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Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.

Propagation-based and phase-enhanced x-ray imaging was developed as a unique metrology technique to visualize the internal structure of high-pressure fuel injection nozzles. We have visualized the microstructures inside 200-μm fuel injection nozzles in a 3-mm-thick steel housing using this novel technique. Furthermore, this new x-ray-based metrology technique has been used to directly study the highly transient needle motion in the nozzles in situ and in real-time, which is virtually impossible by any other means. The needle motion has been shown to have the most direct effect on the fuel jet structure and spray formation immediately outside of the nozzle. In addition, the spray cone-angle has been perfectly correlated with the numerically simulated fuel flow inside the nozzle due to the transient nature of the needle during the injection.

An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).

Several plug-in hybrid electric vehicles (PHEVs) have recently been made available by conversion companies for laboratory testing. The viability of the technology must be evaluated by dynamometer benchmark testing, but because the technology is so new, existing and new test methods must first be investigated. Converted Gen 2 Toyota Prius vehicles from Hymotion, EnergyCS, and Hybrids Plus were tested at Argonne's dynamometer facility according to general testing concepts. These vehicles all share basic attributes - all are blended type PHEVs, all use Lithium battery technology, and all deplete charge in a similar fashion (although at different rates). In a time span of one year, lessons learned from one vehicle were carried over into the next test vehicle. A minimum test method was formulated that is well suited for all these vehicles. The method was validated with two vehicles of varying charge-depleting range.

Recovering metals from obsolete automobiles, home appliances, and other metal-containing obsolete durables and other scrap involves shredding these objects and separating the reusable metals from the shredded material by using magnets, eddy current separators, and metal detectors. Over 12 million automobiles are shredded annually in the United States alone, and almost all of the 4.5 million metric tonnes (5 million short tons) of the shredder residue produced in the United States annually is disposed of in landfills. Over 13.6 million tonnes (15 million tons) of shredder residue is generated worldwide every year. The rise in disposal costs is further exacerbated in that the percentage of shredder residue that must be disposed of, in comparison with the percentage of marketable recovered metals, is increasing because of the increasing content of polymers in automobiles and in home appliances.

A new type of approval procedure for light-duty vehicles, the Worldwide harmonized Light vehicles Test Procedure (WLTP), developed by an initiative of the United Nations Economic Commission for Europe, will come into force by the end of 2017. The current European type-approval procedure for energy consumption and CO2 emissions of cars, the New European Driving Cycle (NEDC), includes a number of tolerances and flexibilities that no longer accurately reflect state-of-the-art technologies. Indeed, on the basis of an analysis of real-world driving data from the German website spritmonitor.de, the ICCT concluded that the differences between official laboratory and real-world fuel consumption and CO2 values were around 7% in 2001. This discrepancy has been increasing continuously since then to around 30% in 2013, with notable differences found between individual manufacturers and vehicle models.

Disposal of automobile shredder residue (ASR), remaining from the reclamation of steel from junked automobiles, promises to be an increasing environmental and economic concern. Argonne National Laboratory (ANL) is investigating alternative technology for recovering value from ASR while also, it is hoped, lessening landfill disposal concerns. Of the ASR total, some 20% by weight consists of plastics. Preliminary work at ANL is being directed toward developing a protocol, both mechanical and chemical (solvent dissolution), to separate and recover polyurethane foam and the major thermoplastic fraction from ASR. Feasibility has been demonstrated in laboratory-size equipment.

Over 250 million vehicles are operating on United States roads and highways and over 12 million of them reach the end of their useful lives annually. These end-of-life vehicles (ELVs) contain over 24 million tons (21.8 million metric tonnes) of materials including ferrous and non-ferrous metals, polymers, glass, and automotive fluids. They also contain many parts and components that are still useable and some that could be economically rebuilt or remanufactured. Dismantlers acquire the ELVs and recover from them parts for resale “as-is” or after remanufacturing. The dismantler then sells what remains of the vehicle, the “hulk”, to a shredder who shreds it to recover and sell the metals. Presently, the remaining non-metallic materials, commonly known as shredder residue, are mostly landfilled. The vehicle manufacturers, now more than ever, are working hard to build more energy efficient and safer, more affordable vehicles.

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

Limited battery power and poor engine efficiency at cold temperature results in low plug in hybrid vehicle (PHEV) fuel economy and high emissions. Quick rise of battery temperature is not only important to mitigate lithium plating and thus preserve battery life, but also to increase the battery power limits so as to fully achieve fuel economy savings expected from a PHEV. Likewise, it is also important to raise the engine temperature so as to improve engine efficiency (therefore vehicle fuel economy) and to reduce emissions. One method of increasing the temperature of either component is to maximize their usage at cold temperatures thus increasing cumulative heat generating losses. Since both components supply energy to meet road load demand, maximizing the usage of one component would necessarily mean low usage and slow temperature rise of the other component. Thus, a natural trade-off exists between battery and engine warm-up.

As emerging automated vehicle technology is making advances in safety and reliability, engineers are also exploring improvements in energy efficiency with this new paradigm. Powertrain efficiency receives due attention, but also impactful is finding ways to reduce driving losses in coordinated-driving scenarios. Efforts focused on simulation to quantify road load improvements require a sufficient amount of background validation work to support them. This study uses a practical approach to directly quantify road load changes by testing the coordinated driving of two vehicles on a test track at various speeds (64, 88, 113 km/h) and vehicle time gaps (0.3 to 1.3 s). Axle torque sensors were used to directly measure the load required to maintain steady-state speeds while following a lead vehicle at various gap distances.

While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO2 emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. Our research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems.

The addition of metal nanoparticles to standard coolant fluids dramatically increases the thermal conductivity of the liquid. The properties of the prepared nanofluids will allow for lighter, smaller, and higher efficiency spacecraft thermal control systems to be developed. Nanofluids with spherical or rod-shaped metal nanoparticles were investigated. At a volume concentration of 0.5%, the room temperature thermal conductivity of a 2 nm spherical gold nanoparticle-water solution was increased by more than 10% over water alone. Silver nanorods increased the thermal conductivity of ethylene glycol by 53% and water by 26%.

Applying nanotechnology to thermal engineering, ANL has addressed the interesting and timely topic of nanofluids. We have developed methods for producing both oxide and metal nanofluids, studied their thermal conductivity, and obtained promising results: (1) Stable suspensions of nanoparticles can be achieved. (2) Nanofluids have significantly higher thermal conductivities than their base liquids. (3) Measured thermal conductivities of nanofluids are much greater than predicted. For these reasons, nanofluids show promise for improving the design and performance of vehicle thermal management systems. However, critical barriers to further development and application of nanofluid technology are agglomeration of nanoparticles and oxidation of metallic nanoparticles. Therefore, methods to prevent particle agglomeration and degradation are required.

Microstructure level inhomogeneities between the harder martensite phase and the softer ferrite phase render the dual phase (DP) steels more complicated failure mechanisms and associated failure modes compared to the conventionally used low alloy homogenous steels. This paper examines the failure mode DP780 steel under different loading conditions using finite element analyses on the microstructure levels. Micro-mechanics analyses based on the actual microstructures of DP steel are performed. The two-dimensional microstructure of DP steel was recorded by scanning electron microscopy (SEM). The plastic work hardening properties of the ferrite phase was determined by the synchrotron-based high-energy X-ray diffraction technique. The work hardening properties of the martensite phase were calibrated and determined based on the uniaxial tensile test results. Under different loading conditions, different failure modes are predicted in the form of plastic strain localization.

Many leading companies in the automotive industry have been putting tremendous amount of efforts into developing new designs and technologies to make their products more energy efficient. It is straightforward to evaluate the fuel economy benefit of an individual technology in specific systems and components. However, when multiple technologies are combined and integrated into a whole vehicle, estimating the impact without building and testing an actual vehicle becomes very complex, because the efficiency gains from individual components do not simply add up. In an early concept phase, a projection of fuel efficiency benefits from new technologies will be extremely useful; but in many cases, the outlook has to rely on engineer’s insight since it is impractical to run tests for all possible technology combinations.

The process of shredding end-of-life vehicles to recover metals results in a byproduct commonly referred to as shredder residue. The four and a half million metric tons of shredder residue produced annually in the United States is presently land filled. To meet the challenges of automotive materials recycling, the U.S. Department of Energy is supporting research at Argonne National Laboratory in cooperation with the Vehicle Recycling Partnership (VRP) of the United States Council for Automotive Research (USCAR) and the American Plastics Council. This paper presents the results of a study that was conducted by Argonne to determine variations in the composition of shredder residue from different shredders. Over 90 metric tons of shredder residues were processed through the Argonne pilot plant. The contents of the various separated streams were quantitatively analyzed to determine their composition and to identify materials that should be targeted for recovery.

Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.

Many problems are associated with applying standardized vehicle test methods, such as the Federal Test Procedure (FTP), to hybrid electric vehicles (HEVs). Since 1992, the Society of Automotive Engineers' (SAE's) HEV Test Procedure Task Force has been working on developing a standard procedure for HEV testing (Draft SAE J1711). Because the current draft requires considerable knowledge of the vehicle's response to the test cycles, still has unresolved problems, and is too lengthy, Argonne National Laboratory (ANL) uses portions of past J1711 drafts in combination with concepts developed through many HEV tests (over 50 to date) for its HEV competition testing. Successful vehicle characterization was achieved at the 1997 FutureCar Challenge competition by characterizing each vehicle's individual operational modes in such a way that the elements of the FTP and Federal Highway Test were satisfied.

Reductions in vehicle drive losses are as important to improving fuel economy as increases in powertrain efficiencies. In order to measure vehicle fuel economy, chassis dynamometer testing relies on accurate road load determinations. Road load is currently determined (with some exceptions) using established test track coastdown testing procedures. Because new vehicle technologies and usage cases challenge the accuracy and applicability of these procedures, on-road experiments were conducted using axle torque sensors to address the suitability of the test procedures in determining vehicle road loads in specific cases. Whereas coastdown testing can use vehicle deceleration to determine load, steady-state testing can offer advantages in validating road load coefficients for vehicles with no mechanical neutral gear (such as plug-in hybrid and electric vehicles).