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Introducing new exhaust-gas aftertreatment concepts at mass production level places exacting demands on the overall development process - from defining process engineering to developing and calibrating appropriate control-unit algorithms. Strategies for operating and controlling exhaust-gas aftertreatment components, such as oxidation and selective catalytic reduction catalysts (DOC and SCR), diesel particulate filters (DPF) and SCR on DPF systems (SCR/DPF), have a major influence on meeting statutory exhaust-emission standards. Therefore it is not only necessary to consider the physical behavior of individual components in the powertrain but also the way in which they interact as the basis for ensuring efficient operation of the overall system.

The modeling of transient phenomena occurring inside an automotive 3-way catalytic converter poses a significant challenge to the emissions control engineer. Since the significant progress that has been observed with steady-state models cannot be directly exploited in this direction, it is necessary to develop a fully transient model and computer code incorporating dynamic behaviour of the three way catalytic converter in a relatively simple and effective way. The Laboratory of Applied Thermodynamics (LAT), Aristotle University Thessaloniki, is cooperating with the Engine Direction of FIAT Research Center, in the development of a computer code fulfilling these objectives, within the framework of an EEC Brite EuRam cost shared project. The CRF and LAT modeling approaches, along with the underlying philosophy and experimental work, are presented in this paper.

Even though the 3-way catalyst chemistry has been studied extensively in the literature, some performance aspects of practical relevance have not been fully explained. It is believed that the Oxygen Storage Capacity function of 3-way catalytic components dominates the behavior during stoichiometry transitions from lean to rich mode and vice versa whereas a number of mathematical models have been proposed to describe the dynamics of pollutant conversion. Previous studies have suggested a strong impact of Sulfur on the pollutant conversion after a lean to rich transition, which has not been adequately explained and modelled. Lean to rich transitions are highly relevant to catalyst ‘purging’ needed after exposure to high O2 levels (e.g. after fuel cut-offs). This work presents engine test measurements with an engine-aged catalyst that highlight the negative impact of Sulfur on pollutant conversion after a lean to rich transition.

Particulate filters are a widely used emission control device on heavy-duty diesel engines. The accumulation of particulate matter, mostly consisting of soot, inside the filter results in increased filter pressure-drop (backpressure). This increased backpressure has been used by the on-board control systems as trigger for regeneration procedures, which aim to actively oxidize the accumulated soot. However, it is known that passive soot oxidation during normal operation affects the correlation between backpressure and the deposited soot mass in filter. Therefore, the backpressure alone cannot be a reliable trigger for regeneration. In this work we highlight operating conditions with very poor correlation between backpressure and accumulated soot mass in filter and evaluate the possible root causes. Experiments with several heavy-duty diesel engines and particulate filters were conducted on engine test bench.

A physico-chemical model of a Cu-zeolite SCR/DPF-system involving NH₃ storage and SCR reactions as well as soot oxidation reactions with NO₂ has been developed and validated based on fundamental experimental investigations on synthetic gas test bench. The goal of the work was the quantitative modeling of NOx and NH₃ tailpipe emissions in transient test cycles in order to use the model for concept design analysis and the development of control strategies. Another focus was put on the impact of soot on SCR/DPF systems. In temperature-programmed desorption experiments, soot-loaded SCR/DPF filters showed a higher NH₃ storage capacity compared to soot-free samples. The measured effect was small, but could affect the NH₃ slip in vehicle applications. A bimodal desorption characteristic was measured for different adsorption temperatures and heating rates.

As the Diesel Particulate Filter (DPF) technology is nowadays established, research is currently focusing on meeting the emission and durability requirements by proper system design. This paper focuses on the optimum combination between the catalytic coating and substrate structural properties using experimental and simulation methodologies. The application of these methodologies will be illustrated for the case of SiC substrates coated with innovative sol-gel coatings. Coated samples are characterized versus their uncoated counterparts. Multi-dimensional DOC and DPF simulation models are used to study several effects parametrically and increase our understanding on the governing phenomena. The comparative analysis of DOC/DPF systems covers filtration – pressure drop characteristics, CO/HC/NO oxidation performance, effect of washcoat amount and catalyst dispersion on oxidation activity and finally passive regeneration performance.

The pressure for compact and efficient deNO systems has led to increased interest of incorporating SCR coatings in the DPF walls. This technology could be very attractive especially if high amounts of washcoat loadings could be impregnated in the DPF porous walls, which is only possible with high porosity filters. To counterbalance the filtration and backpressure drawbacks from such high porosity applications, the layered wall technology has already been proposed towards minimizing soot penetration in the wall and maximizing filtration efficiency. In order to deal with the understanding of the complex interactions in such advanced systems and assist their design optimization, this paper presents an advanced modeling framework and selected results from simulation studies trying to illustrate the governing phenomena affecting deNO performance and passive DPF regeneration in the above combined systems.

The low-NOx standard for heavy-duty trucks proposed by the California Air Resources Board will require rapid warm-up of the aftertreatment system (ATS). Several different aftertreatment architectures and technologies, all based on selective catalytic reduction (SCR), are being considered to meet this need. One of these architectures, the close-coupled SCR (ccSCR), was evaluated in this study using two different physics-based, 1D models; the simulations focused on the first 300 seconds of the cold-start Federal Test Procedure (FTP). The first model, describing a real, EuroVI-compliant engine equipped with series turbochargers, was used to evaluate a ccSCR located either i) immediately downstream of the low-pressure turbine, ii) in between the two turbines, or iii) in a by-pass around the high pressure turbine.

The design of integrated exhaust lines that combine particulate and NOx emission control is a multidimensional optimization problem. The present paper demonstrates the use of an exhaust system simulation platform which is composed of well-established multidimensional mathematical models for the transient thermal and chemical phenomena in DOC, DPF and SCR systems as well as connecting pipe heat transfer effects. The analysis is focused on the European Driving Cycle conditions. Illustrative examples on complete driving cycle simulations with and without forced regeneration events are presented for alternative design approaches. The results illustrate the importance of DOC and DPF heat capacity effects and connecting pipe heat losses on the SCR performance. The possibility of combining DPF and SCR functionality on a single wall-flow substrate is studied.

Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.

The objective of this study is to study the soot layer density and permeability in wall-flow diesel particulate filters. Knowledge of the soot morphology as function of the operating conditions is important for the design and on-board control of Diesel Particulate Filters (DPFs). The experimental set-up relies on a specially designed soot loading procedure on single-channel cordierite filters. The experimental conditions simulate real-world as close as possible regarding the filtration velocity, temperature and soot quality, since the sampling is done in real exhaust. By cutting, weighing and imaging the single channel filters it is possible to measure with accuracy the soot layer thickness as deposited under different operating conditions. Combined with pressure drop measurements and modeling, it is further possible to evaluate the soot layer permeability.

Conventional methods of physicochemical models require various experts and a high measurement demand to achieve the required model accuracy. With an additional request for faster development time for diagnostic algorithms, this method has reached the limits of economic feasibility. Machine learning algorithms are getting more popular in order to achieve a high model accuracy with an appropriate economical effort and allow to describe complex problems using statistical methods. An important point is the independence from other modelled variables and the exclusive use of sensor data and actuator settings. The concept has already been successfully proven in the field of modelling for exhaust gas aftertreatment sensors. An engine-out nitrogen oxide (NOX) emission sensor model based on polynomial regression was developed, trained, and transferred onto a conventional automotive electronic control unit (ECU) and also proves real-time capability.

For the NOx removal from diesel exhaust, the selective catalytic reduction (SCR) and lean NOx traps are established technologies. However, these procedures lack efficiency below 200 °C, which is of importance for city driving and cold start phases. Thus, the present paper deals with the development of a novel low-temperature deNOx strategy implying the catalytic NOx reduction by hydrogen. For the investigations, a highly active H2-deNOx catalyst, originally engineered for lean H2 combustion engines, was employed. This Pt-based catalyst reached peak NOx conversion of 95 % in synthetic diesel exhaust with N2 selectivities up to 80 %. Additionally, driving cycle tests on a diesel engine test bench were also performed to evaluate the H2-deNOx performance under practical conditions. For this purpose, a diesel oxidation catalyst, a diesel particulate filter and a H2 injection nozzle with mixing unit were placed upstream to the full size H2-deNOx catalyst.

Advanced SI engines for passenger cars often use the cylinder deactivation technology for dethrottling and thus achieving a reduction of fuel consumption. The gas exchange valves of the deactivated cylinders are closed permanently by a zero lift of the cams. The solutions for cylinder deactivation can vary in the kind of gas composition included in the deactivated cylinders: charge air, exhaust gas or vacuum. All these strategies have in common the frequent loss of captured charge mass from cycle to cycle. Their two-stroke compression-expansion cycle additionally intensifies this phenomenon. Thus, a significant decrease of the minimum cylinder pressure can cause an undesired entry of lubricant into the combustion chamber. The idea was to ventilate the generally deactivated cylinders frequently to compensate the loss of captured cylinder charge mass. The task was to keep the minimum cylinder pressure above a certain limit to prevent the piston rings from a failure.

The transient heat transfer behavior of an automotive catalytic converter has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO oxidation, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters are the results of data in literature tuned by experiments. Simplified cases of constant flow rates and gas temperatures in the catalyst inflow have been chosen for a comprehensive analysis of the heat and mass transfer phenomena. The impact of inlet flow temperatures and inlet flow rates on the heat up characteristics as well as in the CO emissions have been quantified. A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinates are introduced.

The objective of this study is to present a particulate filter concept, based on a new porous material: INCOFOAM® HighTemp, a Ni-based superalloy foam. The paper examines the filtration and pressure drop characteristics as well as the regeneration performance of different filter configurations, based on experimental data and modeling. A number of different foam structures with variable pore characteristics are studied. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests on the chassis dynamometer and on-road. In parallel, a previously developed mathematical model is applied to study and understand the filtration and pressure drop mechanisms in the case of clean and soot loaded filters.

Combustion engines in hybrid vehicles turn on and off several times during a typical passenger car trip. Each engine restart may pose a risk of excessive tailpipe emissions in real-drive conditions if the after-treatment system fails to maintain an adequate temperature level during zero flow. In view of the tightening worldwide tailpipe emissions standards and real-world conformity requirements, it is important to detect and resolve such risks via cost-effective engineering tools relying on accurate 3d analysis of the thermal and chemical behavior of exhaust systems. In this work, we present a series of experiments to examine the impact of zero-flow duration on the exhaust system cooling and subsequent emissions risk. We also present a catalyst model calibrated to predict the 3d thermal and chemical behavior under normal and zero flow conditions. Particular emphasis is given to the phenomena of free convection and thermal radiation dominating the heat transfer at zero flow.

The paper describes the development of a modelling approach to simulate the effect of the new Worldwide harmonized Light duty Test Procedure (WLTP) on the certified CO2 emissions of light duty vehicles. The European fleet has been divided into a number of segments based on specific vehicle characteristics and technologies. Representative vehicles for each segment were selected. A test protocol has been developed in order to generate the necessary data for the validation of the vehicle simulation models. In order to minimize the sources of uncertainty and the effects of flexibilities, a reference “template model” was developed to be used in the study. Subsequently, vehicle models were developed using AVL Cruise simulation software based on the above mentioned template model. The various components and sub-modules of the models, as well as their input parameters, have been defined with the support of the respective OEMs.

This paper presents experimental and modeling results related to the application of a novel material as a diesel particulate filter substrate. The material, trademarked as INCOFOAM® HighTemp, is a Ni-based superalloy foam. The material can be produced in sheet form with a large range of microstructure parameters. Thanks to the mechanical properties of the sheets, they can be flexibly shaped in various forms. The foam can be washcoated with active catalytic material to promote regeneration. The experimental testing covers flow and pressure drop behavior with air and exhaust gas, filtration efficiency measurements as function of particle size and regeneration rate measurements. The testing starts from mini-scale reactors and proceeds to real exhaust testing on the engine bench as well as vehicle tests with legislated driving cycles. Special emphasis is given to the characterization of the foam as a catalyst substrate.

One of the main challenges in developing cost-effective diesel particulate filters is to guarantee a thermally safe regeneration under all possible conditions on the road. Uncontrolled regenerations occur when the soot reaction rate is so high that the cooling effect of the incoming exhaust gas is insufficient to keep the temperature below the required limit for material integrity. These conditions occur when the engine switches to idle while the filter is already hot enough to initiate soot oxidation, typically following engine operation at high torque and speed or active filter regeneration. The purpose of this work is to investigate engine management techniques to reduce the reaction rate during typical failure mode regenerations. A purely experimental investigation faces many difficulties, especially regarding measurement accuracy, repeatability in filter soot loading, and repeatability in the regeneration protocol.