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A reduced autoignition mechanism for iso-octane has been developed by identifying paths to formation of the stable species measured during motoring knock experiments and eliminating paths to formation of species that were not measured. The resulting mechanism includes low-, intermediate-, and high-temperature reactions and consists of 103 species and 131 reactions. This mechanism differs from detailed models not only in the number of reactions and species, but most importantly, in the nature and rates of the degenerate chain branching reactions. To implement this mechanism, a knock subroutine has been added to a quasidimensional spark ignition engine model that accounts for heat losses, blowby, etc. Thus, errors in the reactivity predictions can be assigned almost exclusively to the kinetics. Numerical predictions of the exhaust composition during motoring knock are compared with experimental measurements as a function of compression ratio for several operating conditions.

It is a very challenging problem to reliably ignite extremely lean mixtures, especially for the low speed, high load conditions of large-bore natural gas engines. If these engines are to be use for the distributed power generation market, it will require operation with higher boost pressures and even leaner mixtures. Both place greater demands on the ignition system. The railplug is a very promising ignition system for lean burn natural gas engines with its high-energy deposition and high velocity plasma arc. It requires care to properly design railplugs for this new application, however. For these engines, in-cylinder pressure and mixture temperature are very high at the time of ignition due to the high boost pressure. Hot spots may exist on the electrodes of the ignitor, causing pre-ignition problems. A heat transfer model is proposed in this paper to aid the railplug design. The electrode temperature was measured in an operating natural gas engine.