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Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

Small bore diesel engines often adopt a two-valve cylinder head and a non-central injector layout to expand the port flow passage area. This non-central injector layout causes asymmetrical gas flow and fuel distribution, resulting in worse heat losses and a less homogenous fuel-air mixture than an equivalent four-valve cylinder head layout with a central injector. This paper describes the improvement of piston bowl geometry to achieve a more homogeneous gas flow and fuel-air mixture. This concept reduced fuel consumption by 2.5% compared to the original piston bowl geometry, while also reducing NOx emissions by 10%.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.

Two types of new conceptual lead free overlays are developed for automotive internal combustion(IC) engine bearings. The overlays are consisted of molybdenum disulfide(MoS2) and polyamideimide(PAI) resin for binding. One of the overlays is suitable for diesel engines with higher unit load and the other overlay is suitable for gasoline engines with higher sliding velocity. Both overlays indicate good corrosion resistance and wear resistance comparing with conventional lead base overlay. Moreover, higher fatigue resistance is obtained in combination with high performance lead free bearing alloy. These new bearings have the potential to become alternative materials to conventional copper lead bearings with lead base overlay.

HEV and PHEV require an improved aftertreatment system to clean the exhaust gas in various driving situations. The efficiency of aftertreatment system is significantly influenced by the residence time of the gas in a catalyst which gas flow has generally strong pulsation. Simulation showed up to 70% reduction of exhaust gas emission if the pulsation could be completely attenuated. A new concept exhaust manifold was designed to minimize pulsation flow by wall impingement, with slight increase of pressure loss. Experimental results with new concept exhaust manifold showed exhaust gas emission were reduced 16% at cold condition and 40% at high-load condition.

Small bore diesel engines often adopt a two-valve cylinder head and a non-central injector layout to expand the port flow passage area. This non-central injector layout causes asymmetrical gas flow and fuel distribution, resulting in worse heat losseses and a less homogenous fuel-air mixture than an equivalent four-valve cylinder head layout with a central injector. To improve these problems Toyota applied a new concept which was characterized by tapered shape design on the upper portion of the piston and low compression ratio to achieve more homogeneous gas flow and fuel-air mixture. This paper describes the impact of new combustion concept and the mechanism of the improvement by 3D-CFD analysis and optical measurement.

Toyota Motor Corporation has been developing technologies for reductions on the environmental load. This paper reports the following as a part of technological development for the painting process. Prior to the application of the E-coat, vehicle bodies are pretreated with zinc phosphates. This is applied to ensure good adhesion and corrosion resistance of the E-coat film. To obtain an excellent pretreatment film, surface conditioning with titanium colloid is generally applied before pretreatment. Since colloid flocculation control was difficult in the case of a conventional titanium colloid-type surface conditioner, the surface conditioner had to be renewed at approximately two-month intervals. The liquid life, however, increased remarkably as a result of adopting fine zinc-type surface conditioners and adding an organic protective surface layer. The water supply/discharge amount was decreased significantly compared with previous amounts.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

As a result of recent improvements in engine efficiency, vehicle heating performance has decreased and the demand for auxiliary heat sources is increasing. To help meet this need, we have developed an auxiliary heat system known as the “Hot Gas Heater”. The Hot Gas Heater uses components common to the vehicle air-conditioning system that are not used during winter. However, there are some concerns with this system. In this paper we describe our solutions to these problems. We reduced gas flow noise through multi-stage pressure reduction, and prevented fogging by adding “water retention memory” and “evaporator outlet air temperature control” functions to the system. As a further benefit, we developed a New Accumulator Cycle that moves the cooling cycle accumulator tank to the high-pressure side.

A highly efficient new 2.8-liter inline 4-cylinder diesel engine has been developed in response to growing demand for diesel engines and to help save energy while providing high-torque performance. Engine efficiency was improved by reducing cooling loss based on an innovative combustion concept applied across the whole engine. Cooling loss was reduced by restricting in-cylinder gas flows and improving combustion chamber insulation. To prevent the restricted gas flows from affecting emissions, a new combustion chamber shape was developed that increased air utilization in the cylinder through optimizing the in-cylinder fuel distribution. Combustion chamber insulation was improved by a new insulation coat that changes the wall surface temperature in accordance with the gas temperature. This reduces cooling loss and avoids the trade-off effect of intake air heating.

A new HC adsorber system was developed to achieve California SULEV emission standards for a V8 5.0-liter engine application (i.e. LS600hL). A HC adsorber system was first released on 2001 PZEV Prius (1.5-liter engine) in U.S.A. For the 5.0L application the substrate volume of both catalyst and adsorber had to be enlarged for a large volume displacement. Prius-type adsorber system could not be adopted for LS600hL because of the problems of installation. So, a new constructional adsorber was proposed. However the increase of gas flow into the adsorber substrate was a problem for desorption. The gas flow into the adsorber substrate was found to be controllable by the specification adjustment of the “throat” and “retainer” parts of adsorber system. Thus the rapid desorption was successfully reduced, and the HC adsorber system achieved a 50% reduction of HC emission.

Temperature stratification plays an important role in HCCI combustion. The onsets of auto-ignition and combustion duration are sensitive to the temperature field in the engine cylinder. Numerical simulations of HCCI engine combustion are affected by the use of wall boundary conditions, especially the temperature condition at the cylinder and piston walls. This paper reports on numerical studies and experiments of the temperature field in an optical experimental engine in motored run conditions aiming at improved understanding of the evolution of temperature stratification in the cylinder. The simulations were based on Large-Eddy-Simulation approach which resolves the unsteady energetic large eddy and large scale swirl and tumble structures. Two dimensional temperature experiments were carried out using laser induced phosphorescence with thermographic phosphors seeded to the gas in the cylinder.