventional SI combustion engine. But HCCI depends on chemical reaction of fuel and air mixture. So controlling of ignition timing is difficult, and HCCI is high THC and CO emissions because temperature can't reach the enough temperature to reduce those. In this study, we investigated factor for auto ignition timing and combustion completion on n-Butane/Air mixture by a two-stroke HCCI engine. Auto Ignition temperature are known to be decided by fuel(1), for n-Butane, the temperature was 1150±30K. And as we researched combustion completion from In-cylinder gas temperature, increasing In-cylinder gas temperature caused high combustion efficiency and low THC, CO emissions.

Homogeneous Charge Compression Ignition (HCCI) engine attracts much attention because of its high thermal efficiency and low NOx, PM emissions. On the other hand, Di-Methyl Ether (DME) is expected as one of alternative fuel for the internal combustion engines. In this study, four-stroke HCCI engine running on DME is developed to make it realistic application in production engines. This paper shows construction of the control method using both internal EGR at high temperature and external EGR at low temperature and estimates the performance of developed HCCI engine. Besides combustion characteristics of DME and the effects of EGR are researched with experiment and numerical calculation with elementary reactions. As a result, developed HCCI engine got comparable high thermal efficiency to conventional diesel engine but much lower Indicated Mean Effective Pressure (IMEP) than that. Meanwhile it can be said that DME is suitable fuel for the HCCI engines in combustion characteristics.