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Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

Off-cycle emissions from seven different types of 1994 light-duty vehicles were examined The test fleet consisted of 19 individual vehicles including a passenger car, two makes of light light-duty trucks, and five types of heavy light-duty trucks The driving cycles used for these tests were the US06(hard acceleration, high speed) cycle and the 20 °F FTP (the “Cold FTP”) Conventional FTPs were done for comparison Each vehicle was usually operated on at least two of the following CNG, LPG, Federal Phase 1 reformulated gasoline (FP1 RFG), and a low sulfur certification gasoline For both the conventional FTP and the US06 cycles, the alternative fuels produce statistically significant benefits in Ozone Forming Potential and exhaust toxics but the NOx emissions are not statistically different from those when operating on FP1 RFG with at least 90% confidence During Cold FTP tests, the emissions of CO and of toxics when operating on FP1 RFG are not statistically different from those when operating on a low sulfur certification gasoline In contrast the alternative fuels produce statistically significant benefits in the emissions of both CO and toxics compared to either of the gasolines during Cold FTP tests The Reactivity Adjustment Factor calculated from the present conventional FTP results for CNG agrees closely with the CARB value However, the present RAF for LPG is about half CARB s value, which is believed to be a consequence of the low propene in Texas LPG compared to the high propene in California LPG The effects of the test type on the emissions are also discussed

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested over the Federal Test Procedure (FTP) driving cycle. Speciated engine-out hydrocarbon emissions were measured. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. One of the blended fuels was CARB Phase 2 reformulated gasoline which was used as the reference fuel. The remaining four blended fuels were made from refinery components to meet specified distillation profiles. The pure hydrocarbon fuels were iso-octane and toluene - an alkane and an aromatic with essentially identical boiling points. The five blended fuels can be grouped to examine the effects of fuel volatility and MTBE. Additionally, correlations were sought between the fuel properties and the Specific Reactivity, the exhaust “toxics”, and the pass-through of unburned fuel species.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.