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Sulphur poisoning and regeneration of NOx trap catalysts have been studied in synthetic exhausts and in an engine bench. Sulphur gradually poisoned the NOx storage sites in the axial direction of the NOx trap. During sulphur regenerations, hydrogen was found to be more efficient than carbon monoxide in removing the sulphur from the trap. The sulphur regeneration became more efficient the richer the environment (λ<1) and the higher the temperature (at least 600°C). H2S was found to be the main product during the sulphur regeneration. However, it was possible to reduce the H2S formation and instead produce more SO2 by running with lambda close to one or by pulsing lambda. Even if a relatively large amount of sulphur was removed from the NOx trap, these methods gave a much less efficient regeneration per sulphur atom removed than when running relatively rich constantly. Finally, a model that could explain this observation was proposed.

This paper reports the numerical studies of self-ignition and early combustion process of n-heptane sprays under various diluted air conditions. The numerical simulations employ a detailed chemistry approach, coupled directly with the computational fluid dynamics (CFD). A “subgrid” Partially Stirred Reactor (PaSR) model has been developed to account for the turbulence-chemistry-interaction. This model has been implemented into the KIVA3V CFD code. A detailed chemical mechanism of reduced size (65 species and 273 elementary reactions) for the n-heptane fuel has been derived and applied to the simulations of spray combustion. The studies focus on sprays injected into a high-pressure constant-volume chamber. Firstly, the validation of the current numerical model has been carried out for the case in which the injection and initial conditions are similar to those used in the “classical” Aachen experiments (50bar and 800K).

The expansion of current driving cycles for emission regulations to higher load operation in the near future (such as the US06 supplement to the FTP-75 driving cycle) requires attention to low emission combustion concepts in medium to high load regimes. One possibility to reduce NO emissions is to increase the EGR rate. The combustion-temperature reducing effects of high EGR rates can significantly reduce NO formation, to the point where engine-out NOx emissions approach zero levels. However, engine-out soot and CO emissions typically increase at high EGR levels, due to the reduced soot and CO oxidation rates at reduced combustion temperatures and oxygen concentrations. The work presented in this paper focuses on different strategies to reduce soot and CO emissions associated with EGR rates of up to 50%, at which NO formation is largely avoided, but combustion temperatures are not low enough to consider the process as Low-Temperature Combustion (LTC).

Future demands for improvements in the fuel economy of gasoline passenger car engines will require the development and implementation of advanced combustion strategies, to replace, or combine with the conventional spark ignition strategy. One possible strategy is homogeneous charge compression ignition (HCCI) achieved using negative valve overlap (NVO). However, several issues need to be addressed before this combustion strategy can be fully implemented in a production vehicle, one being to increase the upper load limit. One constraint at high loads is the combustion becoming too rapid, leading to excessive pressure-rise rates and large pressure fluctuations (ringing), causing noise. In this work, efforts were made to reduce these pressure fluctuations by using a late injection during the later part of the compression. A more appropriate acronym than HCCI for such combustion is SCCI (Stratified Charge Compression Ignition).

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

This work evaluates the effect of charge stratification on combustion phasing, rate of heat release and emissions for HCCI combustion. Engine experiments in both optical and traditional single cylinder engines were carried out with PRF50 as fuel. The amount of stratification as well as injection timing of the stratified charge was varied. It was found that a stratified charge can influence combustion phasing, increasing the stratification amount or late injection timing of the stratified charge leads to an advanced CA50 timing. The NOx emissions follows the CA50 advancement, advanced CA50 timing leads to higher NOx emissions. Correlation between CA50 can also be seen for HC and CO emissions when the injection timing was varied, late injection and thereby advanced CA50 timing leads to both lower HC and CO emissions.

In order to investigate the effects of split injection on emission formation and engine performance, experiments were carried out using a heavy duty single cylinder diesel engine. Split injections with varied dwell time and start of injection were investigated and compared with single injection cases. In order to isolate the effect of the selected parameters, other variables were kept constant. In this investigation no EGR was used. The engine was equipped with a common rail injection system with a piezo-electric injector. To interpret the observed phenomena, engine CFD simulations using the KIVA-3V code were also made. The results show that reductions in NOx emissions and brake specific fuel consumption were achieved for short dwell times whereas they both were increased when the dwell time was prolonged. No EGR was used so the soot levels were already very low in the cases of single injections.

When increasing EGR from low levels to a level that corresponds to low temperature combustion, soot emissions initially increase due to lower soot oxidation before decreasing to almost zero due to very low soot formation. At the EGR level where soot emissions start to increase, the NOx emissions are low, but not sufficiently low to comply with future emission standards and at the EGR level where low temperature combustion occurs CO and HC emissions are too high. The purpose of this study was to investigate the possibilities for shifting the so-called soot bump (where soot levels are increased) to higher EGR levels, or to reduce the magnitude of the soot bump using very high injection pressures (up to 240 MPa) while reducing the NOx emissions using EGR. The possibility of reducing the CO and HC emissions at high EGR levels due to the increased mixing caused by higher injection pressure was also investigated and the flame was visualized using an endoscope at chosen EGR values.

The emissions from a parallel hybrid combustion engine and electric powertrain operated on a modified New European Drive Cycle (NEDC) was investigated in order to determine the relation between emissions and the road and engine load profile. The effect of simulated electric motor assistance during accelerations on emissions was investigated as a means to reduce particulate and gaseous emissions. The time resolved particulate number and size distribution was measured in addition to gaseous emissions. The combustion engine was a downsized, three cylinder spark ignited direct injection (SIDI) turbocharged engine fuelled with gasoline. Electric motor assistance during accelerations was simulated by reduction of the vehicle mass. This reduced engine load during accelerations. Fuel rich engine transients occurred during accelerations. NOx emissions were reduced with electric assistance due to a reduction in engine load.

Future emission legislation will require substantial reductions of NOx and particulate matter (PM) emissions from diesel engines. The combustion and emission formation in a diesel engine is governed mainly by spray formation and mixing. Important parameters governing these are droplet size, distribution, concentration and injection velocity. Smaller orifices are believed to give smaller droplet size, even with reduced injection pressure, which leads to better fuel atomization, faster evaporation and better mixing. In this paper experiments are performed on a single cylinder heavy-duty direct injection diesel engine with three nozzles of different orifice diameters (Ø0.227 mm, Ø0.130 mm, Ø0.090 mm). Two loads (low and medium) and three speeds were investigated. The test results confirmed a substantial reduction in HC and soot emissions at lower loads for the small orifices.

Reducing emissions and improving efficiency are major goals of modern internal combustion engine research. The use of biomass-derived fuels in Diesel engines is an effective way of reducing well-to-wheels (WTW) greenhouse gas (GHG) emissions. Moreover, partially premixed combustion (PPC) makes it possible to achieve very efficient combustion with low emissions of soot and NOx. The objective of this study was to investigate the effect of using alcohol/Diesel blends or neat alcohols on emissions and thermal efficiency during PPC. Four alcohols were evaluated: n-butanol, isobutanol, n-octanol, and 2-ethylhexanol. The alcohols were blended with fossil Diesel fuel to produce mixtures with low cetane numbers (26-36) suitable for PPC. The blends were then tested in a single cylinder light duty (LD) engine. To optimize combustion, the exhaust gas recirculation (EGR) level, lambda, and injection strategy were tuned.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.