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The modeling of transient phenomena occurring inside an automotive 3-way catalytic converter poses a significant challenge to the emissions control engineer. Since the significant progress that has been observed with steady-state models cannot be directly exploited in this direction, it is necessary to develop a fully transient model and computer code incorporating dynamic behaviour of the three way catalytic converter in a relatively simple and effective way. The Laboratory of Applied Thermodynamics (LAT), Aristotle University Thessaloniki, is cooperating with the Engine Direction of FIAT Research Center, in the development of a computer code fulfilling these objectives, within the framework of an EEC Brite EuRam cost shared project. The CRF and LAT modeling approaches, along with the underlying philosophy and experimental work, are presented in this paper.

Particle emissions have been generally associated to diesel engines. However, spark-ignition direct injection (SI-DI) engines have been observed to produce notable amounts of particulate matter as well. The upcoming Euro 6 legislation for passenger cars (effective in 2014, stricter limit in 2017) will further limit the particulate emissions from SI engines by introducing a particle number emission (PN) limit, and it is not probable that the SI-DI engines are able to meet this limit without resorting to additional aftertreatment systems. In this study, the solid particle emissions of a SI-DI passenger car with and without an installed Particle Oxidation Catalyst (POC®) were studied over the New European Driving Cycle (NEDC) on a chassis dynamometer and over real transient acceleration situations on road. It was observed that a considerable portion of particle number emissions occurred during the transient acceleration phases of the cycle.

This study examines the effects of neat soy-based biodiesel (B100) and its 50% v/v blend (B50) with low sulphur automotive diesel on vehicle PAH emissions. The measurements were conducted on a chassis dynamometer with constant volume sampling (CVS) according to the European regulated technique. The vehicle was a Euro 2 compliant diesel passenger car, equipped with a 1.9 litre common-rail turbocharged direct injection engine and an oxidation catalyst. Emissions of PAHs, nitro-PAHs and oxy-PAHs were measured over the urban phase (UDC) and the extra-urban phase (EUDC) of the type approval cycle (NEDC). In addition, for evaluating realistic driving performance the non-legislated Artemis driving cycles (Urban, Road and Motorway) were used. Overall, 12 PAHs, 4 nitro-PAHs, and 6 oxy-PAHs were determined. The results indicated that PAH emissions exhibited a reduction with biodiesel during all driving modes.

Even though the 3-way catalyst chemistry has been studied extensively in the literature, some performance aspects of practical relevance have not been fully explained. It is believed that the Oxygen Storage Capacity function of 3-way catalytic components dominates the behavior during stoichiometry transitions from lean to rich mode and vice versa whereas a number of mathematical models have been proposed to describe the dynamics of pollutant conversion. Previous studies have suggested a strong impact of Sulfur on the pollutant conversion after a lean to rich transition, which has not been adequately explained and modelled. Lean to rich transitions are highly relevant to catalyst ‘purging’ needed after exposure to high O2 levels (e.g. after fuel cut-offs). This work presents engine test measurements with an engine-aged catalyst that highlight the negative impact of Sulfur on pollutant conversion after a lean to rich transition.

Particulate filters are a widely used emission control device on heavy-duty diesel engines. The accumulation of particulate matter, mostly consisting of soot, inside the filter results in increased filter pressure-drop (backpressure). This increased backpressure has been used by the on-board control systems as trigger for regeneration procedures, which aim to actively oxidize the accumulated soot. However, it is known that passive soot oxidation during normal operation affects the correlation between backpressure and the deposited soot mass in filter. Therefore, the backpressure alone cannot be a reliable trigger for regeneration. In this work we highlight operating conditions with very poor correlation between backpressure and accumulated soot mass in filter and evaluate the possible root causes. Experiments with several heavy-duty diesel engines and particulate filters were conducted on engine test bench.

This presentation will introduce the overall goals of the EcoCAR competition in brief, and will go into the third and final year of the competition in detail. The final year of competition saw teams refining and testing their student-built advanced technology vehicles including hybrids, plug-in hybrids, hydrogen fuel cell PHEVs and one battery electric. Important events, such as the Spring Workshop chassis dynamometer testing event at the U.S. Environmental Protection agency, as well as significant competition results, such as vehicle performance, consumer acceptability and efficiency will be presented. Presenter Patrick Walsh

The aim of this paper is to analyze the quantitative impact of fuel sulfur content on particulate oxidation catalyst (POC) functionality, focusing on soot emission reduction and the ability to regenerate. Studies were conducted on fuels containing three different levels of sulfur, covering the range of 6 to 340 parts per million, for a light-duty application. The data presented in this paper provide further insights into the specific issues associated with usage of a POC with fuels of higher sulfur content. A 48-hour loading phase was performed for each fuel, during which filter smoke number, temperature and back-pressure were all observed to vary depending on the fuel sulfur level. The Fuel Sulfur Content (FSC) affected also soot particle size distributions (particle number and size) so that with FSC 6 ppm the soot particle concentration was lower than with FSC 65 and 340, both upstream and downstream of the POC.

The effect of a novel particle oxidation catalyst (POC®) on diesel particle emissions is studied in heavy duty and light duty applications. Regulated particulate matter (PM) emission measurement is followed by analyzing either soluble organic fraction (SOF) or volatile organic (VOF) fraction. In addition, in heavy duty diesel application, size distributions are measured. Results show that PM reductions as high as 48-79% can be achieved when using POC in combination with a conventional diesel oxidation catalyst (DOC). As expected, the volatile fraction of the PM was very effectively reduced, but also the non-volatile fraction (i.e. soot) was reduced. In tested steady state driving modes soot reduction was found to be 31-55%.

Legislations worldwide have started imposing stringent emission standards for particulate matter (PM) emitted by diesel engines. The main reason for these actions is the adverse effects on human health caused by particle emissions. Conventional ceramic Diesel Particulate Filters (DPF) have proven exceptionally effective in reducing particulate emissions with efficiencies of 90% or more. However, these filters require regular active regenerations as well as periodical ash removal in order to avoid a blockage of the exhaust line. These procedures are both costly and complex and as a result alternative aftertreatment solutions have been developed. One of these solutions is the Particle Oxidation Catalyst, POC-X. The main aim of the POC-X is not to equal the high efficiencies of the DPF, but to achieve the best possible particle reduction without creating the risk of blocking or the need for complex filter regeneration procedures.

As the Diesel Particulate Filter (DPF) technology is nowadays established, research is currently focusing on meeting the emission and durability requirements by proper system design. This paper focuses on the optimum combination between the catalytic coating and substrate structural properties using experimental and simulation methodologies. The application of these methodologies will be illustrated for the case of SiC substrates coated with innovative sol-gel coatings. Coated samples are characterized versus their uncoated counterparts. Multi-dimensional DOC and DPF simulation models are used to study several effects parametrically and increase our understanding on the governing phenomena. The comparative analysis of DOC/DPF systems covers filtration – pressure drop characteristics, CO/HC/NO oxidation performance, effect of washcoat amount and catalyst dispersion on oxidation activity and finally passive regeneration performance.

The pressure for compact and efficient deNO systems has led to increased interest of incorporating SCR coatings in the DPF walls. This technology could be very attractive especially if high amounts of washcoat loadings could be impregnated in the DPF porous walls, which is only possible with high porosity filters. To counterbalance the filtration and backpressure drawbacks from such high porosity applications, the layered wall technology has already been proposed towards minimizing soot penetration in the wall and maximizing filtration efficiency. In order to deal with the understanding of the complex interactions in such advanced systems and assist their design optimization, this paper presents an advanced modeling framework and selected results from simulation studies trying to illustrate the governing phenomena affecting deNO performance and passive DPF regeneration in the above combined systems.

The design of integrated exhaust lines that combine particulate and NOx emission control is a multidimensional optimization problem. The present paper demonstrates the use of an exhaust system simulation platform which is composed of well-established multidimensional mathematical models for the transient thermal and chemical phenomena in DOC, DPF and SCR systems as well as connecting pipe heat transfer effects. The analysis is focused on the European Driving Cycle conditions. Illustrative examples on complete driving cycle simulations with and without forced regeneration events are presented for alternative design approaches. The results illustrate the importance of DOC and DPF heat capacity effects and connecting pipe heat losses on the SCR performance. The possibility of combining DPF and SCR functionality on a single wall-flow substrate is studied.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

A new metal foam material for diesel particulate filtration, trademarked as INCOFOAM® HighTemp, was recently presented. Extensive tests showed the potential of achieving filtration efficiencies of the order of 85% or more at low pressure drop using a radial flow design concept with graded foam porosity. By applying a catalytic washcoat, the foam exhibits enhanced gas mixing and thus higher conversion efficiencies at high space velocities. In addition, due to an excellent soot-catalyst contact, the washcoated foam exhibited high catalytic regeneration rates. The present paper focuses on a novel “cross-flow” design concept for a better filtration/pressure drop trade-off as well as application of the foam as an oxidation catalyst substrate. The experimental testing starts from small-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests on the chassis dynamometer and on-road testing.

The objective of this study is to study the soot layer density and permeability in wall-flow diesel particulate filters. Knowledge of the soot morphology as function of the operating conditions is important for the design and on-board control of Diesel Particulate Filters (DPFs). The experimental set-up relies on a specially designed soot loading procedure on single-channel cordierite filters. The experimental conditions simulate real-world as close as possible regarding the filtration velocity, temperature and soot quality, since the sampling is done in real exhaust. By cutting, weighing and imaging the single channel filters it is possible to measure with accuracy the soot layer thickness as deposited under different operating conditions. Combined with pressure drop measurements and modeling, it is further possible to evaluate the soot layer permeability.

Natural gas and biogas alone or in combination with conventional liquid fuels (dual-fuel applications) are advanced alternative solutions to diesel and gasoline in the future. Burning of natural- or biogas produces less CO2 emissions per energy unit, and particulate matter emissions can also be reduced compared to more traditional liquefied fuels. This decrease in engine out emissions can be utilized as a tool to meet tightening emission limits and to improve the air quality locally in the areas with big challenges especially related nitrogen oxide and particulate emissions. In the present study the focus was on the development of catalytic emission control technology for both mobile and stationary lean-burn natural gas applications. Main activities were related to the oxidation catalyst and its improvements towards sulfur poisoning and to enhance methane light-off performance.

The transient heat transfer behavior of an automotive catalytic converter has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO oxidation, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters are the results of data in literature tuned by experiments. Simplified cases of constant flow rates and gas temperatures in the catalyst inflow have been chosen for a comprehensive analysis of the heat and mass transfer phenomena. The impact of inlet flow temperatures and inlet flow rates on the heat up characteristics as well as in the CO emissions have been quantified. A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinates are introduced.

The objective of this study is to present a particulate filter concept, based on a new porous material: INCOFOAM® HighTemp, a Ni-based superalloy foam. The paper examines the filtration and pressure drop characteristics as well as the regeneration performance of different filter configurations, based on experimental data and modeling. A number of different foam structures with variable pore characteristics are studied. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests on the chassis dynamometer and on-road. In parallel, a previously developed mathematical model is applied to study and understand the filtration and pressure drop mechanisms in the case of clean and soot loaded filters.

Combustion engines in hybrid vehicles turn on and off several times during a typical passenger car trip. Each engine restart may pose a risk of excessive tailpipe emissions in real-drive conditions if the after-treatment system fails to maintain an adequate temperature level during zero flow. In view of the tightening worldwide tailpipe emissions standards and real-world conformity requirements, it is important to detect and resolve such risks via cost-effective engineering tools relying on accurate 3d analysis of the thermal and chemical behavior of exhaust systems. In this work, we present a series of experiments to examine the impact of zero-flow duration on the exhaust system cooling and subsequent emissions risk. We also present a catalyst model calibrated to predict the 3d thermal and chemical behavior under normal and zero flow conditions. Particular emphasis is given to the phenomena of free convection and thermal radiation dominating the heat transfer at zero flow.

Reducing fuel consumption and emissions from road transport is a key factor for tackling global warming, promoting energy security and sustaining a clean environment. Several technical measures have been proposed in this aspect amongst which the application of low viscosity engine lubricants. Low viscosity lubricants are considered to be an interesting option for reducing fuel consumption (and CO2 emissions) throughout the fleet in a relatively cost effective way. However limited data are available regarding their actual “real-world” performance with respect to CO2 and other pollutant emissions. This study attempts to address the issue and to provide experimental data regarding the benefit of low viscosity lubricants on fuel consumption and CO2 emissions over both the type-approval and more realistic driving cycles.