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This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2012. First, the paper covers the key regulatory developments in the field, including finalized criteria pollutant tightening in California; and in Europe, the development of real-world driving emissions (RDE) standards. The US finalized LD (light-duty) greenhouse gas (GHG) regulation for 2017-25. The paper then gives a brief, high-level overview of key developments in LD and HD engine technology, covering both gasoline and diesel. Marked improvements in engine efficiency are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are just starting to demonstrate 50% brake thermal efficiency. NOx control technologies are then summarized, including SCR (selective catalytic reduction) with ammonia, and hydrocarbon-based approaches.

Sub-23nm particles emission from the light-duty vehicle is widely discussed now and possible to be counted into the next stage emission legislation, such as Euro7. In this article, 16 China6 gasoline vehicles were tested over the WLTC and two surrogate RDE lab cycles for particulate number (PN) emission, the difference between PN23 (particle size >23nm) and PN10 (particle size>10nm) emission was analyzed. Testing results showed that the average PN10 emission increased 59% compared to PN23, which will bring great challenges for those vehicles to meet the future regulation requirement if sub-23nm particle is counted. The sub-23nm particles emission was proportional to the PN23 particles emission and generated mostly from the cold start or the transient engine conditions with rich combustion. Compared to the proposal of Euro 7, PN10 emission from some tested vehicles will need further two orders of magnitude reduction.

Diesel particulate filters are expected to be used on most passenger car applications designed to meet coming European emission standards, EU5 and EU6. Similar expectations hold for systems designed to meet US Tier 2 Bin 5 standards. Among the various products oxide filter materials, such as cordierite and aluminum titanate, are gaining growing interest due to their unique properties. Besides the intrinsic robustness of the filter products a well designed operating strategy is required for the successful use of filters. The operating strategy is comprised of two elements: the soot estimation and the regeneration strategy. In this paper the second element is discussed in detail by means of theoretical considerations as well as dedicated engine bench experiments. The impact the key operating variables, soot load, exhaust mass flow, oxygen content and temperature, have on the conditions inside the filter are discussed.

Over the past decade, regulations for mobile source emissions have become more stringent thus, requiring advances in emissions systems to comply with the new standards. For the popular diesel powered passenger cars particularly in Europe, diesel particulate filters (DPFs) have been integrated to control particulate matter (PM) emissions. Corning Incorporated has developed a new proprietary aluminum titanate-based material for filter use in passenger car diesel applications. Aluminum titanate (hereafter referred to as AT) filters were launched commercially in the fall of 2005 and have been equipped on more than several hundred thousand European passenger vehicles. Due to their outstanding durability, filtration efficiency and pressure drop attributes, AT filters are an excellent fit for demanding applications in passenger cars. Extensive testing was conducted on engine to evaluate the survivability and long-term thermo-mechanical durability of AT filters.

A concern has been expressed regarding the durability of the ceramic thin wall and ultra-thin wall substrates under severe thermal and mechanical conditions. Damage that might result from these conditions would most likely lead to a reduction in catalyst performance. One of the potential damage mechanisms for automotive catalysts is erosion resulting from the impingement of particles onto the front face of the catalyst system. A basic study of the particulate erosion phenomenon of cellular ceramic substrates was undertaken in order to determine, in a controlled setting, the substrate, particulate, and flow conditions that might bring this damage about. This report will discuss a room temperature study of the effects of particle size, particle density, gas flow rate, cellular part orientation, and cellular design parameters on the erosion of ceramic substrates.

With the introduction of a stringent particulate number (PN) limit and real driving emission (RDE) requirements, gasoline particulate filters (GPF) are widely adopted for gasoline engines in Europe and China. The filter collects soot and ash. Like in diesel applications, the collected soot will continuously burn under favorable exhaust conditions. However, at extreme conditions, there could be large amounts of soot build-up, which may induce a highly exothermal event, potentially damaging the filter. Thus, it is important to understand what drives the over-heating in application, and develop counter measures. In this study, an on-vehicle fuel cut (FC) testing procedure was developed. The testing was conducted on two vehicles, one gasoline direct injection (GDI) vehicle and one multiple port injection (MPI) vehicle, with different exhaust systems designs (a close coupled GPF and an under floor GPF) and catalyst coating levels (bare and heavily coated GPFs).

Diesel particulate filters (DPF) have become a standard aftertreatment component for a majority of current on-road/non-road diesel engines used in the US and Europe. The upcoming Stage V emissions regulations in Europe will make DPFs a standard component for emissions reductions for non-road engines. The tightening in NOx emissions standard has resulted in the use of selective catalytic reduction (SCR) technology for NOx reduction and as a result the general trend in engine technology as of today is towards a higher engine-out NOx/PM ratio enabling passive regeneration of the DPF. The novel filter concept discussed in this paper is optimized for low pressure drop, high filtration efficiency, and low thermal mass for optimized regeneration and fast heat-up, therefore reducing CO2 implications for the DPF operation.

As demand for wall-flow Diesel particulate filters (DPF) increases, accurate predictions of DPF behavior, and in particular of the accumulated soot mass, under a wide range of operating conditions become important. This effort is currently hampered by a lack of a systematic knowledge of the accumulated particulate deposit microstructural properties. In this work, an experimental and theoretical study of the growth process of soot cakes in honeycomb ceramic filters is presented. Particular features of the present work are the application of first- principles measurement and simulation methodology for accurate determination of soot cake packing density and permeability, and their systematic dependence on the filter operating conditions represented by the Peclet number for mass transfer. The proposed measurement methodology has been also validated using various filters on different Diesel engines.

Engine laboratory tests were conducted to assess the impact of B20 biodiesel on the performance of cordierite diesel particulate filters (DPFs). Test fuels included 20% soy based methyl ester blended into ultra low sulfur diesel fuel, and two ULSD on-road market fuels. B20 has a higher cetane number, boiling point and oxygen content than typical on-road diesel fuels. A comparative study was performed using a model year 2007 medium duty diesel truck engine. The aftertreatment system included a diesel oxidation catalyst (DOC) followed by a cordierite wall flow DPF. A laboratory-grade supplemental fuel doser was used in the exhaust stream for precise regeneration of the DPF. Tests revealed that the fuel dosing rate was higher and DOC fuel conversion efficiency was poorer for the B20 fuel during low exhaust temperature regenerations. The slip of B20 fuel past the DOC was shown to produce significantly higher exotherms in the DPF during regeneration.

India is the world’s largest two-wheeler (2Wh) market. With the proportion of its middle class rapidly rising, 2Wh sales and the resulting emissions, are expected to grow exponentially. The decision to leap-frog from BSIV to BSVI emission norms shows India’s commitment to clean up its atmosphere. As of now, the regulation mandates Gaseous Pollutant (CO, HC, NOx) emission limits for all 2Whs and a particulate limit (PM & PN) for 2Whs powered by Direct Injection (DI) engines. Most of the 2Whs manufactured in India are powered by gasoline engines using the Port Fuel Injection (PFI) technology, and hence by definition particulate emission limits do not apply to them. Particulates when inhaled - especially of the ultrafine sizes capable of entering the blood stream - pose a serious health risk. This was the primary motivation to investigate the particulate emission levels of the 2Whs, which as on date, do not come under the purview of BSVI regulation.

High emission performance standards and precious metals costs have pushed the catalytic substrate toward high cell density and thin wall, such as the 600/4, 600/3 and 900/2 products. Due to the inherently lower mechanical strength of these products, coupled with a shift from underbody to close-coupled placement, a concern was expressed that the severe thermal and mechanical conditions may cause structural damage to the substrate, which in turn could impact the catalyst performance. One source of reduced performance during use is the loss of catalyst due to erosion. A previous study1 indicated that the existence of particulate in an air-stream could cause substrate erosion. However, it was not clear if other factors could contribute to or accelerate the erosion process. In order to address this question, experiments were performed to examine the influence of high velocity flow, temperature, impingement angle, particulate characteristics, and coating effect on erosion.

A previous paper reported (SAE Paper 2002-01-2884) that it was possible to decrease mode-weighted NOx emissions compared to the OEM calibration with corresponding increases in particulate matter (PM) emissions. These PM emission increases were partially overcome with the use of oxygenated diesel fuel additives. We wanted to know if compounds of toxicological concern were emitted more or less using oxygenated diesel fuel additives that were used in conjunction with a modified engine operating strategy to lower engine-out NOx emissions. Emissions of toxicologically relevant compounds from fuels containing triproplyene glycol monomethyl ether and dibutyl maleate were the same or lower compared to a low sulfur fuel (15 ppm sulfur) even under engine operating conditions designed to lower engine-out NOx emissions.

It has been reported that particulate emissions from diesel vehicles could be associated with damaging human health, global warming and a reduction in air quality. These particles cover a very large size range, typically 3 to 10 000 nm. Filters in the vehicle exhaust systems can substantially reduce particulate emissions but until very recently it was not possible to directly characterise actual on-road emissions from a vehicle. This paper presents the first study of the effect of filter systems on the particulate emissions of a heavy-duty diesel vehicle during real-world driving. The presence of sulfur in the fuel and in the engine lubricant can lead to significant emissions of sulfate particles < 30 nm in size (nanoparticles).

Characterization of diesel particulate filters requires test methods that permit rapid and accurate assessment of important performance requirements. The operation of the filter is comprised of two primary functions, particle filtering and filter soot regeneration. One challenge facing implementation of diesel filter technology lies with the difficult process of regenerating the filter after accumulating a full complement of soot. This paper will primarily focus on laboratory bench testing methods developed to study the regeneration characteristics of filters under a variety of test conditions. To rapidly assess the performance of many filters it was important to develop laboratory techniques that approximate engine exposure conditions. A simulated soot loading process and a well-controlled regeneration test method were developed.

Wall-flow filter technology has been used for many years to remove particulate emissions from a select number of diesel engine exhaust systems. Significant implementation of diesel particulate filters will require the definition of regeneration strategies that permit the filters to be regularly and durably purged of accumulated non-volatile particulates. This paper will examine the laboratory-bench characterization of filter responses to the wide variety of input conditions to which they may be exposed in practice. The lab-bench filter characterization will be done as a function of generic independent variables such as flow rate, inlet temperature, oxygen content and soot loading. The testing will be conducted on uncatalyzed filters for this preliminary study. The characterization approach will examine such dependent variables as completeness of regeneration and maximum exotherm temperatures.

Driven mainly by tightening of regulations, advance diesel emission control technologies are rapidly advancing. This paper will review the field with the intent of highlighting representative studies that illustrate the state-of-the-art. First, the author makes estimates of the emission control efficiency targets for heavy and light duty applications. Given the emerging significance of ultrafines to health, and to emission control technologies, an overview of the significant developments in ultrafine particulate science is provided, followed by an assessment of filter technology. Major deNOx catalyst developments, in addition to SCR and LNT progress is described. Finally, system integration examples are provided. In general, progress is impressive and studies have demonstrated that high-efficiency systems are within reach in all sectors highway vehicle sectors. Engines are making impressive gains, and will increase the options for emission control.

This summary covers representative developments from 2008 in diesel regulations, engine technology, and NOx, particulate matter (PM), and hydrocarbon (HC) control. Europe is finalizing the Euro VI heavy-duty (HD) regulations for 2013 with the intent of technologically harmonizing with the US. A new particle number standard will be adopted. California is considering tightening the light-duty fleet average to US Tier 2 Bin 2 levels, and CO2 mandates are emerging in Europe for LD, and in the US for all vehicles. LD engine technology is focused on downsizing to deliver lower CO2 emissions, enabled by advances in boost and EGR (exhaust gas recirculation). Emerging concepts are shown for attaining Bin 2 emission levels. HD engines will make deNOx systems optional for even the tightest NOx standards, but deNOx systems enable much lower fuel consumption levels and will likely be used. NOx control is centered on SCR (selective catalytic reduction) for diverse applications.

This summary covers the developments from 2007 in diesel regulations, engine technology, and NOx and PM control. Regulatory developments are now focused on Europe, where heavy-duty regulations have been proposed for 2013. The regulations are similar in technology needs to US2010. Also, the European Commission proposed the first CO2 emission limits of 130 g/km, which are nearly at parity to the Japanese fuel economy standards. Engines are making very impressive progress, with clean combustion strategies in active development mainly for US light-duty application. Heavy-duty research engines are more focused on traditional approaches, and will provide numerous engine/aftertreatment options for hitting the tight US 2010 regulations. NOx control is centered on SCR (selective catalytic reduction) for diverse applications. Focus is on cold operation and system optimization. LNT (lean NOx traps) durability is quantified, and performance enhanced with a sulfur trap.

This paper will review the field of diesel emission control with the intent of highlighting representative studies that illustrate the state-of-the-art. First, the author reviews general technology approaches for heavy and light duty applications. Given the emerging significance of ultrafines to health, and to emission control technologies, an overview of the significant developments in ultrafine particulate science is provided, followed by an assessment of filter technology. Regarding NOx control, SCR (selective catalytic reduction) and LNT (lean NOx traps) progress is described. Finally, system integration examples are provided. In general, progress is impressive and studies demonstrate that high-efficiency systems are within reach in all highway vehicle sectors. Engines are making impressive gains, and will increase the options for emission control.

Significant particulate emission reductions of diesel engines can be achieved using diesel particulate filters (DPFs). Ceramic wall flow filters with a PM efficiency of >90% have proven to be effective components in emission control. The challenge for the application lies with the development and adaptation of a reliable regeneration strategy. The main focus is emission efficiency over the legally required durability periods, as well as over the useful vehicle life. It will be shown, that new DPF systems are characterized by a high degree of integration with the engine management system, to allow for initiation of the regeneration and its control for optimum DPF protection. Using selected cases, the optimum combination and tuning will be demonstrated for successful regenerations, taking into account DPF properties.