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The modeling of transient phenomena occurring inside an automotive 3-way catalytic converter poses a significant challenge to the emissions control engineer. Since the significant progress that has been observed with steady-state models cannot be directly exploited in this direction, it is necessary to develop a fully transient model and computer code incorporating dynamic behaviour of the three way catalytic converter in a relatively simple and effective way. The Laboratory of Applied Thermodynamics (LAT), Aristotle University Thessaloniki, is cooperating with the Engine Direction of FIAT Research Center, in the development of a computer code fulfilling these objectives, within the framework of an EEC Brite EuRam cost shared project. The CRF and LAT modeling approaches, along with the underlying philosophy and experimental work, are presented in this paper.

Even though the 3-way catalyst chemistry has been studied extensively in the literature, some performance aspects of practical relevance have not been fully explained. It is believed that the Oxygen Storage Capacity function of 3-way catalytic components dominates the behavior during stoichiometry transitions from lean to rich mode and vice versa whereas a number of mathematical models have been proposed to describe the dynamics of pollutant conversion. Previous studies have suggested a strong impact of Sulfur on the pollutant conversion after a lean to rich transition, which has not been adequately explained and modelled. Lean to rich transitions are highly relevant to catalyst ‘purging’ needed after exposure to high O2 levels (e.g. after fuel cut-offs). This work presents engine test measurements with an engine-aged catalyst that highlight the negative impact of Sulfur on pollutant conversion after a lean to rich transition.

Particulate filters are a widely used emission control device on heavy-duty diesel engines. The accumulation of particulate matter, mostly consisting of soot, inside the filter results in increased filter pressure-drop (backpressure). This increased backpressure has been used by the on-board control systems as trigger for regeneration procedures, which aim to actively oxidize the accumulated soot. However, it is known that passive soot oxidation during normal operation affects the correlation between backpressure and the deposited soot mass in filter. Therefore, the backpressure alone cannot be a reliable trigger for regeneration. In this work we highlight operating conditions with very poor correlation between backpressure and accumulated soot mass in filter and evaluate the possible root causes. Experiments with several heavy-duty diesel engines and particulate filters were conducted on engine test bench.

The paper compares Road Racing World Championship Grand Prix (WGP) engine solutions developed in compliance with the 2002 Federation Internationale de Motocyclisme (FIM) Technical Regulations. Ad-hoc assumptions, similarity rules and nondimensional parameters from previous projects are used to define geometric and operating parameters for partly similar engine solutions basically differing in the number of cylinders, three, four, five or six, and the cylinder layout, in-line or V-angle. Results are shown as computed classical engine outputs versus engine speed, including brake, indicated and friction values. By increasing the number of cylinders, charging efficiency reduces, while thermal efficiency increases. Higher values of brake torque and power and lower values of brake specific fuel consumption are provided by the V-angle six cylinder engine.

As the Diesel Particulate Filter (DPF) technology is nowadays established, research is currently focusing on meeting the emission and durability requirements by proper system design. This paper focuses on the optimum combination between the catalytic coating and substrate structural properties using experimental and simulation methodologies. The application of these methodologies will be illustrated for the case of SiC substrates coated with innovative sol-gel coatings. Coated samples are characterized versus their uncoated counterparts. Multi-dimensional DOC and DPF simulation models are used to study several effects parametrically and increase our understanding on the governing phenomena. The comparative analysis of DOC/DPF systems covers filtration – pressure drop characteristics, CO/HC/NO oxidation performance, effect of washcoat amount and catalyst dispersion on oxidation activity and finally passive regeneration performance.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

The pressure for compact and efficient deNO systems has led to increased interest of incorporating SCR coatings in the DPF walls. This technology could be very attractive especially if high amounts of washcoat loadings could be impregnated in the DPF porous walls, which is only possible with high porosity filters. To counterbalance the filtration and backpressure drawbacks from such high porosity applications, the layered wall technology has already been proposed towards minimizing soot penetration in the wall and maximizing filtration efficiency. In order to deal with the understanding of the complex interactions in such advanced systems and assist their design optimization, this paper presents an advanced modeling framework and selected results from simulation studies trying to illustrate the governing phenomena affecting deNO performance and passive DPF regeneration in the above combined systems.

The design of integrated exhaust lines that combine particulate and NOx emission control is a multidimensional optimization problem. The present paper demonstrates the use of an exhaust system simulation platform which is composed of well-established multidimensional mathematical models for the transient thermal and chemical phenomena in DOC, DPF and SCR systems as well as connecting pipe heat transfer effects. The analysis is focused on the European Driving Cycle conditions. Illustrative examples on complete driving cycle simulations with and without forced regeneration events are presented for alternative design approaches. The results illustrate the importance of DOC and DPF heat capacity effects and connecting pipe heat losses on the SCR performance. The possibility of combining DPF and SCR functionality on a single wall-flow substrate is studied.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

The objective of this study is to study the soot layer density and permeability in wall-flow diesel particulate filters. Knowledge of the soot morphology as function of the operating conditions is important for the design and on-board control of Diesel Particulate Filters (DPFs). The experimental set-up relies on a specially designed soot loading procedure on single-channel cordierite filters. The experimental conditions simulate real-world as close as possible regarding the filtration velocity, temperature and soot quality, since the sampling is done in real exhaust. By cutting, weighing and imaging the single channel filters it is possible to measure with accuracy the soot layer thickness as deposited under different operating conditions. Combined with pressure drop measurements and modeling, it is further possible to evaluate the soot layer permeability.

In the last few years the cost analysis methodologies have progressively become indispensable tools for the administrative management of a firm. In parallel, the need to integrate them to the quantification of the environmental impacts is getting stronger and stronger. One of the most innovative approaches of integration is “Life Cycle Costing” (LCC), which determines the costs associated to the life cycle of products and processes, including also the ones deriving from their environmental impacts. An example is shown here, with reference to the economical and environmental costs related to the life cycle of a metallic vehicle component.

Using the Life Cycle Analysis methodology, a detailed study of the car glass production phases (from the extraction of raw materials until the recycling) has been developped. This kind of approach goes in the board of the new Fiat strategies to achieve declared goals of environmental efficiency, not only to adapt its choices to new parameters of law, but also to obtain advantages of competitivity on the global market. In particular, with reference to the outline of FARE (Fiat Auto REcycling) project, the end of life of used glass for cars has been evaluated; the primary products of Fiat Punto model (windshield, windshield rear and lateral windows) are recovered to remanufacture and to get a new secondary product as the glass bottles for packaging (open loop recycling), since, until now, it is impossible to have a good quality of glass for cars from the same glass scraps.

As an era of autonomous driving approaches, it is necessary to translate handling comfort - currently a responsibility of human drivers - to a vehicle imbedded algorithm. Therefore, it is imperative to understand the relationship between perceived driving comfort and human driving behaviour. This paper develops a methodology able to generate the information necessary to study how this relationship is expressed in highway overtakes. To achieve this goal, the approach revolved around the implementation of sensor Data Fusion, by processing data from CAN, camera and LIDAR from experimental tests. A myriad of variables was available, requiring individuating the key-information and parameters for recognition, classification and understanding of the manoeuvres. The paper presents the methodology and the role each sensor plays, by expanding on three main steps: Data segregation and parameter selection; Manoeuvre detection and processing; Manoeuvre classification and database generation.

Mechanical properties of EV11 engine exhaust valve steel have been determined for two different heat treatment conditions, corresponding to coarse and fine grained structure with different carbide content. Testing has been performed at room temperature, 650, 750 and 850°C; the following information has been obtained: - hardness and tensile properties - creep rate dependence on stress and temperature. The selection of engine valve material has been discussed on the basis of the above information type combined with existing models for fatigue phenomena. The role of metallurgical variables has been examined with particular regard to creep resistance, the first indication being that creep rate is unaffected by carbide particles.

The transient heat transfer behavior of an automotive catalytic converter has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO oxidation, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters are the results of data in literature tuned by experiments. Simplified cases of constant flow rates and gas temperatures in the catalyst inflow have been chosen for a comprehensive analysis of the heat and mass transfer phenomena. The impact of inlet flow temperatures and inlet flow rates on the heat up characteristics as well as in the CO emissions have been quantified. A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinates are introduced.

The objective of this study is to present a particulate filter concept, based on a new porous material: INCOFOAM® HighTemp, a Ni-based superalloy foam. The paper examines the filtration and pressure drop characteristics as well as the regeneration performance of different filter configurations, based on experimental data and modeling. A number of different foam structures with variable pore characteristics are studied. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests on the chassis dynamometer and on-road. In parallel, a previously developed mathematical model is applied to study and understand the filtration and pressure drop mechanisms in the case of clean and soot loaded filters.

Combustion engines in hybrid vehicles turn on and off several times during a typical passenger car trip. Each engine restart may pose a risk of excessive tailpipe emissions in real-drive conditions if the after-treatment system fails to maintain an adequate temperature level during zero flow. In view of the tightening worldwide tailpipe emissions standards and real-world conformity requirements, it is important to detect and resolve such risks via cost-effective engineering tools relying on accurate 3d analysis of the thermal and chemical behavior of exhaust systems. In this work, we present a series of experiments to examine the impact of zero-flow duration on the exhaust system cooling and subsequent emissions risk. We also present a catalyst model calibrated to predict the 3d thermal and chemical behavior under normal and zero flow conditions. Particular emphasis is given to the phenomena of free convection and thermal radiation dominating the heat transfer at zero flow.

Reducing fuel consumption and emissions from road transport is a key factor for tackling global warming, promoting energy security and sustaining a clean environment. Several technical measures have been proposed in this aspect amongst which the application of low viscosity engine lubricants. Low viscosity lubricants are considered to be an interesting option for reducing fuel consumption (and CO2 emissions) throughout the fleet in a relatively cost effective way. However limited data are available regarding their actual “real-world” performance with respect to CO2 and other pollutant emissions. This study attempts to address the issue and to provide experimental data regarding the benefit of low viscosity lubricants on fuel consumption and CO2 emissions over both the type-approval and more realistic driving cycles.

The paper describes the development of a modelling approach to simulate the effect of the new Worldwide harmonized Light duty Test Procedure (WLTP) on the certified CO2 emissions of light duty vehicles. The European fleet has been divided into a number of segments based on specific vehicle characteristics and technologies. Representative vehicles for each segment were selected. A test protocol has been developed in order to generate the necessary data for the validation of the vehicle simulation models. In order to minimize the sources of uncertainty and the effects of flexibilities, a reference “template model” was developed to be used in the study. Subsequently, vehicle models were developed using AVL Cruise simulation software based on the above mentioned template model. The various components and sub-modules of the models, as well as their input parameters, have been defined with the support of the respective OEMs.

This paper presents experimental and modeling results related to the application of a novel material as a diesel particulate filter substrate. The material, trademarked as INCOFOAM® HighTemp, is a Ni-based superalloy foam. The material can be produced in sheet form with a large range of microstructure parameters. Thanks to the mechanical properties of the sheets, they can be flexibly shaped in various forms. The foam can be washcoated with active catalytic material to promote regeneration. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests with legislated driving cycles. Special emphasis is given to the characterization of the foam as a catalyst substrate.