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Technical Paper

The Effect of Friction Modifiers and DI Package on Friction Reduction Potential of Next Generation Engine Oils: Part II Aged Oils

2019-04-02
2019-01-0303
Engine oil plays an important role in improving fuel economy of vehicles by reducing frictional losses in an engine. Our previous investigation explored the friction reduction potential of next generation engine oils by looking into the effects of friction modifiers and dispersant Inhibitor packages when engine oil was fresh. However, engine oil starts aging the moment engine start firing because of high temperature and interactions with combustion gases. Therefore, it is more relevant to investigate friction characteristics of aged oils. In this investigation, oils were aged for 5000 miles in taxi cab application.
Journal Article

Proof-of-Principle Investigation into the Use of Custom Rapid Aging Procedures to Evaluate and Demonstrate Catalyst Durability

2010-10-25
2010-01-2269
The application of accelerated catalyst aging procedures on an engine dynamometer test bed for the purpose of demonstrating catalyst durability is examined. A proof-of-principle approach is followed using catalysts from vehicles certified to U.S. Tier 2 Bin 4 and California SULEV 2 levels. Accelerated durability demonstration methods based upon conventional fuel cut cycles were employed to age catalysts to levels predicted by quantification of thermal catalyst bed severity on the Standard Road Cycle (SRC) relative to the fuel cut aging cycle using the Bench Aging Time (BAT) equation. Emissions deterioration on the accelerated aging cycle is compared to the automobile manufacturers' certification values and to whole vehicle emissions performance results from several different in-use vehicle fleets. The influence of technology on whole vehicle emissions levels and deterioration characteristics is also evaluated.
Technical Paper

Physicochemical Mechanisms for Fluoroelastomer Seal Failures

2016-10-17
2016-01-2272
Elastomer compatibility is an important property of lubricants. When seals degrade oil leakages may occur, which is a cause of concern for original equipment manufacturers (OEMs) because of warranty claims. Leakage is also a concern for environmental reasons. Most often, the mechanical properties and fitting of the oil seals is identified as the source of failure, but there are cases where the interaction between the lubricant and the seal material can be implicated. The performance of seal materials in tensile testing is a required method that must be passed in order to qualify lubricant additive packages. We conducted an extensive study of the interactions between these elastomeric materials and lubricant additive components, and their behavior over time. The physicochemical mechanisms that occur to cause seal failures will be discussed.
Journal Article

Lubricants for (Hybrid) Electric Transmissions

2013-04-08
2013-01-0298
In electric or hybrid electric transmissions, the transmission fluids can be in contact with the parts of the electric motors, for example, electrical windings in the stators in order to efficiently cool the electric motors and to insulate the electrical parts to prevent a short circuit of the electric motors. The transmission fluids must therefore have low electrical conductivities [1,2,3,4,5,6,7,8,9]. Transmission fluids contain dispersants, which can be reaction products of hydrocarbyl substituted carboxylic acids or anhydrides and amines. These dispersants can be further post-treated with boron and phosphorus compounds to improve friction and anti-wear properties. Certain dispersants, which have nitrogen content up to 10,000 ppm by weight, and boron plus phosphorus to nitrogen ((B+P)/N) weight ratios of from 0.1 to about 0.8 : 1.0, were found to be effective to provide low electrical conductivities less than 1,700 pS/m [10].
Journal Article

Impact of Particle Characteristics and Engine Conditions on Deposit-Induced Pre-Ignition and Superknock in Turbocharged Gasoline Engines

2017-10-08
2017-01-2345
Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.
Technical Paper

Impact of Engine Oil Detergent on Low Speed Pre-Ignition (LSPI) and Fuel Economy Performance

2020-04-14
2020-01-1424
Low Speed Pre-Ignition (LSPI), also referred to as Stochastic Pre-Ignition (SPI), Superknock or Megaknock is an undesirable combustion phenomenon that limits the fuel economy, drivability, emissions and durability performance of modern turbocharged gasoline engines. Numerous studies have previously reported that the frequency of LSPI is sensitive to engine oil composition. One of these drivers is the concentration of Calcium, which is usually delivered in the form of a detergent in the additive package. Switching to completely all-Magnesium detergent and/or severely limiting the concentration of Ca in the engine oil have recently been proposed as potential means to reduce LSPI. In this work, we evaluate the impact of detergent type on LSPI performance as well as on other performance that the modern engine oil needs to deliver. Particularly the impact of detergent type on Fuel Economy performance is evaluated.
Journal Article

Fuel Economy Beyond ILSAC GF-5: Correlation of Modern Engine Oil Tests to Real World Performance

2012-09-10
2012-01-1618
A host of bench and engine tests have historically been used by formulators to assess fuel economy when developing engine oils for gasoline-powered passenger cars and light trucks. Some of these methods assess basic lubricant physical properties such as hydrodynamic, boundary and thin-film friction, and are useful for quickly screening experimental components and formulations. Some methods assess rotational drag of a motored engine and offer insights into the friction of various engine parts. Still other methods directly measure the energy consumption in a test engine running in a research laboratory and thus come the closest to simulating a consumer-operated vehicle. Each test method has inherent limitations and is based on underlying assumptions, producing artifacts that must first be understood and then analyzed for relevance to either industry lubricant specifications or real world fuel economy performance.
Journal Article

Formation of Intake Valve Deposits in Gasoline Direct Injection Engines

2016-10-17
2016-01-2252
Gasoline direct-injection (GDI) engines have a well-known propensity to form intake valve deposits (IVD), regardless of operator service, engine architecture, or cylinder configuration. Due to the lack of a fuel-washing process that is typical of Port Fuel Injected (PFI) engines, the deposits steadily accumulate over time and can lead to deterioration in combustion, unstable operation, valve-sticking, or engine failure. Vehicles using these engines are often forced to undergo expensive maintenance to mechanically remove the deposits, which eventually re-form. The deposit formation process has not been well-characterized and there is no standardized engine test to study the impact of fuel or lubricant formulation variables. To meet this need, a proprietary vehicle-based GDI-IVD test that is both repeatable and responsive to chemistry has been developed.
Technical Paper

Fluid Effects on Shifting Clutch Friction

2016-10-17
2016-01-2206
Good shift quality in automatic transmissions is important for fuel efficiency, driver comfort, and performance. Maintaining this performance over the life of the vehicle is also important. Typically lubricant development focuses on reducing viscosity and friction in order to reduce parasitic losses. In an automatic transmission other factors are also important for good performance, primarily due to the shifting clutches and the torque converter clutch. A high level of friction is desirable for torque capacity and a steady decrease in friction as sliding speed (rpm) decreases is necessary for both good shift feel and good friction system durability over the lifetime of the vehicle. Changes in the friction system over time that result in a lowering of the friction level, particularly at higher sliding speeds, compromise the performance of both types of clutches.
Technical Paper

Engine Accelerated Aging Method Developed to Study the Effect of Lubricant Formulations on Catalyzed Gasoline Particulate Filter Durability

2018-09-10
2018-01-1804
Catalyzed gasoline particulate filter (cGPF) is the prime technology to meet future stringent regulations for particulates from gasoline direct injection (GDI) engines. One of the technical concerns is the ultimate durability of cGPF in regards to engine lubricant formulations. This study investigated two tailored lubricant formulations on catalyzed GPFs which were aged on engine followed by emission testing on vehicle. An engine accelerated aging protocol was developed for cGPFs to simulate thermal aging, ash and soot loading that is at least equivalent to 200,000 km durability requirement. Evaluations include tailpipe emission levels, backpressure, catalytic performance, and post-mortem analysis. Both formulations have demonstrated a high level of cGPF performance retention; performance being assessed in terms of emission level at the end of durability demonstration testing. These formulations provide flexibility in selecting robust lubricant to meet various system requirements.
Technical Paper

Effects of Aromatic and Olefin on the Formations of PAHs in GDI Engine

2017-10-08
2017-01-2390
In this paper, the impacts of Aromatic and Olefin on the formation of poly-aromatic hydrocarbons (PAHs) in the gasoline direct injection (GDI) engine were experimentally and numerically investigated. The objective of this study is to describe the formation process of the soot precursors including one ring to four ring aromatics (A1-A4). In order to better understand the effects of the fuel properties on the formations of PAHs. Three types of fuels, namely base gasoline, gasoline with higher aromatics content, and gasoline with higher olefin content were experimentally studied. At the same time, these aspects were also numerically investigated in the CHEMKIN code by using premixed laminar flame model and surrogated fuels. The results show that higher aromatics content in gasoline will lead to much higher PAHs formation. Similar trend was also found in the gasoline with higher olefin content.
Technical Paper

Effect of Oil and Gasoline Properties on Pre-Ignition and Super-Knock in a Thermal Research Engine (TRE) and an Optical Rapid Compression Machine (RCM)

2016-04-05
2016-01-0720
High boost and direct injection are effective ways for energy saving in gasoline engines. However, the occurrence of super-knock at high load has become a main obstacle for further improving power density and fuel economy. It has been known that super-knock can be induced by pre-ignition, and oil droplet auto-ignition is found to be one of the possible mechanisms. In this study, experiments were conducted in a single-cylinder thermal research engine (TRE), in which different types of oil and surrogates were directly injected into the cylinder and then led to pre-ignition and super-knock. The effect of oil injection timing, oil injection quantity, different gasoline and different oil were tested. All the oil in this work could induce pre-ignition, even though their combustion phasing was much later than that in the case of n-hexadecane.
Technical Paper

Effect of Ash on Gasoline Particulate Filter Using an Accelerated Ash Loading Method

2018-04-03
2018-01-1258
Gasoline particulate filter (GPF) is considered a suitable solution to meet the increasingly stringent particle number (PN) regulations for both gasoline direct injection (GDI) and multi-port fuel injection (MPI) engines. Generally, GDI engines emit more particulate matter (PM) and PN. In recent years, GDI engines have gained significant market penetration in the automobile industry owing to better fuel economy and drivability. In this study, an accelerated ash loading method was tested by doping lubricating oil into the fuel for a GDI engine. Emission tests were performed at different ash loads with different driving cycles and GPF combinations. The results showed that the GPF could significantly reduce particle emissions to meet the China 6 regulation. With further ash loading, the filtration efficiency increased above 99% and the effects on fuel consumption and backpressure were found to be limited, even with an ash loading of up to 50 g/l.
Journal Article

Development of a Novel Vehicle-Based Method to Assess the Impact of Lubricant Quality on Passenger Car Energy Efficiency

2012-09-10
2012-01-1619
The traditional vehicle-based approach to measuring the effect of oil-related fuel economy has relied on separate oil-aging and measurement processes where oil-aging takes place using an established driving protocol like the EPA Approved Mileage Accumulation (AMA) Driving Schedule for vehicle aging, then at set mileage intervals fuel economy is assessed using procedures such as the EPA FTP75 and Highway Fuel Economy emission test protocols described in 40 CFR, Parts 86 and 600. These test methods are useful for producing discrete snapshots of fuel economy at set mileage intervals but are unable to provide continuous information about oil-related changes in fuel economy. During the tests, the vehicle's fuel economy is indirectly calculated using a carbon-balance method of the bagged sample of dilute tailpipe emissions that effectively integrates the fuel economy of the vehicle during the sample interval which varies between eight and fifteen minutes.
Technical Paper

Correlation of the Sequence VID Laboratory Fuel Economy Test to Real World Fuel Economy Improvements

2013-04-08
2013-01-0297
When gasoline-fueled vehicles are operated in consumer service, the oil used to lubricate the engine plays a key role in engine cooling, reducing friction, maintaining efficient operation, and optimizing fuel economy. The effects of normal vehicle operation on oil deterioration have a direct impact on fuel consumption. The authors have observed substantial differences between the deterioration of engine oil and resulting fuel economy under real-world driving conditions, and the deterioration of oils and resulting fuel economy in the standard laboratory test used to assess fuel economy in North America, the Sequence VID engine test (ASTM D7589). By analyzing the data from vehicles and comparing these data to the Sequence VID the authors have proposed and evaluated several changes to the Sequence VID test that improve the correlation with real-world operation and improve test discrimination.
Technical Paper

Continuously Variable Transmission (CVT) Fuel Economy

2017-10-08
2017-01-2355
Due to its simplicity and fuel economy benefit, continuously variable transmission (CVT) technology has gained a lot of attention in recent years. Market penetration of CVT technology is increasing rapidly compared to step-type automatic transmission technology. OEMs, Tier 1 suppliers, and lubricant suppliers are working to further improve the fuel economy benefit of CVTs. As a lubricant supplier, we want to understand the effects of fluid properties on CVT fuel economy (FE). We have formulated fluids that had KV100 ranges from 2-4 cSt to 7-9 cSt with various types and viscosities of base oils. Wide ranges of viscosity indexes, steel-on-steel friction, and other properties were tested. Full vehicle fuel economy tests were performed in a temperature controlled environment with a robotic driver. The test revealed that there was more than 3% overall FE variation compared to a reference fluid.
Technical Paper

Catalyzed Gasoline Particulate Filter (GPF) Performance: Effect of Driving Cycle, Fuel, Catalyst Coating

2017-10-08
2017-01-2366
Because of the increased use of gasoline direct engine (GDI) in the automobile industry, there is a significant need to control particulates from GDI engines based on emission regulations. One potential technical approach is the utilization of a gasoline particulate filter (GPF). The successful adoption of this emission control technology needs to take many aspects into consideration and requires a system approach for optimization. This study conducted research to investigate the impact of vehicle driving cycles, fuel properties and catalyst coating on the performance of GPF. It was found that driving cycle has significant impact on particulate emission. Fuel quality still plays a role in particulate emissions, and can affect the GPF performance. Catalyzed GPF is preferred for soot regeneration, especially for the case that the vehicle operation is dominated by congested city driving condition, i.e. low operating temperatures. The details of the study are presented in the paper.
Journal Article

A General Method for Fouling Injectors in Gasoline Direct Injection Vehicles and the Effects of Deposits on Vehicle Performance

2017-10-08
2017-01-2298
The ubiquity of gasoline direct injection (GDI) vehicles has been rapidly increasing across the globe due to the increasing demand for fuel efficient vehicles. GDI technology offers many advantages over conventional port fuel injection (PFI) engines, such as improvements in fuel economy and higher engine power density; however, GDI technology presents unique challenges as well. GDI engines can be more susceptible to fuel injector deposits and have higher particulate emissions relative to PFI engines due to the placement of the injector inside the combustion chamber. Thus, the need for reliable test protocols to develop next generation additives to improve GDI vehicle performance is paramount. This work discloses a general test method for consistently fouling injectors in GDI vehicles and engines that can accommodate multiple vehicle/engine types, injector designs, and drive cycles, which allows for development of effective GDI fuel additives.
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