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This work evaluates the effect of charge stratification on combustion phasing, rate of heat release and emissions for HCCI combustion. Engine experiments in both optical and traditional single cylinder engines were carried out with PRF50 as fuel. The amount of stratification as well as injection timing of the stratified charge was varied. It was found that a stratified charge can influence combustion phasing, increasing the stratification amount or late injection timing of the stratified charge leads to an advanced CA50 timing. The NOx emissions follows the CA50 advancement, advanced CA50 timing leads to higher NOx emissions. Correlation between CA50 can also be seen for HC and CO emissions when the injection timing was varied, late injection and thereby advanced CA50 timing leads to both lower HC and CO emissions.