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Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

Experiments were conducted on a turbocharged three cylinder automotive common rail diesel engine with port injection of butanol. This dual fuel engine was run with neat butanol and blends of water and butanol (up to 20% water by mass). Experiments were performed at a constant speed of 1800 rpm and a brake mean effective pressure of 11.8 bar (full load) at varying butanol to diesel energy share values while diesel was either injected as a single pulse or as twin pulses (Main plus Post). Open engine controllers were used for varying the injection parameters of diesel and butanol. Water butanol blends improved the brake thermal efficiency by a small extent because of better combustion phasing as compared to butanol without water. When the butanol to diesel energy share was high, auto-ignition of butanol occurred before the injection of diesel. This lowered the ignition delay of diesel and hence elevated the smoke level.

Use of biodiesel from non-edible vegetable oil as an alternative fuel to mineral diesel is attractive economically and environmentally. Diesel engines emit several harmful gaseous emissions and some of them are regulated worldwide, while countless others are not regulated. These unregulated species are associated with severe health hazards. Karanja biodiesel is a popular alternate fuel in South Asia and various governments are considering its large-scale implementation. Therefore it is important to study the possible adverse impact of this new alternate fuel. In this study, unregulated and regulated emissions were measured at varying engine speeds (1500, 2500 and 3500 rpm) for various engine loads (0%, 20%, 40%, 60%, 80% and 100% rated load) using 20% Karanja biodiesel blend (KB20) and diesel in a 4-cylinder 2.2L common rail direct injection (CRDI) sports utility vehicle (SUV) engine.

Gasoline direct injection (GDI) technology is already in use in four wheeler applications owing to the additional benefits in terms of better combustion and fuel economy. The air-assisted in-cylinder injection is the emerging technology for gasoline engines which works with low pressure injection systems unlike gasoline direct injection (GDI) system. GDI systems use high pressure fuel injection, which provides better combustion and reduced fuel consumption. It envisages small droplet size and low penetration rate which will reduce wall wetting and hydrocarbon emissions. This study is concerned with a CFD analysis of an air-assisted injection system to evaluate mixture spray characteristics. For the analysis, the air injector fitted onto a constant volume chamber (CVC) maintained at uniform pressure is considered. The analysis is carried out for various CVC pressures, mixture injection durations and fuel quantities so as to understand the effect on mixture spray characteristics.

Better understanding of flow phenomena inside the combustion chamber of a diesel engine and accurate measurement of flow parameters is necessary for engine optimization i.e. enhancing power output, fuel economy improvement and emissions control. Airflow structures developed inside the engine combustion chamber significantly influence the air-fuel mixing. In this study, in-cylinder air flow characteristics of a motored, four-valve diesel engine were investigated using time-resolved high-speed Tomographic Particle Imaging Velocimetry (PIV). Single cylinder optical engine provides full optical access of combustion chamber through a transparent cylinder and flat transparent piston top. Experiments were performed in different vertical planes at different engine speeds during the intake and compression stroke under motoring condition. For visualization of air flow pattern, graphite particles were used for flow seeding.

In this study, 3D air-flow-field evolution in a single cylinder optical research engine was determined using tomographic particle imaging velocimetry (TPIV) at different engine speeds. Two directional projections of captured flow-field were pre-processed to reconstruct the 3D flow-field by using the MART (multiplicative algebraic reconstruction technique) algorithm. Ensemble average flow pattern was used to investigate the air-flow behavior inside the combustion chamber during the intake and compression strokes of an engine cycle. In-cylinder air-flow characteristics were significantly affected by the engine speed. Experimental results showed that high velocities generated during the first half of the intake stroke dissipated in later stages of the intake stroke. In-cylinder flow visualization indicated that large part of flow energy dissipated during the intake stroke and energy dissipation was the maximum near the end of the intake stroke.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.

The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.

The use of alcohol-gasoline blends enables the favorable features of alcohols to be utilized in spark ignition (SI) engines while avoiding the shortcomings of their application as straight fuels. Eucalyptus and orange oils possess high octane values and are also good potential alternative fuels for SI engines. The high octane value of these fuels can enhance the octane value of the fuel when it is blended with low-octane gasoline. In the present work, 20 percent by volume of orange oil, eucalyptus oil, methanol and ethanol were blended separately with gasoline, and the performance, combustion and exhaust emission characteristics were evaluated at two different compression ratios. The phase separation problems arising from the alcohol-gasoline blends were minimized by adding eucalyptus oil as a co-solvent. Test results indicate that the compression ratio can be raised from 7.4 to 9 without any detrimental effect, due to the higher octane rating of the fuel blends.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

In modern engine design, downsizing and reducing weight while still providing an increased amount of power has been a general trend in recent decades. Traditionally, an engine design with superior NVH performance usually comes with a heavier, thus sturdier structure. Therefore, modern engine design requires that NVH be considered in the very early design stage to avoid modifications of engine structure at the last minute, when very few changes can be made. NVH design optimization of engine components has become more practical due to the development of computer software and hardware. However, there is still a need for smarter algorithms to draw a direct relationship between the design and the radiated sound power. At the moment, techniques based on modal acoustic transfer vectors (MATVs) have gained popularity in design optimization for their good performance in sound pressure prediction.

With increasing energy prices and concerns about the environmental impact of greenhouse gas (GHG) emissions, a growing number of national governments are putting emphasis on improving the energy efficiency of the equipment employed throughout their transportation systems. Within the U.S. transportation sector, energy use in commercial vehicles has been increasing at a faster rate than that of automobiles. A 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected from 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. and global economies.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

In gasoline direct injection (GDI) engines, air-fuel mixture homogeneity plays a major role on engine performance, especially in combustion and emission characteristics. The performance of the engine largely depends on various engine operating parameters viz., start of injection, duration of injection and spark timing. In order to achieve faster results CFD is becoming a handy tool to optimize and understand the effect of these parameters. Therefore, this study aims on evaluating the two injection parameters viz., single and split injection to evaluate different flame characteristics. Novelty in this study is to define five different parameters which are called α, β, γ, δ and η the details of which are explained in the paper. In order to understand the flame characteristics, these five parameters are found to be very useful. In the present study, a single-cylinder, two-valve, four- stroke engine which is used in two-wheelers in India is considered for carrying out the CFD analysis.

The effect of variation in injection pressure and Injection timing on the performance and exhaust emission characteristics of a direct injection, naturally aspirated Diesel engine operating on Diesel and Diesel-Biodiesel Blends were studied. A three-way factorial design consisting of four levels of injection pressure (150,210, 265,320 bar), four levels of injection timing (19° btdc, 21.5° btdc, 26° btdc, and 30.5° btdc) and five different fuel types (D100, B10, B20, B40, and B60) were employed in this test. The experimental analysis shows that when operating with Linseed Oil Methyl Ester-Diesel blends, we could increase the injection pressure by about 25% over the normal value of 20MPa. The engine performance and exhaust emission characteristics of the engine operating on the ester fuels at advanced injection timing were better than when operating at increased injection pressure.