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A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

The potential peaking of world conventional oil production and the possible imperative to reduce carbon emissions will put great pressure on vehicle manufacturers to produce more efficient vehicles, on vehicle buyers to seek them out in the marketplace, and on energy suppliers to develop new fuels and delivery systems. Four cases for stabilizing or reducing light vehicle fuel use, oil use, and/or carbon emissions over the next 50 years are presented. Case 1 - Improve mpg so that the fuel use in 2020 is stabilized for the next 30 years. Case 2 - Improve mpg so that by 2030 the fuel use is reduced to the 2000 level and is reduced further in subsequent years. Case 3 - Case 1 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. Case 4 - Case 2 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. The mpg targets for new cars and light trucks require that significant advances be made in developing cost-effective and very efficient vehicle technologies.

The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

As connected and automated vehicle technologies emerge and proliferate, lower frequency vehicle trajectory data is becoming more widely available. In some cases, entire fleets are streaming position, speed, and telemetry at sample rates of less than 10 seconds. This presents opportunities to apply powertrain simulators such as the National Renewable Energy Laboratory’s Future Automotive Systems Technology Simulator to model how advanced powertrain technologies would perform in the real world. However, connected vehicle data tends to be available at lower temporal frequencies than the 1-10 Hz trajectories that have typically been used for powertrain simulation. Higher frequency data, typically used for simulation, is costly to collect and store and therefore is often limited in density and geography. This paper explores the suitability of lower frequency, high availability, connected vehicle data for detailed powertrain simulation.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

The key hurdles to achieving wide consumer acceptance of battery electric vehicles (BEVs) are weather-dependent drive range, higher cost, and limited battery life. These translate into a strong need to reduce a significant energy drain and resulting drive range loss due to auxiliary electrical loads the predominant of which is the cabin thermal management load. Studies have shown that thermal sub-system loads can reduce the drive range by as much as 45% under ambient temperatures below −10 °C. Often, cabin heating relies purely on positive temperature coefficient (PTC) resistive heating, contributing to a significant range loss. Reducing this range loss may improve consumer acceptance of BEVs. The authors present a unified thermal management system (UTEMPRA) that satisfies diverse thermal and design needs of the auxiliary loads in BEVs.

Due to its high efficiency and superior durability the diesel engine is again becoming a prime candidate for future light-duty vehicle applications within the United States. While in Europe the overall diesel share exceeds 40%, the current diesel share in the U.S. is 1%. Despite the current situation and the very stringent Tier 2 emission standards, efforts are being made to introduce the diesel engine back into the U.S. market. In order to succeed, these vehicles have to comply with emissions standards over a 120,000 miles distance while maintaining their excellent fuel economy. The availability of technologies such as high-pressure common-rail fuel systems, low sulfur diesel fuel, NOx adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with the light-duty Tier 2 emission requirements. In support of this, the U.S.

In order to meet common fuel specifications such as cetane number and volatility, a refinery must blend a number of refinery stocks derived from various process units in the refinery. Fuel chemistry can be significantly altered in meeting fuel specifications. Additionally, fuel specifications are seldom changed in isolation, and the drive to meet one specification may alter other specifications. Homogeneous charge compression ignition (HCCI) engines depend on the kinetic behavior of a fuel to achieve reliable ignition and are expected to be more dependent on fuel specifications and chemistry than today's conventional engines. Regression analysis can help in determining the underlying relationships between fuel specifications, chemistry, and engine performance. Principal Component Analysis (PCA) is used as an adjunct to regression analysis in this work, because of its ability to deal with co-linear variables and potential to uncover ‘hidden’ relationships between the variables.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

A 1.3-L direct injection diesel engine was used in steady-state testing to determine the emissions performance of a matrix of ultra-low sulfur diesel fuels encompassing two types of sulfur removal and the use of fuel oxygenates. As expected, exhaust gas recirculation was the most effective technique for NOx reduction. With regard to fuel effects, an oxygenated diesel fuel produced with a conventional sulfur removal process reduced particulate emissions substantially, and these particulate reductions could be converted into NOx reductions by using higher levels of exhaust gas recirculation. On a simulated FTP, this oxygenated fuel simultaneously decreased NOx emissions by 30% and total particulate emissions by 50% compared to a baseline fuel.

In this paper, researchers at the National Renewable Energy Laboratory present the results of simulation studies to evaluate potential fuel savings as a result of improvements to vehicle rolling resistance, coefficient of drag, and vehicle weight as well as hybridization for four powertrains for medium-duty parcel delivery vehicles. The vehicles will be modeled and simulated over 1,290 real-world driving trips to determine the fuel savings potential based on improvements to each technology and to identify best use cases for each platform. The results of impacts of new technologies on fuel saving will be presented, and the most favorable driving routes on which to adopt them will be explored.

As part of a cooperative development program, six diesel fuels (a reference and five blends containing oxygenates) were evaluated under four steady-state conditions using a prototype 1.26-L 3-cylinder four-valve common-rail DI diesel engine. All of the fuels contained low sulfur (mostly < 5 ppm by mass), and they were chosen to determine the impacts of oxygenate volatility, concentration, and chemical type (paraffinic or aromatic) on exhaust emissions - with particular emphasis on particulate emissions. In addition to HC, CO, NOx and PM emissions measurements, emissions of the volatile portion of the PM and particle size were determined. Relative to the very low sulfur reference fuel, the oxygenated fuels reduced PM and NOx under some operating conditions, but produced little effect on either HC or CO emissions. Aliphatic oxygenates at 6 wt. percent oxygen in the reference fuel reduced simulated FTP PM emissions by 15 - 27 %.

Following concern about the association between adverse health effects and ambient particulate concentrations, there are now an increasing number of heavy-duty Diesel engines fitted with catalysed particulate filters. These filters virtually eliminate carbon particle emissions but there is some evidence suggesting a potential to form a cloud of secondary nucleation particles post trap. This event occurs at high temperature operating conditions and is produced mainly from the increased sulphate production over the catalyst. This paper investigates the measurement of particle emissions from a heavy-duty engine operating over the European legislated cycle, both with and without a filter fitted and investigates how emissions are affected by the use of a sulphur-free Diesel fuel. The work also demonstrates a contribution to the measured nucleation particles from material desorbed not only from the trap, but also from the exhaust system.

A key to the success of the national hydrogen and fuel cell codes and standards developments efforts to date was the creation and implementation of national templates through which the U.S. Department of Energy (DOE), the National Renewable Energy Laboratory (NREL), and the major standards development organizations (SDOs) and model code organizations coordinate the preparation of critical standards and codes for hydrogen and fuel cell technologies and applications and maintain a coordinated national agenda for hydrogen and fuel cell codes and standards

This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

The quality of neat biodiesel (B100) is critical for ensuring biodiesel blends used in diesel-powered vehicles do not adversely impact engine performance. In the United States, B100 is required to meet ASTM International’s purity and fuel property requirements in D6751, “Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels.” Here we review the development of this standard for the different grades of B100. The BQ-9000 program, which currently covers over 90% of U.S. and Canadian production volumes, is also described. Engine and original equipment manufacturers have expressed a desire for credible, third-party data on values of various ASTM B100 properties in the commercial market to inform their efforts to address future emissions and durability requirements.

Oxidative degradation of biodiesel under accelerated conditions has been examined by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), and gravimetric measurement of deposit formation. The formation of gums and deposits caused by oxidation in storage or in an engine fuel system is a significant issue because of the potential for fuel pump and injector fouling. The results of this study indicate several important pathways for degradation and two pathways leading to formation of oligomers and, ultimately, deposits. Peroxides formed in the initial stage of oxidation can decompose to form aldehydes, ketones, and acids. These can react further in aldol condensation to form oligomers. Additionally, peroxides can react with fatty acid chains to form dimers and higher oligomers. Deposits form when the polarity and molecular weight of these oligomers is high enough.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).